Subtle but significant effects of CO<inf>2</inf> acidified seawater on embryos of the intertidal snail, Littorina obtusata

Our understanding of the effects of ocean acidification on whole organism function is growing, but most current information is for adult stages of development. Here, we show the effects of reduced pH seawater (pH 7.6) on aspects of the development, physiology and behaviour of encapsulated embryos of the marine intertidal gastropod Littorina obtusata. We found reduced viability and increased development times under reduced pH conditions, and the embryos had significantly altered behaviours and physiologies. In acidified seawater, embryos spent more time stationary, had slower rotation rates, spent less time crawling, but increased their movement periodicity compared with those maintained under control conditions. Larval and adult heart rates were significantly lower in acidified seawater, and hatchling snails had an altered shell morphology (lateral length and spiral shell length) compared to control snails. Our findings show that ocean acidification may have multiple, subtle effects during the early development of marine animals that may have implications for their survival beyond those predicted using later life stages. © Inter-Research 2009

Effect of nickel on the microstructure and mechanical property of die-cast Al–Mg–Si–Mn alloy

The effect of nickel on the microstructure and mechanical properties of a die-cast Al–Mg–Si–Mn alloy has been investigated. The results show that the presence of Ni in the alloy promotes the formation of Ni-rich intermetallics. These occur consistently during solidification in the die-cast Al–Mg–Si–Mn alloy across different levels of Ni content. The Ni-rich intermetallics exhibit dendritic morphology during the primary solidification and lamellar morphology during the eutectic solidification stage. Ni was found to be always associated with iron forming AlFeMnSiNi intermetallics, and no Al3Ni intermetallic was observed when Ni concentrations were up to 2.06 wt% in the alloy. Although with different morphologies, the Ni-rich intermetallics were identified as the same AlFeMnSiNi phase bearing a typical composition of Al[100–140](Fe,Mn)[2–7]SiNi[4–9]. With increasing Ni content, the spacing of the α-Al–Mg2Si eutectic phase was enlarged in the Al–Mg–Si–Mn alloy. The addition of Ni to the alloy resulted in a slight increase in the yield strength, but a significant decrease in the elongation. The ultimate tensile strength (UTS) increased slightly from 300 to 320 MPa when a small amount (e.g. 0.16 wt%) of Ni was added to the alloy, but further increase of the Ni content resulted in a decrease of the UTS.The Engineering and Physical Sciences Research Council (EPSRC), Technology Strategy Board (TSB) and Jaguar Land Rover (JLR) in the United Kingdom

Draft genome sequence of Kocuria sp. strain UCD-OTCP (phylum Actinobacteria)

© 2013 Coil et al. Here, we present the draft genome of Kocuria sp. strain UCD-OTCP, a member of the phylum Actinobacteria, isolated from a restaurant chair cushion. The assembly contains 3,791,485 bp (G+C content of 73%) and is contained in 68 scaffolds

Sobre la presencia de Sauropoda (Dinosauria) en la Formación Mirambel (Barremiense inferior, Teruel, España).

El registro fósil de dinosaurios de la Formación Mirambel (Barremiense, Teruel, España) es relativamente escaso. Hasta el momento se ha citado la presencia de ornitópodos iguanodontios y tero´podos tetanuros basales. En este trabajo se documenta por primera vez la presencia de sauro´podos en esta unidad. Son restos postcraneales fragmentarios encontrados en diferentes yacimientos. En su conjunto presentan caracteres diagnósticos que permite interpretar la presencia de uno o más taxones de Titanosauriformes, que podrían estar incluidos en Somphospondyli, pero en ningún caso en Titanosauria. he fossil record of dinosaurs from the Mirambel Formation (Barremian, Teruel province, Spain) is relatively scarce, being cited the presence of iguan- odontian ornithopods and basal tetanuran theropods until now. In this paper, we document the presence of sauropods in this unit for the first time. They are fragmentary postcranial remains found in different fossil localities. Taken together, they present diagnostic characters for documenting the presence of one or more taxa within Titanosauriformes, which could be Somphospondyli, but in any case can be included within Titanosauria

An overview of the lower cretaceous dinosaur tracksites from the mirambel formation in the iberian range (ne spain)

Up to now, the ichnological vertebrate record from the Barremian Mirambel Formation (NE Spain) has remained completely unknown despite the fact that osteological findings have been reported in recent years. Here we provide an overview of 11 new dinosaur tracksites found during a fieldwork campaign in the year 2011. The majority of these tracksites (seven) preserve small- to medium-sized tridactyl tracks here assigned to indeterminate theropods. Only one footprint presents enough characters to classify it as Megalosauripus isp. Ornithopod tracks identified as Caririchnium isp. and Iguanodontipodidae indet. and sauropod tracks are recorded at two tracksites. The footprints are preserved in a variety of paleoenvironmental conditions and thus display different kinds of preservation (true tracks, shallow undertracks, natural casts and undertrack casts). The ichnological record from the Mirambel Formation seems to be theropod dominated. This is a clear discrepancy with the osteological record identified in this formation, which shows a predominance of ornithopod dinosaurs

High Performance Electrocatalysts Based on Pt Nanoarchitecture for Fuel Cell Applications

