Controlled formation and disappearance of creases

Soft, elastic materials are capable of large and reversible deformation, readily leading to various modes of instability that are often undesirable, but sometimes useful. For example, when a soft elastic material is compressed, its initially flat surface will suddenly form creases. While creases are commonly observed, and have been exploited to control chemical patterning, enzymatic activity, and adhesion of surfaces, the conditions for the formation and disappearance of creases have so far been poorly controlled. Here we show that a soft elastic bilayer can snap between the flat and creased states repeatedly, with hysteresis. The strains at which the creases form and disappear are highly reproducible, and are tunable over a large range, through variations in the level of pre-compression applied to the substrate and the relative thickness of the film. The introduction of bistable flat and creased states and hysteretic switching is an important step to enable applications of this type of instability.Engineering and Applied Science

The role of substrate pre-stretch in post-wrinkling bifurcations

When a stiff film on a soft substrate is compressed, the surface of the film forms wrinkles, with tunable wavelengths and amplitudes that enable a variety of applications. As the compressive strain increases, the film undergoes post-wrinkling bifurcations, leading to period doubling and eventually to formation of localized folds or ridges. Here we study the post-wrinkling bifurcations in films on pre-stretched substrates. Through a combination of experiments and simulations, we demonstrate that pre-stretched substrates not only show substantial shifts in the critical strain for the onset of post-wrinkling bifurcations, but also exhibit qualitatively different post-wrinkled states. In particular, we report on the stabilization of wrinkles in films on pre-tensioned substrates and the emergence of ‘chaotic’ morphologies in films on pre-compressed substrates.Engineering and Applied Science

Evidence of paracrystalline cation order in the Ruddlesden-Popper phase LaSr3NiRuO8 through total scattering techniques

Cation ordering in perovskite-derived phases can lead to a wealth of tunable physical properties. Ordering is typically driven by a large difference between the cation size and charge, but many Ruddlesden–Popper phases An+1BnO3n+1 appear to lack such B-site ordering, even when these differences are present. One such example is the “double” Ruddlesden–Popper n = 1 composition LaSr3NiRuO8. In this material, a lack of B-site ordering is observed through traditional crystallographic techniques, but antiferromagnetic ordering in the magnetism data suggests that B-site cation ordering is indeed present. Neutron total scattering, particularly analysis of the neutron pair distribution function, reveals that the structure is locally B-site-ordered below 6 Å but becomes slightly disordered in the midrange structure around 12 Å. This provides evidence for paracrystalline order in this material: cation ordering within a single perovskite sheet that lacks perfect registry within the three-dimensional stack of sheets. This work highlights the importance of employing a structural technique that can probe both the local and midrange order in addition to the crystallographic structure and provides a structural origin to the observed magnetic properties of LaSr3NiRuO8. Further, it is proposed that paracrystalline order is likely to be common among these layered-type oxides

Blueprinting Photothermal Shape-Morphing of Liquid Crystal Elastomers

Liquid crystal elastomers (LCEs) are an attractive platform for dynamic shape‐morphing due to their ability to rapidly undergo large deformations. While recent work has focused on patterning the director orientation field to achieve desired target shapes, this strategy cannot be generalized to material systems where high‐resolution surface alignment is impractical. Instead of programming the local orientation of anisotropic deformation, an alternative strategy for prescribed shape‐morphing by programming the magnitude of stretch ratio in a thin LCE sheet with constant director orientation is developed here. By spatially patterning the concentration of gold nanoparticles, uniform illumination leads to gradients in photothermal heat generation and therefore spatially nonuniform deformation profiles that drive out‐of‐plane buckling of planar films into predictable 3D shapes. Experimentally realized shapes are shown to agree closely with both finite element simulations and geometric predictions for systems with unidirectional variation in deformation magnitude. Finally, the possibility to achieve complex oscillatory motion driven by uniform illumination of a free‐standing patterned sheet is demonstrated

