Influence of Domain Wall on Magnetocaloric Effect in GdPt2_{2}

The resistivity, magnetoresistance and in-field heat capacity measurements were performed on GdPt$_{2}$ intermetallic compound. The magnetocaloric parameters $\Delta T_{ad}$ and $-\Delta S$ were derived from the in-field heat capacity data. Comparison has been made between the magnetocaloric effect $-\Delta S$ and difference in resistivity $-\Delta \rho$ $(=\rho(H)-\rho(0))$ as a function of temperature. There is distinct difference in the temperature dependence of $-\Delta S$ and $-\Delta \rho$ below the ferromagnetic transition temperature. However after removing the domain wall contribution from $-\Delta \rho$, the nature of $-\Delta S$ and $-\Delta \rho$ dependence as a function of temperature are similar. Our observation indicates that the domain wall contribution in magnetocaloric effect is negligible in spite of the fact that it has significant contribution in magnetotransport.Comment: RevTex 4 pages, 6 figure

Origin of Middle-Infrared Peaks in Cerium Compounds

We have demonstrated that the middle-infrared (mid-IR) peaks in the optical conductivity spectra of Ce$X_3$ ($X$ = Pd, Sn, In) can be explained by first-principle band structure calculation with the spin-orbit interaction. The mid-IR peak shapes in these materials are not identical to one another: CePd$_3$, CeSn$_3$, and CeIn$_3$ have a triple-peak structure, double-peak structure and broad single-peak structure, respectively. These peaks can be theoretically explained by the optical transition from the occupied state to the spin-orbit splitted Ce $4f$ state. This result indicates that the mid-IR peaks originate from the simple band picture with the Ce $4f$ state near the Fermi level, not from the conventional cf hybridization gap based on the periodic Anderson model.Comment: 5 pages, 6 figures. To be published in J. Phys. Soc. Jpn. 78(1) (2009

Change of Magnetic Properties of Th₂Fe₁₇ Due to Interstitial Solution of C and N

The changes in magnetic and crystallographic properties in the series Th2Fe17Cx and Th2Fe 17Nx have been studied. The changes in the latter series were also studied by 57Fe Mössbauer spectroscopy. The ultimate enhancements of the saturation moments in these series are 13% and 24%, respectively. This is much larger than observed previously in the corresponding rare-earth compounds, although the Curie temperature enhancements are of comparable magnitude. In the Th-Fe-C system a novel compound of the BaCd 11 type was found, having a Curie temperature around 370 K

Why the iron magnetization in Gd2Fe14B and the spontaneous magnetization of Y2Fe14B depend on temperature differently

This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics.It is demonstrated that the temperature dependence of the iron sublattice magnetization in Gd2Fe14B is affected significantly by the Gd-Fe exchange interaction. This is at variance with the common perception that MFe(T) in iron-rich rare-earth intermetallics is determined predominantly by the Fe-Fe exchange. This phenomenon is discussed by considering the modification of the low-energy spin-wave spectrum of Gd2Fe14B, as compared to that of Y2Fe14B, under the influence of the Gd-Fe interaction. The result is of particular significance for evaluating the temperature dependence of the magnetocrystalline anisotropy of iron or cobalt compounds with anisotropic rare earths (e.g., Nd2Fe14B) and in turn, of the hard magnetic properties of such compounds

Can antiferromagnetism and superconductivity coexist in the high-field paramagnetic superconductor Nd(O,F)FeAs?

We present measurements of the temperature and field dependencies of the magnetization M(T,H) of Nd(O0.89F0.11)FeAs at fields up to 33T, which show that superconductivity with the critical temperature Tc ~ 51K cannot coexist with antiferromagnetic ordering. Although M(T,H) at 55 < T < 140K exhibits a clear Curie-Weiss temperature dependence corresponding to the Neel temperature TN ~ 11-12K, the behavior of M(T,H) below Tc is only consistent with either paramagnetism of weakly interacting magnetic moments or a spin glass state. We suggest that the anomalous magnetic behavior of an unusual high-field paramagnetic superconductor Nd(O1-xFx)FeAs is mostly determined by the magnetic Nd ions.Comment: 4 pages, 4 figure

Geometric, electronic, and magnetic structure of Co2_2FeSi: Curie temperature and magnetic moment measurements and calculations

In this work a simple concept was used for a systematic search for new materials with high spin polarization. It is based on two semi-empirical models. Firstly, the Slater-Pauling rule was used for estimation of the magnetic moment. This model is well supported by electronic structure calculations. The second model was found particularly for Co$_2$ based Heusler compounds when comparing their magnetic properties. It turned out that these compounds exhibit seemingly a linear dependence of the Curie temperature as function of the magnetic moment. Stimulated by these models, Co$_2$FeSi was revisited. The compound was investigated in detail concerning its geometrical and magnetic structure by means of X-ray diffraction, X-ray absorption and M\"o\ss bauer spectroscopies as well as high and low temperature magnetometry. The measurements revealed that it is, currently, the material with the highest magnetic moment ($6\mu_B$) and Curie-temperature (1100K) in the classes of Heusler compounds as well as half-metallic ferromagnets. The experimental findings are supported by detailed electronic structure calculations

Geometrical quadrupolar frustration in DyB4_4

Physical properties of DyB$_4$ have been studied by magnetization, specific heat, and ultrasonic measurements. The magnetic entropy change and the ultrasonic properties in the intermediate phase II indicate that the degeneracy of internal degrees of freedom is not fully lifted in spite of the formation of magnetic order. The ultrasonic attenuation and the huge softening of $C_{44}$ in phase II suggests existence of electric-quadrupolar (orbital) fluctuations of the 4$f$-electron. These unusual properties originate from the geometrical quadrupolar frustration.Comment: 4 pages, 4 figures, accepted for publication in Journal of the Physical Society of Japa

Towards the theory of ferrimagnetism

Two-sublattice ferrimagnet, with spin-$s_1$ operators $\bf{S_{1i}}$ at the sublattice $A$ site and spin-$s_2$ operators $\bf{S_{2i}}$ at the sublattice $B$ site, is considered. The magnon of the system, the transversal fluctuation of the total magnetization, is a complicate mixture of the transversal fluctuations of the sublattice $A$ and $B$ spins. As a result, the magnons' fluctuations suppress in a different way the magnetic orders of the $A$ and $B$ sublattices and one obtains two phases. At low temperature $(0,T^*)$ the magnetic orders of the $A$ and $B$ spins contribute to the magnetization of the system, while at the high temperature $(T^*,T_N)$, the magnetic order of the spins with a weaker intra-sublattice exchange is suppressed by magnon fluctuations, and only the spins with stronger intra-sublattice exchange has non-zero spontaneous magnetization. The $T^*$ transition is a transition between two spin-ordered phases in contrast to the transition from spin-ordered state to disordered state ($T_N$-transition). There is no additional symmetry breaking, and the Goldstone boson has a ferromagnetic dispersion in both phases. A modified spin-wave theory is developed to describe the two phases. All known Neel's anomalous $M(T)$ curves are reproduced, in particular that with "compensation point". The theoretical curves are compared with experimental ones for sulpho-spinel $MnCr2S_{4-x}Se_{x}$ and rare earth iron garnets.Comment: 9 pages, 8 figure