Electronic equipment vulnerability to fire released carbon fibers

The vulnerability of electronic equipment to damage by carbon fibers released from burning aircraft type structural composite materials was investigated. Tests were conducted on commercially available stereo power amplifiers which showed that the equipment was damaged by fire released carbon fibers but not by the composite resin residue, soot and products of combustion of the fuel associated with burning the carbon fiber composites. Results indicate that the failure rates of the equipment exposed to the fire released fiber were consistent with predictions based on tests using virgin fibers

Passive Integrated Transponder Tags: Review of Studies on Warmwater Fishes With Notes on Additional Species

Although numerous studies have assessed retention and survival of passive integrated transponder (PIT) tags, data are scattered and information gaps remain for many diminutive fishes. Our study objectives were to 1) systematically review PIT tag studies and summarize retention, growth, and survival data for warmwater fishes; and 2) conduct a laboratory study to evaluate the retention, survival, and growth effects of intracoelomic-placed, half duplex PIT tags on six small-bodied species common to warmwater streams. Our systematic review suggested small sample sizes were common within PIT tag retention and survival studies (39% with n ≤ 20) and that many experiments (15%, 14 of 97) failed to use control fish as part of their evaluations. Studies focused primarily on short-term changes (15 d to 2 y) in tag retention and survival. Tag retention was equal to or greater than 90% in 85% of the experiments reviewed and median survival was 92%. Growth was reported by fishes in the majority of reviewed studies. We found similar results after PIT tagging (peritoneum tagging using 12- or 23-mm half duplex tags) adult Cardinal Shiner Luxilus cardinalis, Central Stoneroller Campostoma annomalum, Greenside Darter Etheostoma blennioides, Orangethroat Darter Etheostoma spectabile, Slender Madtom Noturus exilis, and juvenile Smallmouth Bass Micropterus dolomieu. Tag retention for all species was high, with only one tag loss recorded after 60 d. Survival was also high (≥88%) for all of our species with the exception of Orangethroat Darter (56% survival). No significant difference in mean growth between treatment and control groups was found. Both our results and the findings of the literature review suggested generally high tag retention and low mortality in tagged fishes (across 31 species reviewed). However, within our study (e.g., Orangethroat Darter) and from the literature, examples of negative effects of PIT tagging on fishes were apparent, suggesting methodological testing is necessary before using PIT tags in field studies. We suggest future studies would benefit from addressing the behavioral implications that may be associated with tagging and examination of longer-term tag retention. Furthermore, standard reporting (i.e., sample sizes) in PIT tag studies would be beneficial, and use of control subjects or groups for statistical comparisons is needed

Engineering Schottky contacts in open-air fabricated heterojunction solar cells to enable high performance and ohmic charge transport.

The efficiencies of open-air processed Cu2O/Zn(1-x)Mg(x)O heterojunction solar cells are doubled by reducing the effect of the Schottky barrier between Zn(1-x)Mg(x)O and the indium tin oxide (ITO) top contact. By depositing Zn(1-x)Mg(x)O with a long band-tail, charge flows through the Zn(1-x)Mg(x)O/ITO Schottky barrier without rectification by hopping between the sub-bandgap states. High current densities are obtained by controlling the Zn(1-x)Mg(x)O thickness to ensure that the Schottky barrier is spatially removed from the p-n junction, allowing the full built-in potential to form, in addition to taking advantage of the increased electrical conductivity of the Zn(1-x)Mg(x)O films with increasing thickness. This work therefore shows that the Zn(1-x)Mg(x)O window layer sub-bandgap state density and thickness are critical parameters that can be engineered to minimize the effect of Schottky barriers on device performance. More generally, these findings show how to improve the performance of other photovoltaic system reliant on transparent top contacts, e.g., CZTS and CIGS.This work was supported by EPSRC of the UK (award number RG3717)This is the accepted manuscript. The final version is available from ACS at http://pubs.acs.org/doi/abs/10.1021/am5058663

Small scale spatial variability of snow density and depth over complex alpine terrain: Implications for estimating snow water equivalent

