Ultrabright Linearly Polarized Photon Generation from a Nitrogen Vacancy Center in a Nanocube Dimer Antenna

We demonstrate an exceptionally bright photon source based on a single nitrogen- vacancy center (NV-center) in a nanodiamond (ND), placed in the nanoscale gap between two monocrystalline silver cubes in a dimer configuration. The system is operated near saturation at a stable photon rate of 850 kcps, while we further achieve strongly polarized emission and high single photon purity, evident by the measured auto-correlation with a g(2)(0)-value of 0.08. These photon source features are key parameters for quantum technological applications, such as secure communication based on quantum key distribution. The cube antenna is assembled with an atomic force microscope, which allows us to predetermine the dipole orientation of the NV-center and optimize cube positioning accordingly, while also tracking the evolution of emission parameters from isolated ND to the 1 and 2 cube configuration. The experiment is well described by finite element modelling, assuming an instrinsic quantum efficiency of 0.35. We attribute the large photon rate of the assembled photon source, to increased quantum efficiency of the NV-center and high antenna efficiency

A webometric analysis of Australian Universities using staff and size dependent web impact factors (WIF)

This study describes how search engines (SE) can be employed for automated, efficient data gathering for Webometric studies using predictable URLs. It then compares the usage of staffrelated Web Impact Factors (WIFs) to sizerelated impact factors for a ranking of Australian universities, showing that rankings based on staffrelated WIFs correlate much better with an established ranking from the Melbourne Institute than commonly used sizedependent WIFs. In fact sizedependent WIFs do not correlate with the Melbourne ranking at all. It also compares WIF data for Australian Universities provided by Smith (1999) for a longitudinal comparison of the WIF of Australian Universities over the last decade. It shows that sizedependent WIF values declined for most Australian universities over the last ten years, while staffdependent WIFs rose

Resonance energy transfer from a fluorescent dye molecule to plasmon and electron-hole excitations of a metal nanoparticle

We study the distance dependence of the rate of electronic excitation energy transfer from a dye molecule to a metal nanoparticle. Using the spherical jellium model, we evaluate the rates corresponding to the excitation of l = 1, 2, and 3 modes of the nanoparticle. Our calculation takes into account both the electron-hole pair and the plasmon excitations of the nanoparticle. The rate follows conventional R^-6 dependence at large distances while small deviations from this behavior are observed at shorter distances. Within the framework of the jellium model, it is not possible to attribute the experimentally observed d^-4 dependence of the rate to energy transfer to plasmons or e-h pair excitations.Comment: 4 figure

The dynamics of loop formation in a semiflexible polymer

The dynamics of loop formation by linear polymer chains has been a topic of several theoretical/experimental studies. Formation of loops and their opening are key processes in many important biological processes. Loop formation in flexible chains has been extensively studied by many groups. However, in the more realistic case of semiflexible polymers, not much results are available. In a recent study (K. P. Santo and K. L. Sebastian, Phys. Rev. E, \textbf{73}, 031293 (2006)), we investigated opening dynamics of semiflexible loops in the short chain limit and presented results for opening rates as a function of the length of the chain. We presented an approximate model for a semiflexible polymer in the rod limit, based on a semiclassical expansion of the bending energy of the chain. The model provided an easy way to describe the dynamics. In this paper, using this model, we investigate the reverse process, i.e., the loop formation dynamics of a semiflexible polymer chain by describing the process as a diffusion-controlled reaction. We perform a detailed multidimensional analysis of the problem and calculate closing times for a semiflexible chain which leads to results that are physically expected. Such a multidimensional analysis leading to these results does not seem to exist in the literature so far.Comment: 37 pages 4 figure

A test of the CPL parameterization for rapid dark energy equation of state transitions

We test the robustness and flexibility of the Chevallier-Polarski-Linder (CPL) parameterization of the Dark Energy equation of state $w(z)=w_0+w_a \frac{z}{1+z}$ in recovering a four-parameter step-like fiducial model. We constrain the parameter space region of the underlying fiducial model where the CPL parameterization offers a reliable reconstruction. It turns out that non negligible biases leak into the results for recent ($z<2.5$) rapid transitions, but that CPL yields a good reconstruction in all other cases. The presented analysis is performed with supernova Ia data as forecasted for a space mission like SNAP/JDEM, combined with future expectations for the CMB shift parameter $R$ and the BAO parameter $A$.Comment: 8 pages, 6 ps figure

