A regioselectivity switch in Pd-catalyzed hydroallylation of alkynes.

By exploiting the reactivity of a vinyl-Pd species, we control the regioselectivity in hydroallylation of alkynes under Pd-hydride catalysis. A monophosphine ligand and carboxylic acid combination promotes 1,5-dienes through a pathway involving isomerization of alkynes to allenes. In contrast, a bisphosphine ligand and copper cocatalyst favor 1,4-dienes via a mechanism that involves transmetalation. Our study highlights how to access different isomers by diverting a common organometallic intermediate

Remedial brushless AC operation of fault-tolerant doubly salient permanent-magnet motor drives

The doubly salient permanent-magnet (DSPM) machine is a new class of stator-PM brushless machines, which inherently offers the fault-tolerant feature. In this paper, a new operation strategy is proposed and implemented for fault-tolerant DSPM motor drives. The key is to operate the DSPM motor drive in a remedial brushless ac (BLAC) mode under the open-circuit fault condition, while operating in the conventional brushless dc mode under normal condition. Both cosimulation and experimental results confirm that the proposed remedial BLAC operation can maintain the average torque, reduce the torque ripple, and retain the self-starting capability under the open-circuit fault. © 2006 IEEE.published_or_final_versio

Remedial injected harmonic current operation of redundant flux-switching permanent magnet motor drives

published_or_final_versio

The Online Data Quality Monitoring System at BESIII

The online Data Quality Monitoring (DQM) plays an important role in the data taking process of HEP experiments. BESIII DQM samples data from online data flow, reconstructs them with offline reconstruction software, and automatically analyzes the reconstructed data with user-defined algorithms. The DQM software is a scalable distributed system. The monitored results are gathered and displayed in various formats, which provides the shifter with current run information that can be used to find problems early. This paper gives an overview of DQM system at BESIII.Comment: Already submit to Chinese Physics

Stator-flux-oriented fault-tolerant control of flux-switching permanent-magnet motors

Flux-switching permanent-magnet (FSPM) motors are a newly developed brushless AC (BLAC) machine having magnets in the stator. This paper proposes and implements a stator-flux-oriented (SFO) control strategy for fault-tolerant operation of FSPM motors. The key is to set the q-axis component of armature current invariant before and after the fault. In the rotor reference frame, by building a SFO-dq equation of the FSPM motor, the fault-tolerant control strategy is deduced. The finite-element method and the field-circuit cosimulation method are employed to analyze the performance of the FSPM motor drive. Finally, a dSPACE-based FSPM motor drive platform is built for experimental verification. Both the steady-state and dynamic performances at normal and fault-tolerant operations are tested, confirming that the proposed fault-tolerant operation can keep the output torque invariant while offering good dynamic performance during fault. © 2011 IEEE.published_or_final_versionThe IEEE International Magnetic Conference (INTERMAG2011), Taipei, Taiwan, 25-29 April 2011. In IEEE Transactions on Magnetics, 2011, v. 47 n. 10, p. 4191-419

Diagnostic value of two dimensional shear wave elastography combined with texture analysis in early liver fibrosis.

