INFLUÊNCIA DO DIÂMETRO DE ESTACAS NO DESENVOLVIMENTO DOS BROTOS DE Platanus x acerifolia

O objetivo do presente trabalho foi determinar o diâmetro ideal de estacas para a produção de mudas de Platanus x acerifolia. As estacas utilizadas foram coletadas em árvores cuja a brotação apresentava-se com um ano de idade. Foram comparados três diâmetros de estacas: diâmetros inferiores a 1 cm, diâmetros entre 1 e 2 cm e diâmetros superiores a 2 cm. Todas as estacas possuiam 30 cm de comprimento. Decorridos 90 dias do plantio das estacas, foram medidas as alturas dos brotos, onde na qual o maior desenvolvimento foi observado nas estacas com diâmetro entre 1 e 2 centímetros

Influence of the slice position on chloride migration tests for concrete in marine conditions

Chloride migration tests are used to measure the concrete capacity to inhibit chloride attack. Many researchers carry out this test in a slice of concrete extracted from the central part of cylindrical specimens, discarding about 75% of the concrete used to mold the specimens. This fact generated the question: would it be possible to extract more slices from a same specimen without losing the confidence in the results? The main purpose of this work is to answer this question. Moreover, another aim of this study was to show the difference of chloride penetration between finished faces and the formwork surfaces of concrete beams and slabs. The results indicated that it is possible to use more slices of a single specimen for a chloride migration test. Moreover, it was demonstrated that there is a significant difference of chloride penetration between the finished surface and the formwork surface of the specimens. (C) 2008 Elsevier Ltd. All rights reserved.Polytechnic School of the University of Sao Paulo (POLI-USP)FAPESP (Research Support Foundation of the State of Sao Paulo

Adsorption of NO on the Rh-₁₃, Pd-₁₃, Ir-₁₃, and Pt-₁₃ Clusters: A Density Functional Theory Investigation

The adsorption of NO on transition-metal (TM) surfaces has been widely studied by experimental and theoretical techniques; however, our atomistic understanding of the interaction of nitrogen monoxide (NO) with small TM clusters is far from satisfactory, which compromises a deep understanding of real catalyst devices. In this study, we report a density functional theory study of the adsorption properties of NO on the TM13 (TM = Rh, Pd, Ir, Pt) clusters employing the projected augmented wave method. We found that the interaction of NO with TM13 is much more complex than that for NO/TM(111). In particular, for low symmetry TM13 clusters, there is a strong rearrangement of the electronic charge density upon NO adsorption and, as a consequence, the adsorption energy shows a very complex dependence even for adsorption sites with the same local effective coordination. We found a strong enhancement of the binding energy of NO to the TM13 clusters compared with the TM(111) surfaces, as the antibonding NO states are not occupied for NO/TM13, and the general relationship based on the d-band model between adsorption energy and the center of gravity of the occupied d-states does not hold for the studied TM13 clusters, in particular, for clusters with low symmetry. In contrast with the adsorption energy trends, the geometric NO/TM13 parameters and the vibrational N-O frequencies for different coordination sites follow the same trend as for the respective TM(111) surfaces, while the changes in the frequencies between different surfaces and TM13 clusters reflect the strong NO-TM13 interaction.Brazilian financial agency CNPqBrazilian financial agency CNPqBrazilian financial agency CAPESBrazilian financial agency CAPESSao Paulo Science Foundation (FAPESP)Sao Paulo Science Foundation (FAPESP