This study analyzes spatial variability of snow depth and density from measurements made in February and April of 2010 and 2011 in three 1–2 km2 areas within a valley of the central Spanish Pyrenees. Snow density was correlated with snow depth and different terrain characteristics. Regression models were used to predict the spatial variability of snow density, and to assess how the error in computed densities might influence estimates of snow water equivalent (SWE). The variability in snow depth was much greater than that of snow density. The average snow density was much greater in April than in February. The correlations between snow depth and density were generally statistically significant but typically not very high, and their magnitudes and signs were highly variable among sites and surveys. The correlation with other topographic variables showed the same variability in magnitude and sign, and consequently the resulting regression models were very inconsistent, and in general explained little of the variance. Antecedent climatic and snow conditions prior to each survey help highlight the main causes of the contrasting relation shown between snow depth, density and terrain. As a consequence of the moderate spatial variability of snow density relative to snow depth, the absolute error in the SWE estimated from computed densities using the regression models was generally less than 15%. The error was similar to that obtained by relating snow density measurements directly to adjacent snow depths.This work was supported by research projects CGL2011-27536/HID: “Hidrologia nival en el Pirineo central español: variabilidad espacial, importancia hidrológica y su respuesta a la variabilidad y cambio climático”, financed by the Spanish Commission of Science and Technology, and FEDER; ACQWA (FP7-ENV- 2008-1-212250); the projects “La nieve en el Pirineo aragonés: Distribución especial y su respuesta a las condiciones climáticas” and “Efecto de los escenarios de cambio climático sobre la hidrología superficial y la gestión de embalses del Pirineo Aragonés”, financed by “Obra Social La Caixa”; and “Influencia del cambio climático en el turismo de nieve-CTTP1/10”, financed by the Comunidad de Trabajo de los Pirineos, CTP.Peer Reviewe

Size-Dependent Photon Emission from Organometal Halide Perovskite Nanocrystals Embedded in an Organic Matrix

10.1021/jz502615eJournal of Physical Chemistry Letters63446-45

Effects of Snow Water Storage on Hydrologic Partitioning Across the Mountainous, Western United States

In the montane western United States, where the majority of downstream water resources are derived from snowmelt, a warming climate threatens the timing and amount of future water availability. It is expected that the fraction of precipitation falling as snow will continue decreasing and the timing of snowmelt will continue shifting earlier in the year with unknown impacts on partitioning between evapotranspiration and streamflow. To assess this, we employ a Snow Storage Index (SSI) to represent the annual temporal phase difference between daily precipitation and daily modeled surface water inputs (SWI, the sum of rainfall and snowmelt), weighted by the respective amounts. We coupled the SSI metric with a Budyko-based framework to determine the effect of snow water storage on relative hydrologic partitioning across snow-influenced watersheds in the western U.S. Greater snow water storage was positively correlated with greater hydrologic partitioning to streamflow, particularly in the North Cascades/Cascades (r2: 0.62), Blue Mountains (r2: 0.56), Canadian Rockies (r2: 0.55), Idaho Batholith, (r2: 0.48), and Columbia Mountains/Northern Rockies (r2: 0.45). The weekly SWI:P ratio was an equally strong predictor for hydrologic partitioning, particularly in mid-spring (e.g., March/April) in the same mountainous areas (r2: 0.62&ndash;0.74, across the same eco-regions). The retention of snow water storage and subsequent release of stored water in summer months resulted in increased hydrologic partitioning to streamflow. If SSI decreases with future warming, the volume of water partitioned streamflow will decrease non-uniformly across the western U.S. with substantial implications for ecosystems and agricultural, industrial, and domestic water supplies. &nbsp;</p

Single-walled carbon nanotube interactions with HeLa cells

This work concerns exposing cultured human epithelial-like HeLa cells to single-walled carbon nanotubes (SWNTs) dispersed in cell culture media supplemented with serum. First, the as-received CoMoCAT SWNT-containing powder was characterized using scanning electron microscopy and thermal gravimetric analyses. Characterizations of the purified dispersions, termed DM-SWNTs, involved atomic force microscopy, inductively coupled plasma – mass spectrometry, and absorption and Raman spectroscopies. Confocal microRaman spectroscopy was used to demonstrate that DM-SWNTs were taken up by HeLa cells in a time- and temperature-dependent fashion. Transmission electron microscopy revealed SWNT-like material in intracellular vacuoles. The morphologies and growth rates of HeLa cells exposed to DM-SWNTs were statistically similar to control cells over the course of 4 d. Finally, flow cytometry was used to show that the fluorescence from MitoSOX™ Red, a selective indicator of superoxide in mitochondria, was statistically similar in both control cells and cells incubated in DM-SWNTs. The combined results indicate that under our sample preparation protocols and assay conditions, CoMoCAT DM-SWNT dispersions are not inherently cytotoxic to HeLa cells. We conclude with recommendations for improving the accuracy and comparability of carbon nanotube (CNT) cytotoxicity reports