BACKGROUND: Staging diagnosis of liver fibrosis is a prerequisite for timely diagnosis and therapy in patients with chronic hepatitis B. In recent years, ultrasound elastography has become an important method for clinical noninvasive assessment of liver fibrosis stage, but its diagnostic value for early liver fibrosis still needs to be further improved. In this study, the texture analysis was carried out on the basis of two dimensional shear wave elastography (2D-SWE), and the feasibility of 2D-SWE plus texture analysis in the diagnosis of early liver fibrosis was discussed. AIM: To assess the diagnostic value of 2D-SWE combined with textural analysis in liver fibrosis staging. METHODS: This study recruited 46 patients with chronic hepatitis B. Patients underwent 2D-SWE and texture analysis; Young\u27s modulus values and textural patterns were obtained, respectively. Textural pattern was analyzed with regard to contrast, correlation, angular second moment (ASM), and homogeneity. Pathological results of biopsy specimens were the gold standard; comparison and assessment of the diagnosis efficiency were conducted for 2D-SWE, texture analysis and their combination. RESULTS: 2D-SWE displayed diagnosis efficiency in early fibrosis, significant fibrosis, severe fibrosis, and early cirrhosis (AUC \u3e 0.7, P \u3c 0.05) with respective AUC values of 0.823 (0.678-0.921), 0.808 (0.662-0.911), 0.920 (0.798-0.980), and 0.855 (0.716-0.943). Contrast and homogeneity displayed independent diagnosis efficiency in liver fibrosis stage (AUC \u3e 0.7, P \u3c 0.05), whereas correlation and ASM showed limited values. AUC of contrast and homogeneity were respectively 0.906 (0.779-0.973), 0.835 (0.693-0.930), 0.807 (0.660-0.910) and 0.925 (0.805-0.983), 0.789 (0.639-0.897), 0.736 (0.582-0.858), 0.705 (0.549-0.883) and 0.798 (0.650-0.904) in four liver fibrosis stages, which exhibited equivalence to 2D-SWE in diagnostic efficiency (P \u3e 0.05). Combined diagnosis (PRE) displayed diagnostic efficiency (AUC \u3e 0.7, P \u3c 0.01) for all fibrosis stages with respective AUC of 0.952 (0.841-0.994), 0.896 (0.766-0.967), 0.978 (0.881-0.999), 0.947 (0.835-0.992). The combined diagnosis showed higher diagnosis efficiency over 2D-SWE in early liver fibrosis (P \u3c 0.05), whereas no significant differences were observed in other comparisons (P \u3e 0.05). CONCLUSION: Texture analysis was capable of diagnosing liver fibrosis stage, combined diagnosis had obvious advantages in early liver fibrosis, liver fibrosis stage might be related to the hepatic tissue hardness distribution

Axial exchange currents and nucleon spin

We calculate the hypercharge and flavor singlet axial couplings related to the spin of the nucleon in a constituent quark model. In addition to the standard one-body axial currents, the model includes two-body axial exchange currents. The latter are necessary to satisfy the Partial Conservation of Axial Current (PCAC) condition. For both axial couplings we find significant corrections to the standard quark model prediction. Exchange currents reduce the valence quark contribution to the nucleon spin and afford an interpretation of the missing nucleon spin as orbital angular momentum carried by nonvalence quark degrees of freedom.Comment: 14 pages, 1 figur

Biaxial deformation of collagen and elastin fibers in coronary adventitia

The microstructural deformation-mechanical loading relation of the blood vessel wall is essential for understanding the overall mechanical behavior of vascular tissue in health and disease. We employed simultaneous mechanical loading-imaging to quantify in situ deformation of individual collagen and elastin fibers on unstained fresh porcine coronary adventitia under a combination of vessel inflation and axial extension loading. Specifically, the specimens were imaged under biaxial loads to study microscopic deformation-loading behavior of fibers in conjunction with morphometric measurements at the zero-stress state. Collagen fibers largely orientate in the longitudinal direction, while elastin fibers have major orientation parallel to collagen, but with additional orientation angles in each sublayer of the adventitia. With an increase of biaxial load, collagen fibers were uniformly stretched to the loading direction, while elastin fibers gradually formed a network in sublayers, which strongly depended on the initial arrangement. The waviness of collagen decreased more rapidly at a circumferential stretch ratio of λθ = 1.0 than at λθ = 1.5, while most collagen became straightened at λθ = 1.8. These microscopic deformations imply that the longitudinally stiffer adventitia is a direct result of initial fiber alignment, and the overall mechanical behavior of the tissue is highly dependent on the corresponding microscopic deformation of fibers. The microstructural deformation-loading relation will serve as a foundation for micromechanical models of the vessel wall