Water exchange at a hydrated platinum electrode is rare and collective

We use molecular dynamics simulations to study the exchange kinetics of water molecules at a model metal electrode surface -- exchange between water molecules in the bulk liquid and water molecules bound to the metal. This process is a rare event, with a mean residence time of a bound water of about 40 ns for the model we consider. With analysis borrowed from the techniques of rare-event sampling, we show how this exchange or desorption is controlled by (1) reorganization of the hydrogen bond network within the adlayer of bound water molecules, and by (2) interfacial density fluctuations of the bulk liquid adjacent to the adlayer. We define collective coordinates that describe the desorption mechanism. Spatial and temporal correlations associated with a single event extend over nanometers and tens of picoseconds.Comment: 10 pages, 9 figure

Apollo experience report: The cryogenic storage system

A review of the design, development, and flight history of the Apollo cryogenic storage system and of selected components within the system is presented. Discussions are presented on the development history of the pressure vessels, heaters, insulation, and selected components. Flight experience and operational difficulties are reported in detail to provide definition of the problems and applicable corrective actions

Structure and thermodynamics of colloid-polymer mixtures: a macromolecular approach

The change of the structure of concentrated colloidal suspensions upon addition of non-adsorbing polymer is studied within a two-component, Ornstein-Zernicke based liquid state approach. The polymers' conformational degrees of freedom are considered and excluded volume is enforced at the segment level. The polymer correlation hole, depletion layer, and excess chemical potentials are described in agreement with polymer physics theory in contrast to models treating the macromolecules as effective spheres. Known depletion attraction effects are recovered for low particle density, while at higher densities novel many-body effects emerge which become dominant for large polymers.Comment: 7 pages, 4 figures; to be published in Europhys. Let

Early Cementation of the Short Creek Oolite Member, Boone Formation (Osagean, Lower Mississippian), Northern Arkansas

The Short Creek Oolite is the only formally named member of the Boone Formation in northern Arkansas. It lacks bedding features, and oolith concentrations that would suggest a shoal environment, and it occurs at variable stratigraphic horizons within the upper Boone Formation consistent with episodic deposition as grainflow slurries. As with modern oolite examples, such as Joulters Cays, Bahamas, the Short Creek preserves numerous intraclasts, and at least one large olistolith indicating an early cementation history

Potential model calculations and predictions for heavy quarkonium

We investigate the spectroscopy and decays of the charmonium and upsilon systems in a potential model consisting of a relativistic kinetic energy term, a linear confining term including its scalar and vector relativistic corrections and the complete perturbative one-loop quantum chromodynamic short distance potential. The masses and wave functions of the various states are obtained using a variational technique, which allows us to compare the results for both perturbative and nonperturbative treatments of the potential. As well as comparing the mass spectra, radiative widths and leptonic widths with the available data, we include a discussion of the errors on the parameters contained in the potential, the effect of mixing on the leptonic widths, the Lorentz nature of the confining potential and the possible $c\bar{c}$ interpretation of recently discovered charmonium-like states.Comment: Physical Review published versio

PSR J0609+2130: A disrupted binary pulsar?

We report the discovery and initial timing observations of a 55.7-ms pulsar, J0609+2130, found during a 430-MHz drift-scan survey with the Arecibo radio telescope. With a spin-down rate of $3.1 \times 10^{-19}$ s s$^{-1}$ and an inferred surface dipole magnetic field of only $4.2 \times 10^{9}$ G, J0609+2130 has very similar spin parameters to the isolated pulsar J2235+1506 found by Camilo, Nice & Taylor (1993). While the origin of these weakly magnetized isolated neutron stars is not fully understood, one intriguing possibility is that they are the remains of high-mass X-ray binary systems which were disrupted by the supernova explosion of the secondary star.Comment: 5 pages, 2 figures, accepted for publication in MNRAS (letters

The application of the global isomorphism to the surface tension of the liquid-vapor interface of the Lennard-Jones fluids

In this communication we show that the surface tension of the real fluids of the Lennard-Jones type can be obtained from the surface tension of the lattice gas (Ising model) on the basis of the global isomorphism approach developed earlier for the bulk properties.Comment: 8 pages, 6 figure

VLA Survey of Dense Gas in Extended Green Objects: Prevalence of 25 GHz Methanol Masers

We present $\sim1-4"$ resolution Very Large Array (VLA) observations of four CH$_3$OH $J_2-J_1$-$E$ 25~GHz transitions ($J$=3, 5, 8, 10) along with 1.3~cm continuum toward 20 regions of active massive star formation containing Extended Green Objects (EGOs), 14 of which we have previously studied with the VLA in the Class~I 44~GHz and Class~II 6.7~GHz maser lines (Cyganowski et al. 2009). Sixteen regions are detected in at least one 25~GHz line ($J$=5), with 13 of 16 exhibiting maser emission. In total, we report 34 new sites of CH$_3$OH maser emission and ten new sites of thermal CH$_3$OH emission, significantly increasing the number of 25~GHz Class I CH$_3$OH masers observed at high angular resolution. We identify probable or likely maser counterparts at 44~GHz for all 15 of the 25~GHz masers for which we have complementary data, providing further evidence that these masers trace similar physical conditions despite uncorrelated flux densities. The sites of thermal and maser emission of CH$_3$OH are both predominantly associated with the 4.5 $\mu$m emission from the EGO, and the presence of thermal CH$_3$OH emission is accompanied by 1.3~cm continuum emission in 9 out of 10 cases. Of the 19 regions that exhibit 1.3~cm continuum emission, it is associated with the EGO in 16 cases (out of a total of 20 sites), 13 of which are new detections at 1.3~cm. Twelve of the 1.3~cm continuum sources are associated with 6.7~GHz maser emission and likely trace deeply-embedded massive protostars