Effects of tunnelling and asymmetry for system-bath models of electron transfer

We apply the newly derived nonadiabatic golden-rule instanton theory to asymmetric models describing electron-transfer in solution. The models go beyond the usual spin-boson description and have anharmonic free-energy surfaces with different values for the reactant and product reorganization energies. The instanton method gives an excellent description of the behaviour of the rate constant with respect to asymmetry for the whole range studied. We derive a general formula for an asymmetric version of Marcus theory based on the classical limit of the instanton and find that this gives significant corrections to the standard Marcus theory. A scheme is given to compute this rate based only on equilibrium simulations. We also compare the rate constants obtained by the instanton method with its classical limit to study the effect of tunnelling and other quantum nuclear effects. These quantum effects can increase the rate constant by orders of magnitude.Comment: 10 pages, 3 figure

NEOShield kinetic impactor demonstration mission

This paper outlines a near-term mission concept developed under the NEOShield Project, for the demonstration of deflection capability of Potentially Hazardous Objects (PHOs). Potentially Hazardous Objects are a subclass of NEOs consisting mostly of asteroids (Potentially Hazardous Asteroids) that have the potential to make close approaches to the Earth whilst featuring a size large enough to cause significant regional damage in the event of an impact. It is currently (as of 2012) expected that only 20 - 30 percent of all existing PHOs are already known. This gives an indication that NEOs, in particular PHOs, are likely to pose a real threat to earth on a long time scale. Among the possible mitigation and deflection options, the mission outlined here seeks to demonstrate NEO deflection by means of a kinetic impactor. The main objectives of the mission are technology demonstration, deflection validation and beta-factor determination. This requires a mission that impacts a NEO in a representative velocity regime, allows measurement of the deflection sufficiently accurately to clearly demonstrate the momentum transfer by the impactor. The beta-factor quantifies the additional momentum transfer achieved through ejecta from the asteroid, which can be achieved both through accurate deflection measurement or ejecta observation, ideally through both. For the development of a fitting mission concept the NEOShield project performed a wide range of trade-offs while taking into consideration a variety of previously developed mission concepts such as Don Quijote

LTP interferometer - noise sources and performance

The LISA Technology Package (LTP) uses laser interferometry to measure the changes in relative displacement between two inertial test masses. The goals of the mission require a displacement measuring precision of 10 pm Hz-1/2 at frequencies in the 3–30 mHz band. We report on progress with a prototype LTP interferometer optical bench in which fused silica mirrors and beamsplitters are fixed to a ZERODUR® substrate using hydroxide catalysis bonding to form a rigid interferometer. The couplings to displacement noise of this interferometer of two expected noise sources—laser frequency noise and ambient temperature fluctuations—have been investigated, and an additional, unexpected, noise source has been identified. The additional noise is due to small amounts of signal at the heterodyne frequency arriving at the photodiode preamplifiers with a phase that quasistatically changes with respect to the optical signal. The phase shift is caused by differential changes in the external optical paths the beams travel before they reach the rigid interferometer. Two different external path length stabilization systems have been demonstrated and these allowed the performance of the overall system to meet the LTP displacement noise requirement

The Kondo Box: A Magnetic Impurity in an Ultrasmall Metallic Grain

We study the Kondo effect generated by a single magnetic impurity embedded in an ultrasmall metallic grain, to be called a ``Kondo box''. We find that the Kondo resonance is strongly affected when the mean level spacing in the grain becomes larger than the Kondo temperature, in a way that depends on the parity of the number of electrons on the grain. We show that the single-electron tunneling conductance through such a grain features Kondo-induced Fano-type resonances of measurable size, with an anomalous dependence on temperature and level spacing.Comment: 4 Latex pages, 4 figures, submitted to Phys. Rev. Let

