205 research outputs found

    Mauste- ja rohdoskasvien raskasmetallit

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    Reactive laser interference patterning on titanium and zinc in high pressure CO2

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    Direct laser interference patterning (DLIP) is a versatile technique for surface patterning that enables formation of micro-nano sized periodic structures on top of the target material. In this study, DLIP in high pressure, supercritical and liquid CO2 by 4-beam DLIP was used to pattern titanium and zinc targets. Field emission scanning electron microscopy, atomic force microscopy, and X-ray photoelectron spectroscopy was used to characterize the patterned surfaces. Field emission SEM analysis showed presence of ordered uniform donut ring pattern with hollow centers for both titanium and zinc with a period slightly under 3 µm while topographical images from atomic force microscopy revealed donut rings protruding outwards typically around 200 nm from target surface and consisted of a crevice at the center with a depth typically around 300 nm and 250 nm for titanium and zinc target, respectively. Based on X-ray photoelectron spectroscopic analysis, this is the first study to report formation of TiO2, TiC, ZnCO3, and zinc hydroxy carbonate on the pattern by DLIP in supercritical and liquid CO2 for titanium and zinc targets. Pressurized CO2 is demonstrated as a promising environment with mirror-based DLIP system for reactive patterning. Due to the superior transport properties and solvent power of supercritical CO2, the current study opens possibilities for reactive patterning in environments that may not have been previously possible.publishedVersionPeer reviewe

    Childhood predictors of later psychiatric hospital treatment: findings from the Finnish 1981 birth cohort study

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    Psychiatric hospital treatment (PHT) is expensive and indicates a severe disorder. Investigation of the early identification of this small patient group has though been hindered by small samples or unsatisfactory assessment in childhood. The present study aims to study the predictive association between psychopathology at age 8 using multi-informant assessment and later PHT. A nationwide birth cohort of Finnish children (n = 5,346) was assessed at age 8 to obtain information about psychopathology using the Rutter parent and teacher reports and self-reports of depressive symptoms. The main outcome was admission to any hospital with a primary diagnosis of any psychiatric disorder according to the Finnish National Hospital Discharge Register between age 13 and 24. Between age 13 and 24, 6.2% of the males and 4.1% of the females had been admitted for PHT. Among males, PHT was independently predicted by non-intact family and adult reports of conduct and of emotional symptoms, while among females by self-reported depressive symptoms. However, the combination of conduct and emotional problems was the strongest predictor for PHT in both sexes. Admission due to psychosis among males was associated with childhood conduct, attention, and emotional problems, but with emotional problems among females. Psychopathology at age 8 can be seen as a long-lasting increased risk of severe psychiatric disorders requiring hospital treatment in adolescence or early adulthood. Attention should be paid to self-reports among females and of comorbid conduct and emotional problems in both sexes in the early identification of this patient group

    Average Finnish intake of nutrients and contaminants

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    Julkaisu myös suomenkielisenä: Suomalaisten keskimääräinen ravinto- ja vierasaineiden saanti. Suomalaisten elintarvikkeiden ravitsemuksellinen laatu ja kemiallinen turvallisuus. Toim. Jorma KumpulainenvokEK

    Johdanto ja yleiskuvaus

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    Julkaisu myös englanninkielisenä: Introduction and overview. Selected nutrients, natural antioxidants and chemical contaminants in Finnish food. Jorma Kumpulainen (Ed.)vokEK

    Ravintotutkijat koolla Helsingissä

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    Role of ARC/CL coded diet and food reference materials in the Central Laboratory's quality assurance system

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    Raskasmetallien saanti eri maissa

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