Antiferromagnetism of SrFe2As2 studied by Single-Crystal 75As-NMR

We report results of 75As nuclear magnetic resonance (NMR) experiments on a self-flux grown high-quality single crystal of SrFe2As2. The NMR spectra clearly show sharp first-order antiferromagnetic (AF) and structural transitions occurring simultaneously. The behavior in the vicinity of the transition is compared with our previous study on BaFe2As2. No significant difference was observed in the temperature dependence of the static quantities such as the AF splitting and electric quadrupole splitting. However, the results of the NMR relaxation rate revealed difference in the dynamical spin fluctuations. The stripe-type AF fluctuations in the paramagnetic state appear to be more anisotropic in BaFe2As2 than in SrFe2As2.Comment: 4 pages, 5 figures; discussion revised; accepted for publication in J. Phys. Soc. Jp

Ligand-Enhanced Abiotic Iron Oxidation and the Effects of Chemical versus Biological Iron Cycling in Anoxic Environments

This study introduces a newly isolated, genetically tractable bacterium (Pseudogulbenkiania sp. strain MAI-1) and explores the extent to which its nitrate-dependent iron-oxidation activity is directly biologically catalyzed. Specifically, we focused on the role of iron chelating ligands in promoting chemical oxidation of Fe(II) by nitrite under anoxic conditions. Strong organic ligands such as nitrilotriacetate and citrate can substantially enhance chemical oxidation of Fe(II) by nitrite at circumneutral pH. We show that strain MAI-1 exhibits unambiguous biological Fe(II) oxidation despite a significant contribution (~30–35%) from ligand-enhanced chemical oxidation. Our work with the model denitrifying strain Paracoccus denitrificans further shows that ligand-enhanced chemical oxidation of Fe(II) by microbially produced nitrite can be an important general side effect of biological denitrification. Our assessment of reaction rates derived from literature reports of anaerobic Fe(II) oxidation, both chemical and biological, highlights the potential competition and likely co-occurrence of chemical Fe(II) oxidation (mediated by microbial production of nitrite) and truly biological Fe(II) oxidation

Highest weight state description of the isotropic spin-1 chain

We introduce an overcomplete highest weight state basis as a calculational tool for the description of the isotropic spin-1 chain with bilinear exchange coupling J1 and biquadratic coupling J2. The ground state can be expressed exactly at the three special points in the phase diagram where the Hamiltonian corresponds to a sum of nearest neighbor total spin projection operators (J1=0>J2, J1=-J2<0, and J1=-J2/3<0). In particular, at the phase transition point J1=-J2<0 it is possible to exactly compute the ground states, excited states, expectation values, and correlation functions by using the new total spin basis.Comment: 8 pages, 1 figure, the most recent version can be found at http://www.physik.uni-kl.de/eggert/papers

A webometric analysis of Australian Universities using staff and size dependent web impact factors (WIF)

This study describes how search engines (SE) can be employed for automated, efficient data gathering for Webometric studies using predictable URLs. It then compares the usage of staffrelated Web Impact Factors (WIFs) to sizerelated impact factors for a ranking of Australian universities, showing that rankings based on staffrelated WIFs correlate much better with an established ranking from the Melbourne Institute than commonly used sizedependent WIFs. In fact sizedependent WIFs do not correlate with the Melbourne ranking at all. It also compares WIF data for Australian Universities provided by Smith (1999) for a longitudinal comparison of the WIF of Australian Universities over the last decade. It shows that sizedependent WIF values declined for most Australian universities over the last ten years, while staffdependent WIFs rose

Controlling the elution order of insulin and its analogs in sub-/supercritical fluid chromatography using methanesulfonic acid and 18-crown-6 as mobile phase additives

The purity analysis of therapeutic peptides can often be challenging, demanding the application of more than a single analytical technique. Supercritical fluid chromatography nowadays is a promising alternative to reversed-phase liquid chromatography, providing orthogonal and complementary information. This study investigated its applicability for the separation of human insulin, its analogs and degradation products. A previously published method development protocol for peptides up to 2000 Da was successfully applied to the higher molecular weight insulins (6 kDa). A single gradient method was optimized for all insulins using a Torus DEA column (100 × 3.0 mm, 1.7 μm), carbon dioxide and a modifier consisting of methanol/acetonitrile/water/methanesulfonic acid (65:35:2:0.1, v/v/v/v). Consecutively, the crown ether 18-crown-6, which is well known to complex charged lysine sidechains and other amino functionalities, was added to the modifier to evaluate its impact on selectivity. A decreased retention and a shift in the elution order for the insulins were observed. An inverse effect on retention was found when combined with a neutral stationary phase chemistry (Viridis BEH)