Observing Quark-Gluon Plasma with Strange Hadrons

We review the methods and results obtained in an analysis of the experimental heavy ion collision research program at nuclear beam energy of 160-200A GeV. We study strange, and more generally, hadronic particle production experimental data. We discuss present expectations concerning how these observables will perform at other collision energies. We also present the dynamical theory of strangeness production and apply it to show that it agrees with available experimental results. We describe strange hadron production from the baryon-poor quark-gluon phase formed at much higher reaction energies, where the abundance of strange baryons and antibaryons exceeds that of nonstrange baryons and antibaryons.Comment: 39 journal pages (155kb text), 8 postscript figures, 8 table

Spatial variability of the physical attributes and the productivity in a distrophic Latosolo of Cascavel - PR, region

Through geostatistics techniques, contour maps, were produced by interpolation using ordinary kriging, representing the spatial variability of the physical attributes; soil density [kg dm-3], soil water [g g-1] and penetration resistance [MPa] in the 0-10, 10-20 and 20-30 cm of depth, besides the soy bean productivity [t ha-1]. Soil attributes and yield data, derived from an unaligned stratified systematic sampling scheme, subdivided in portions with localized management (CML) and without localized management (SML) for the agricultural year 1998/99. The productivity maps in general presented a similar variability standard for the distribution in the non responding area as well as in the area with different chemical treatments applied in the CML plots. Where as the physical attributes presented a similar behavior for the two methods of management. Amongst the physical attributes studied, the penetration resistance in the 0-10 cm of depth was the variable which was best correlated with the productivity.Através de técnicas de geoestatística foram confeccionados mapas de contorno, produzidos por interpolação através da krigagem ordinária representando, desta forma, a variabilidade espacial dos atributos físicos densidade do solo [kg dm-3], teor de água do solo [g g-1] e resistência mecânica a penetração [MPa] nas camadas de 0-10,10-20 e 20-30 cm de profundidade, além da produtividade de soja [t ha-1]. Os atributos do solo e a produtividade se derivaram de um plano de amostragem estratificada sistemática desalinhada, do ano agrícola 1998/99, subdividido em parcelas sem manejo localizado (SML) e parcelas com manejo localizado (CML). De maneira geral, os mapas de produtividade apresentaram um padrão de variabilidade semelhante quanto à distribuição na área não respondendo, assim, ao tratamento químico diferenciado aplicado nas parcelas CML; já os atributos físicos mostraram comportamento semelhante para os dois métodos de cultivo. Dentre os atributos físicos estudados, a resistência à penetração na camada 0-10 cm de profundidade foi a variável que melhor se correlacionou com a produtividade.21221

Pinning quantum phase transition for a Luttinger liquid of strongly interacting bosons

One of the most remarkable results of quantum mechanics is the fact that many-body quantum systems may exhibit phase transitions even at zero temperature. Quantum fluctuations, deeply rooted in Heisenberg's uncertainty principle, and not thermal fluctuations, drive the system from one phase to another. Typically, the relative strength of two competing terms in the system's Hamiltonian is changed across a finite critical value. A well-known example is the Mott-Hubbard quantum phase transition from a superfluid to an insulating phase, which has been observed for weakly interacting bosonic atomic gases. However, for strongly interacting quantum systems confined to lower-dimensional geometry a novel type of quantum phase transition may be induced for which an arbitrarily weak perturbation to the Hamiltonian is sufficient to drive the transition. Here, for a one-dimensional (1D) quantum gas of bosonic caesium atoms with tunable interactions, we observe the commensurate-incommensurate quantum phase transition from a superfluid Luttinger liquid to a Mott-insulator. For sufficiently strong interactions, the transition is induced by adding an arbitrarily weak optical lattice commensurate with the atomic granularity, which leads to immediate pinning of the atoms. We map out the phase diagram and find that our measurements in the strongly interacting regime agree well with a quantum field description based on the exactly solvable sine-Gordon model. We trace the phase boundary all the way to the weakly interacting regime where we find good agreement with the predictions of the 1D Bose-Hubbard model. Our results open up the experimental study of quantum phase transitions, criticality, and transport phenomena beyond Hubbard-type models in the context of ultracold gases

