5 research outputs found
Synthesis and Lanthanide Coordination Chemistry of Phosphine Oxide Decorated Dibenzothiophene and Dibenzothiophene Sulfone Platforms
No full textSyntheses
for new ligands based upon dibenzothiophene and dibenzothiophene sulfone
platforms, decorated with phosphine oxide and methylphosphine oxide
donor groups, are described. Coordination chemistry of 4,6-bis(diphenylphosphinoylmethyl)dibenzothiophene
(<b>8</b>), 4,6-bis(diphenylphosphinoylmethyl)dibenzothiophene-5,5-dioxide
(<b>9</b>) and 4,6-bis(diphenylphosphinoyl)dibenzothiophene-5,5-dioxide
(<b>10</b>) with lanthanide nitrates, Ln(NO<sub>3</sub>)<sub>3</sub>·(H<sub>2</sub>O)<sub><i>n</i></sub> is outlined,
and crystal structure determinations reveal a range of chelation interactions
on Ln(III) ions. The nitric acid dependence of the solvent extraction
performance of <b>9</b> and <b>10</b> in 1,2-dichloroethane
for Eu(III) and Am(III) is described and compared against the extraction
behavior of related dibenzofuran ligands (<b>2</b>, <b>3</b>; R = Ph) and <i>n</i>-octyl(phenyl)-<i>N</i>,<i>N</i>-diisobutylcarbamoylmethyl phosphine oxide (<b>4</b>) measured under identical conditions
Synthesis and lanthanide coordination chemistry of CMPO-decorated dibenzothiophene and dibenzothiophene sulfone platforms
No full text
