56 research outputs found
Light-induced instabilities in photo-oriented liquid crystal cells
In a planar liquid crystal sample sandwiched between a photosensitive and a
reference plate instabilities occurred, when the cell was illuminated from the
reference side. The instabilities were induced both by polarized white light
source and monochromatic laser beams. Static and dynamic regimes were found;
for laser irradiation dynamic instability was found only in a range of
polarization directions. A model, developed for monochromatic excitation,
predicts that at certain thicknesses dynamic instability is forbidden.
Experiments on a wedge-like cell confirmed this conclusion.Comment: to appear in Mol. Cryst. Liq. Crys
Phase behaviors of binary mixtures composed of banana-shaped and calamitic mesogens
In this work, five mixtures with different concentrations of banana-shaped
and calamitic compounds have been prepared and subsequently studied by
polarizing optical microscopy, differential scanning calorimetry, and X-ray
diffraction on non-oriented samples. The phase sequences and molecular
parameters of the binary systems are presented
Supplementary data for the article: Marković, J. M.; Trišović, N. P.; Tóth-Katona, T.; Milčić, M. K.; Marinković, A. D.; Zhang, C.; Jákli, A. J.; Fodor-Csorba, K. A Structure-Property Relationship Study of Bent-Core Mesogens with Pyridine as the Central Unit. New Journal of Chemistry 2014, 38 (4), 1751–1760. https://doi.org/10.1039/c3nj01430d
Supplementary material for: [https://doi.org/10.1039/c3nj01430d]Related to published version: [http://cherry.chem.bg.ac.rs/handle/123456789/1518
Supplementary data for the article: Marković, J. M.; Trišović, N. P.; Tóth-Katona, T.; Milčić, M. K.; Marinković, A. D.; Zhang, C.; Jákli, A. J.; Fodor-Csorba, K. A Structure-Property Relationship Study of Bent-Core Mesogens with Pyridine as the Central Unit. New Journal of Chemistry 2014, 38 (4), 1751–1760. https://doi.org/10.1039/c3nj01430d
Supplementary material for: [https://doi.org/10.1039/c3nj01430d]Related to published version: [http://cherry.chem.bg.ac.rs/handle/123456789/1518
Orientational Order, Molecular Organization, and Dynamics in Mixtures of Bent-Core and Rod-Shaped Mesogens: A H-2 NMR Study
Mixtures of a bent-core mesogen (ClPbis10BB) and a calamitic mesogen (6OO8), showing a nematic phase over the entire compositional range and one or two smectic phases (namely, SmA, SmC, or SmCA) below the nematic one over a wide concentration range, were investigated by means of 2H NMR spectroscopy, exploiting selectively deuterated isotopomers of both mesogens. The analysis of 2H NMR spectra recorded in the liquid crystalline phases on several representative mixtures gave information on the orientational order properties and the molecular organization within the phases as well as on the alignment properties upon application of a magnetic field. On the other hand, the analysis of 2H longitudinal relaxation times (T1Z and T1Q) in 6OO8- d2/ClPbis10BB mixtures and pure 6OO8-d2 allowed the influence of the bent-core mesogen on the dynamics of the calamitic one to be highlighted
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