A Mission to Explore the Pioneer Anomaly

The Pioneer 10 and 11 spacecraft yielded the most precise navigation in deep space to date. These spacecraft had exceptional acceleration sensitivity. However, analysis of their radio-metric tracking data has consistently indicated that at heliocentric distances of $\sim 20-70$ astronomical units, the orbit determinations indicated the presence of a small, anomalous, Doppler frequency drift. The drift is a blue-shift, uniformly changing with a rate of $\sim(5.99 \pm 0.01)\times 10^{-9}$ Hz/s, which can be interpreted as a constant sunward acceleration of each particular spacecraft of $a_P = (8.74 \pm 1.33)\times 10^{-10} {\rm m/s^2}$. This signal has become known as the Pioneer anomaly. The inability to explain the anomalous behavior of the Pioneers with conventional physics has contributed to growing discussion about its origin. There is now an increasing number of proposals that attempt to explain the anomaly outside conventional physics. This progress emphasizes the need for a new experiment to explore the detected signal. Furthermore, the recent extensive efforts led to the conclusion that only a dedicated experiment could ultimately determine the nature of the found signal. We discuss the Pioneer anomaly and present the next steps towards an understanding of its origin. We specifically focus on the development of a mission to explore the Pioneer Anomaly in a dedicated experiment conducted in deep space.Comment: 8 pages, 9 figures; invited talk given at the 2005 ESLAB Symposium "Trends in Space Science and Cosmic Vision 2020", 19-21 April 2005, ESTEC, Noordwijk, The Netherland

Fundamental Physics with the Laser Astrometric Test Of Relativity

The Laser Astrometric Test Of Relativity (LATOR) is a joint European-U.S. Michelson-Morley-type experiment designed to test the pure tensor metric nature of gravitation - a fundamental postulate of Einstein's theory of general relativity. By using a combination of independent time-series of highly accurate gravitational deflection of light in the immediate proximity to the Sun, along with measurements of the Shapiro time delay on interplanetary scales (to a precision respectively better than 0.1 picoradians and 1 cm), LATOR will significantly improve our knowledge of relativistic gravity. The primary mission objective is to i) measure the key post-Newtonian Eddington parameter \gamma with accuracy of a part in 10^9. (1-\gamma) is a direct measure for presence of a new interaction in gravitational theory, and, in its search, LATOR goes a factor 30,000 beyond the present best result, Cassini's 2003 test. The mission will also provide: ii) first measurement of gravity's non-linear effects on light to ~0.01% accuracy; including both the Eddington \beta parameter and also the spatial metric's 2nd order potential contribution (never measured before); iii) direct measurement of the solar quadrupole moment J2 (currently unavailable) to accuracy of a part in 200 of its expected size; iv) direct measurement of the "frame-dragging" effect on light by the Sun's gravitomagnetic field, to 1% accuracy. LATOR's primary measurement pushes to unprecedented accuracy the search for cosmologically relevant scalar-tensor theories of gravity by looking for a remnant scalar field in today's solar system. We discuss the mission design of this proposed experiment.Comment: 8 pages, 9 figures; invited talk given at the 2005 ESLAB Symposium "Trends in Space Science and Cosmic Vision 2020," 19-21 April 2005, ESTEC, Noodrwijk, The Netherland

LISA pathfinder optical interferometry

The LISA Technology Package (LTP) aboard of LISA pathfinder mission is dedicated to demonstrate and verify key technologies for LISA, in particular drag free control, ultra-precise laser interferometry and gravitational sensor. Two inertial sensor, the optical interferometry in between combined with the dimensional stable Glass ceramic Zerodur structure are setting up the LTP. The validation of drag free operation of the spacecraft is planned by measuring laser interferometrically the relative displacement and tilt between two test masses (and the optical bench) with a noise levels of 10pm/[square root of]Hz and 10 nrad/[square root of]Hz between 3mHz and 30mHz. This performance and additionally overall environmental tests was currently verified on EM level. The OB structure is able to support two inertial sensors ([approximate]17kg each) and to withstand 25 g design loads as well as 0...40°C temperature range. Optical functionality was verified successfully after environmental tests. The engineering model development and manufacturing of the optical bench and interferometry hardware and their verification tests will be presented