Creases on the interface between two soft materials

Theory and experiment are presented to show that an interface between two soft materials under compression can form creases, a type of bifurcation distinct from wrinkles. While creases bifurcate from a state of flat interface by a deformation localized in space and large in amplitude, wrinkles bifurcate from a state of flat interface by a deformation nonlocal in space and infinitesimal in amplitude. The interfacial creases set in at a lower critical compression than interfacial wrinkles, but higher than surface creases. The condition for the onset of interfacial creases is scale-free, and is calculated in terms of elastic moduli, pre-strains and applied strains.Engineering and Applied Science

Post-wrinkle bifurcations in elastic bilayers with modest contrast in modulus

Wrinkles, folds, creases and other elastic surface instabilities play a crucial role in many systems in nature and engineering. While surface instabilities of ideal bilayer structures with large contrasts in elastic stiffness are well understood, many natural and man-made structures are far from this ideal. To better understand the behavior of systems with modest stiffness contrast, in particular their secondary post-wrinkling bifurcations, we systematically vary the modulus contrast between the film and the substrate through a combination of experiments and finite element simulations. Above a modulus contrast of about 2, but below approximately 14, wrinkles represent the primary bifurcation mode, but can undergo two distinct types of secondary bifurcations upon further compression: (1) a direct transition from wrinkles to creases, and (2) wrinkles that first undergo period doubling, followed by a transition to creases.Engineering and Applied Science

Under-Ice Light Field in the Western Arctic Ocean During Late Summer

The Arctic is no longer a region dominated by thick multi-year ice (MYI), but by thinner, more dynamic, first-year-ice (FYI). This shift towards a seasonal ice cover has consequences for the under-ice light field, as sea-ice and its snow cover are a major factor influencing radiative transfer and thus, biological activity within- and under the ice. This work describes in situ measurements of light transmission through different types of sea-ice (MYI and FYI) performed during two expeditions to the Chukchi sea in August 2018 and 2019, as well as a simple characterisation of the biological state of the ice microbial system. Our analysis shows that, in late summer, two different states of FYI exist in this region: 1) FYI in an enhanced state of decay, and 2) robust FYI, more likely to survive the melt season. The two FYI types have different average ice thicknesses: 0.74 ± 0.07 m (N = 9) and 0.93 ± 0.11 m (N = 9), different average values of transmittance: 0.15 ± 0.04 compared to 0.09 ± 0.02, and different ice extinction coefficients: 1.49 ± 0.28 and 1.12 ± 0.19 m−1. The measurements performed over MYI present different characteristics with a higher average ice thickness of 1.56 ± 0.12 m, lower transmittance (0.05 ± 0.01) with ice extinction coefficients of 1.24 ± 0.26 m−1 (N = 12). All ice types show consistently low salinity, chlorophyll a concentrations and nutrients, which may be linked to the timing of the measurements and the flushing of melt-water through the ice. With continued Arctic warming, the summer ice will continue to retreat, and the decayed variant of FYI, with a higher scattering of light, but a reduced thickness, leading to an overall higher light transmittance, may become a more relevant ice type. Our results suggest that in this scenario, more light would reach the ice interior and the upper-ocean

ALMA Imaging of HCN, CS and dust in Arp 220 and NGC 6240

We report ALMA Band 7 (350 GHz) imaging at 0.4 - 0.6arcsec resolution and Band 9 (696 GHz) at ~0.25arcsec resolution of the luminous IR galaxies Arp 220 and NGC 6240. The long wavelength dust continuum is used to estimate ISM masses for Arp 220 East, West and NGC 6240 of 1.9, 4.2 and 1.6x10^9 msun within radii of 69, 65 and 190 pc. The HCN emission was modeled to derive the emissivity distribution as a function of radius and the kinematics of each nuclear disk, yielding dynamical masses consistent with the masses and sizes derived from the dust emission. In Arp 220, the major dust and gas concentrations are at radii less than 50 pc in both counter-rotating nuclear disks. The thickness of the disks in Arp 220estimated from the velocity dispersion and rotation velocities are 10-20 pc and the mean gas densities are n_H2 ~10^5 cm^-3 at R < 50 pc. We develop an analytic treatment for the molecular excitation (including photon trapping), yielding volume densities for both the HCN and CS emission with n_H2 ~2x10^5 cm^-3. The agreement of the mean density from the total mass and size with that required for excitation suggests that the volume is essentially filled with dense gas, i.e. it is not cloudy or like swiss cheese