Novel memory-based sensory approach to assess large-scale typicality: the case of mainland Portugal red wines

Twenty professional wine experts were asked to describe their prototypical construct of a representative young red wine from each of the 12 Protected Geographical Indications (PGI) of mainland Portugal. No samples were assessed; the experiment was based on memory alone by completion of 12 extended self-reported sensory questionnaires. Four large-scale areas were differentiated, the typicality being statistically validated and described from a sensory standpoint. Alcohol, acidity, bitterness, and astringency were cross-linked; the respective variations were correlated with published literature and expressed as key factors for the regional macroscale area differentiation. Bitterness and astringency were found to be sensory different and related on a geographical scale, as bitterness was primarily affected by inland/coastal influence; while astringency confirmed its customary north/south dependence that finding is to be considered a new understanding. Moreover, with the proposed methodology, it was possible to achieve a novel nationwide sensory characterization of PGIs, overcoming present day limitations on macroscale sensory research and sample representativeness. Results by uncalibrated prototypical memory assessment of single PGI Beira Atlântico were compared with the outcome of calibrated wine sampling assessment by local experts, using the same sensory questionnaire, and were found significantly correlated. The need for a calibration stage was found uneven regarding the overall group of scrutinized wine descriptors

Omniscient foliations and the geometry of cosmological spacetimes

We identify certain general geometric conditions on a foliation of a spacetime (M,g) by timelike curves that will impede the existence of null geodesic lines, especially if (M,g) possesses a compact Cauchy hypersurface. The absence of such lines, in turn, yields well-known restrictions on the geometry of cosmological spacetimes, in the context of Bartnik's splitting conjecture. Since the (non)existence of null lines is actually a conformally invariant property, such conditions only need to apply for some suitable conformal rescaling of g.Comment: 19 pages, no figure

Unraveling the ferroelectric switching mechanisms in ferroelectric pure and La doped HfO(2 )epitaxial thin films

Epitaxial orthorhombic phase La doped HfO2 films are promising for achieving robust ferroelectric polarization without wake-up effect. However, lowering the coercive field is crucial for achieving low-power memory devices. In this work, we have investigated the influence of the La content effect on the structural and ferroelectric properties of epitaxial HfO2 thin films. We show that while the remanent polarization is optimum for 2-5 at. % La-doped HfO2 films, the coercive field is decreased with La doping. The experimental work is supported by density functional theory (DFT) calculations which show that the polarization switching in epitaxial La:HfO2 films can be understood based on the synergetic contribution of the presence of a non-ferroelectric monoclinic phase and the La doping itself that causes a reduction of the nucleation and DW motion energy barriers for the crossing path, which makes it more probable than the non-crossing one.Financial support from the Spanish Ministry of Science and Innova- tion (MCIN/AEI/10.13039/501100011033) , through the Severo Ochoa FUNFUTURE (CEX2019-000917-S) , PID2020-112548RB-I00 and PID2019-107727RB-I00 projects, and from Generalitat de Catalunya (2021 SGR 00804) is acknowledged. We also acknowledge project TED2021-130453B-C21, funded by MCIN/AEI/10.13039/501100011033 and European Union NextGeneration EU/PRTR. This work was supported by: (i) the Portuguese Foundation for Science and Technology (FCT) in the framework of the Strategic Funding Contract UIDB/04650/2020; (ii) exploratory project 2022.01740.PDTC and (iii) the European Unions Horizon 2020 research and innovation pro- gramme under grant agreement No 958174 (M-ERA-NET3/0003/2021-NanOx4EStor) . J. P. B. S. also thanks FCT for the contract under the Institutional Call to Scientific Employment Stimulus - 2021 Call (CEE- CINST/00018/2021) . A.S. also acknowledges FCT for the PhD grant with reference 2022.13796.BD

Dramatic reductions in water uptake observed in novel POSS nanocomposites based on anhydride-cured epoxy matrix resins

© 2015.A methylnadic anhydride-cured diglycidylether of bisphenol A, is prepared and characterised and a mono-epoxy POSS reagent added (0.5-4wt-%) to produce a series of nanocomposites. Two reaction mechanisms are observed involving esterification at lower temperatures (60-180°C) and etherification at temperatures above 180°C. Using the Ozawa and Kissinger methods, the activation energy for the first reaction was found to be 87-90kJ/mol and 122-124kJ/mol for the second reaction. Incorporation of POSS into the epoxy-anhydride network increases the Tg and cross-link density, indicating a more rigid network, but the values do not follow a trend based solely on POSS content. The char yield increases with POSS content with very little change in the degradation temperature. Incorporation of POSS (1wt-%) can reduce the moisture uptake in the cured resin by ~25% at 75% relative humidity. This is accompanied by a lower impact on glass transition temperature: the Tg is reduced by 10K at saturation, compared with 31K for the unmodified epoxy

A 2.4-GHz low-power/low-voltage wireless plug-and-play module for EEG applications

This paper presents a plug-and-play module for wireless electroencephalogram (EEG) applications. The wireless module is composed by an electrode, processing electronics, a radio-frequency (RF) transceiver, and an associated antenna. The RF transceiver was fabricated in the UMC RF 0.18 mum CMOS process, and operates in the 2.4-GHz ISM band. The receiver has a sensitivity of -60 dBm and a power consumption of 6.3 mW from a 1.8 V supply. The transmitter delivers an output power of 0 dBm with a power consumption of 11.2 mW, for a range of 10 m. It is also presented the electrical performance and comparison between different electrodes for EEG applications, namely sputtered titanium nitride (TiN) electrodes, standard sintered silver/silver chloride (Ag/AgCl) ring electrodes and sputtered iridium oxide (IrO2) electrodes. The experimental results show a better performance of the sputtered IrO2 electrodes compared with the standard sintered Ag/AgCl ring electrodes. These results promise a new opportunity for the application of a dry IrO2 electrodes in wireless modules for using in a wearable EEG braincap. These wireless EEG modules will allow patients to wear a brain cap and maintain their mobility, while simultaneously having their electrical brain activity monitored