Amine-Functionalized Sugarcane Bagasse: A Renewable Catalyst for Efficient Continuous Flow Knoevenagel Condensation Reaction at Room Temperature

A biomass-based catalyst with amine groups (–NH2), viz., amine-functionalized sugarcane bagasse (SCB-NH2), was prepared through the amination of sugarcane bagasse (SCB) in a two-step process. The physicochemical properties of the catalyst were characterized through FT-IR, elemental analysis, XRD, TG, and SEM-EDX techniques, which confirmed the –NH2 group was grafted onto SCB successfully. The catalytic performance of SCB-NH2 in Knoevenagel condensation reaction was tested in the batch and continuous flow reactions. Significantly, it was found that the catalytic performance of SCB-NH2 is better in flow system than that in batch system. Moreover, the SCB-NH2 presented an excellent catalytic activity and stability at the high flow rate. When the flow rate is at the 1.5 mL/min, no obvious deactivation was observed and the product yield and selectivity are more than 97% and 99% after 80 h of continuous reaction time, respectively. After the recovery of solvent from the resulting solution, a white solid was obtained as a target product. As a result, the SCB-NH2 is a promising catalyst for the synthesis of fine chemicals by Knoevenagel condensation reaction in large scale, and the modification of the renewable SCB with –NH2 group is a potential avenue for the preparation of amine-functionalized catalytic materials in industry

A Facile and Eco-Effective Catalytic System for Synthesis of 5-Hydroxymethylfurfural from Glucose

A facile and eco-friendly system for synthesis of 5-hydroxymethylfurfural (HMF) from glucose has been investigated with the catalyst dihydric phosphate (H2PO4—) in a methyl isobutyl ketone (MIBK)/H2O biphasic system. The results showed that the catalyst dosage, reaction temperature, and reaction time had noticeable effects on glucose conversion and the HMF yield; more than 50% yield of HMF was achieved at the optimum conditions. In addition, this catalytic system was broadly substrate-tolerant; a satisfactory HMF yield was obtained from higher substrate concentrations and complex substrates. Furthermore, this efficient catalyst was recycled up to nine consecutive times without the loss of catalytic activity

Catalytic Fractionation of Raw Biomass to Biochemicals and Organosolv Lignin in a Methyl Isobutyl Ketone/H₂O Biphasic System

A biphasic system, consisting of methyl isobutyl ketone and H₂O, has been achieved for a highly integrated one-pot catalytic transformation and delignification process of lignocellulosic biomass. Using SO₃H-functionalized ionic liquids as catalysts, 85.8% of bagasse can be fractionated into 71.4% water-soluble chemicals at 76.3% lignin extraction ratio, under the optimized conditions. The practicability of this biphasic system for other typical biomass sources has also been tested with high efficiency, viz., 79.6 to 91.9% lignin extraction ratio of corncob, corn stalk, rice husk, and rice straw with 56.6 to 72.8% water-soluble chemicals yield at 64.8 to 81.3% feed conversion

Organocatalytic Dehydration of Fructose-Based Carbohydrates into 5‑Hydroxymethylfurfural in the Presence of a Neutral Inner Salt

A series of organic sulfonate inner salts, viz., aprotic imidazolium- and pyridinium-based zwitterions bearing sulfonate groups (−SO3–), were synthesized for the catalytic conversion of fructose-based carbohydrates into 5-hydroxymethylfurfural (HMF). The dramatic cooperation of both the cation and anion of inner salts played a crucial role in the HMF formation. The inner salts have excellent solvent compatibility, and 4-(pyridinium)butane sulfonate (PyBS) affords the highest catalytic activity with 88.2 and 95.1% HMF yields at almost full conversion of fructose in low-boiling-point protic solvent isopropanol (i-PrOH) and aprotic solvent dimethyl sulfoxide (DMSO), respectively. The substrate tolerance of aprotic inner salt was also studied through changing the substrate type, demonstrating its excellent specificity for catalytic valorization of fructose-moiety-containing C6 sugars, such as sucrose and inulin. Meanwhile, the neutral inner salt is structurally stable and reusable; after being recycled four times, the catalyst showed no appreciable loss of its catalytic activity. The plausible mechanism has been elucidated based on the dramatic cooperative effect of both the cation and sulfonate anion of inner salts. The noncorrosive, nonvolatile, and generally nonhazardous aprotic inner salt used in this study will benefit many biochemical-related applications

Shallow anatomy of a continent–ocean transition zone in the northern South China Sea from multichannel seismic data

The Cenozoic tectonic evolution of the South China Sea is reflected in diverse tectonic processes including continental rifting, seafloor spreading, subduction, terrane collision and strike-slip fault movement. A continent-ocean transition zone in the northern South China Sea caused by the lithospheric extension when the continent underwent break-up, rifting and later seafloor spreading, is clearly imaged in the multi-channel seismic data presented in this study. The morphological units of the continent-ocean transition zone are the rift-depression, the volcanic zone and tilted fault blocks. The volcanic zone represents a highest extension zone within the continent-ocean transition zone and is mainly distributed in the southern slope uplift zone along the northern passive margin of the South China Sea. The large listric-normal faults bounding the Dongsha Rise and Baiyun Sag are evidenced in the seismic image. The passive margin in the northern South China Sea underwent the wide-rift to narrow-rift process in the transition zone as inferred from the relation between the surface heat flow and initial rifted crustal thickness. The continent-ocean transition zone in the continental margin of the South China Sea is consistent with high heat flow zone (average 90 mW.m(-2)) observed in the previous heat flow measurements and at ODP Site 1148, and is manifested in a sharp change of the P-wave velocity. The rifted margin of the South China Sea is a non-typical magma poor passive margin or an intermediary form between the Iberian-type non-volcanic and the Greenland-type volcanic margin compared to the world's typical passive margin

Segmentation of the Manila subduction system from migrated multichannel seismics and wedge taper analysis

Based on bathymetric data and multichannel seismic data, the Manila subduction system is divided into three segments, the North Luzon segment, the seamount chain segment and the West Luzon segment starts in Southwest Taiwan and runs as far as Mindoro. The volume variations of the accretionary prism, the forearc slope angle, taper angle variations support the segmentation of the Manila subduction system. The accretionary prism is composed of the outer wedge and the inner wedge separated by the slope break. The backstop structure and a 0.5–1 km thick subduction channel are interpreted in the seismic Line 973 located in the northeastern South China Sea. The clear décollement horizon reveals the oceanic sediment has been subducted beneath the accretionary prism. A number of splay faults occur in the active outer wedge. Taper angles vary from 8.0° ± 1° in the North Luzon segment, 9.9° ± 1° in the seamount segment to 11° ± 1° in the West Luzon segment. Based on variations between the taper angle and orthogonal convergence rates in the world continental margins and comparison between our results and the global compilation, different segments of the Manila subduction system fit well the global pattern. It suggests that subduction accretion dominates the north Luzon and seamount chain segment, but the steep slope indicates in the West Luzon segment and implies that tectonic erosion could dominate the West Luzon segment