Paramagnon dispersion in β\beta-FeSe observed by Fe LL-edge resonant inelastic x-ray scattering

We report an Fe $L$-edge resonant inelastic x-ray scattering (RIXS) study of the unusual superconductor $\beta$-FeSe. The high energy resolution of this RIXS experiment ($\approx\,$55$\,$meV FWHM) made it possible to resolve low-energy excitations of the Fe $3d$ manifold. These include a broad peak which shows dispersive trends between 100-200$\,$meV along the $(\pi,0)$ and $(\pi,\pi)$ directions of the one-Fe square reciprocal lattice, and which can be attributed to paramagnon excitations. The multi-band valence state of FeSe is among the most metallic in which such excitations have been discerned by soft x-ray RIXS

The Emergence of the Thick Disk in a CDM Universe II: Colors and Abundance Patterns

The recently emerging conviction that thick disks are prevalent in disk galaxies, and their seemingly ubiquitous old ages, means that the formation of the thick disk, perhaps more than any other component, holds the key to unravelling the evolution of the Milky Way, and indeed all disk galaxies. In Paper I, we proposed that the thick disk was formed in an epoch of gas rich mergers, at high redshift. This hypothesis was based on comparing N-body/SPH simulations to a variety of Galactic and extragalactic observations, including stellar kinematics, ages and chemical properties.Here examine our thick disk formation scenario in light of the most recent observations of extragalactic thick disks. In agreement, our simulted thick disks are old and relatively metal rich, with V-I colors that do not vary significantly with distance from the plane. Further, we show that our proposal results in an enhancement of alpha-elements in thick disk stars as compared with thin disk stars, consistent with observations of the relevant populations of the Milky Way. We also find that our scenario naturally leads to the formation of an old metal weak stellar halo population with high alpha-element abundances.Comment: submitted to Ap

Further Evidence for a Merger Origin for the Thick Disk: Galactic Stars Along Lines-of-sight to Dwarf Spheroidal Galaxies

The history of the Milky Way Galaxy is written in the properties of its stellar populations. Here we analyse stars observed as part of surveys of local dwarf spheroidal galaxies, but which from their kinematics are highly probable to be non-members. The selection function -- designed to target metal-poor giants in the dwarf galaxies, at distances of ~100kpc -- includes F-M dwarfs in the Milky Way, at distances of up to several kpc. Thestars whose motions are analysed here lie in the cardinal directions of Galactic longitude l ~ 270 and l ~ 90, where the radial velocity is sensitive to the orbital rotational velocity. We demonstrate that the faint F/G stars contain a significant population with V_phi ~ 100km/s, similar to that found by a targeted, but limited in areal coverage, survey of thick-disk/halo stars by Gilmore, Wyse & Norris (2002). This value of mean orbital rotation does not match either the canonical thick disk or the stellar halo. We argue that this population, detected at both l ~ 270 and l ~ 90, has the expected properties of `satellite debris' in the thick-disk/halo interface, which we interpret as remnants of the merger that heated a pre-existing thin disk to form the thick disk.Comment: Accepted, Astrophysical Journal Letter

Two-neutron separation energies, binding energies and phase transitions in the interacting boson model

In the framework of the interacting boson model the three transitional regions (rotational-vibrational, rotational-$\gamma$-unstable and, vibrational-$\gamma$-unstable transitions) are reanalyzed. A new kind of plot is presented for studying phase transitions in finite systems such as atomic nuclei. The importance of analyzing binding energies and not only energy spectra and electromagnetic transitions, describing transitional regions is emphasized. We finally discuss a number of realistic examples.Comment: 34 pages, TeX (ReVTeX). 12 ps figures. 3 tables. Submitted to Nucl. Phys.

Remote participation during glycosylation reactions of galactose building blocks: Direct evidence from cryogenic vibrational spectroscopy

The stereoselective formation of 1,2‐cis‐glycosidic bonds is challenging. However, 1,2‐cis‐selectivity can be induced by remote participation of C4 or C6 ester groups. Reactions involving remote participation are believed to proceed via a key ionic intermediate, the glycosyl cation. Although mechanistic pathways were postulated many years ago, the structure of the reaction intermediates remained elusive owing to their short‐lived nature. Herein, we unravel the structure of glycosyl cations involved in remote participation reactions via cryogenic vibrational spectroscopy and first principles theory. Acetyl groups at C4 ensure α‐selective galactosylations by forming a covalent bond to the anomeric carbon in dioxolenium‐type ions. Unexpectedly, also benzyl ether protecting groups can engage in remote participation and promote the stereoselective formation of 1,2‐cis‐glycosidic bonds