Fuel cells, converting chemical energy from fuels into electricity directly without the need for combustion, are promising energy conversion devices for their potential applications as environmentally friendly, energy efficient power sources. However, to take fuel cell technology forward towards commercialization, we need to achieve further improvements in electrocatalyst technology, which can play an extremely important role in essentially determining cost-effectiveness, performance, and durability. In particular, platinum- (Pt-) based electrocatalyst approaches have been extensively investigated and actively pursued to meet those demands as an ideal fuel cell catalyst due to their most outstanding activity for both cathode oxygen reduction reactions and anode fuel oxidation reactions. In this review, we will address important issues and recent progress in the development of Pt-based catalysts, their synthesis, and characterization. We will also review snapshots of research that are focused on essential dynamics aspects of electrocatalytic reactions, such as the shape effects on the catalytic activity of Pt-based nanostructures, the relationships between structural morphology of Pt-based nanostructures and electrochemical reactions on both cathode and anode electrodes, and the effects of composition and electronic structure of Pt-based catalysts on electrochemical reaction properties of fuel cells.</jats:p

Narrowing the Range of Future Climate Projections Using Historical Observations of Atmospheric CO2

This is the final version. Available from American Meteorological Society via the DOI in this recordUncertainty in the behavior of the carbon cycle is important in driving the range in future projected climate change. Previous comparisons of model responses with historical CO2 observations have suggested a strong constraint on simulated projections that could narrow the range considered plausible. This study uses a new 57-member perturbed parameter ensemble of variants of an Earth system model for three future scenarios, which 1) explores a wider range of potential climate responses than before and 2) includes the impact of past uncertainty in carbon emissions on simulated trends. These two factors represent a more complete exploration of uncertainty, although they lead to a weaker constraint on the range of future CO2 concentrations as compared to earlier studies. Nevertheless, CO2 observations are shown to be effective at narrowing the distribution, excluding 30 of 57 simulations as inconsistent with historical CO2 changes. The perturbed model variants excluded are mainly at the high end of the future projected CO2 changes, with only 8 of the 26 variants projecting RCP8.5 2100 concentrations in excess of 1100 ppm retained. Interestingly, a minority of the high-end variants were able to capture historical CO2 trends, with the large-magnitude response emerging later in the century (owing to high climate sensitivities, strong carbon feedbacks, or both). Comparison with observed CO2 is effective at narrowing both the range and distribution of projections out to the mid-twenty-first century for all scenarios and to 2100 for a scenario with low emissions.This work was supported by the Joint U.K. DECC/DEFRA Met Office Hadley Centre Climate Programme (GA01101). Chris Jones’s contribution was supported by the CRESCENDO project under the European Union's Horizon 2020 research and innovation programme, Grant Agreement 641816. Jo House was supported by a Leverhulme Early Career Fellowship and EU FP7 Project LUC4C (603542). Stephen Sitch was supported by the EU FP7 through Project LUC4C (GA603542)

Inorganic-ligand exchanging time effect in PbS quantum dot solar cell

We investigate time-dependent inorganic ligand exchanging effect and photovoltaic performance of lead sulfide (PbS) nanocrystal films. With optimal processing time, volume shrinkage induced by residual oleic acid of the PbS colloidal quantum dot (CQD) was minimized and a crack-free film was obtained with improved flatness. Furthermore, sufficient surface passivation significantly increased the packing density by replacing from long oleic acid to a short iodide molecule. It thus facilities exciton dissociation via enhanced charge carrier transport in PbS CQD films, resulting in the improved power conversion efficiency from 3.39% to 6.62%. We also found that excess iodine ions on the PbS surface rather hinder high photovoltaic performance of the CQD solar cell

Lignin biomarkers as tracers of mercury sources in lakes water column

This study presents the role of specific terrigenous organic compounds as important vectors of mercury (Hg) transported from watersheds to lakes of the Canadian boreal forest. In order to differentiate the autochthonous from the allochthonous organic matter (OM), lignin derived biomarker signatures [Lambda, S/V, C/V, P/(V ? S), 3,5-Bd/V and (Ad/Al)v] were used. Since lignin is exclusively produced by terrigenous plants, this approach can give a non equivocal picture of the watershed inputs to the lakes. Moreover, it allows a characterization of the source of OM and its state of degradation. The water column of six lakes from the Canadian Shield was sampled monthly between June and September 2005. Lake total dissolved Hg concentrations and Lambda were positively correlated, meaning that Hg and ligneous inputs are linked (dissolved OM r2 = 0.62, p\0.0001; particulate OM r2 = 0.76, p\0.0001). Ratios of P/(V ? S) and 3,5-Bd/V from both dissolved OM and particulate OM of the water column suggest an inverse relationship between the progressive state of pedogenesis and maturation of the OM in soil before entering the lake, and the Hg concentrations in the water column. No relation was found between Hg levels in the lakes and the watershed flora composition—angiosperm versus gymnosperm or woody versus non-woody compounds. This study has significant implications for watershed management of ecosystems since limiting fresh terrestrial OM inputs should reduce Hg inputs to the aquatic systems. This is particularly the case for largescale land-use impacts, such as deforestation, agriculture and urbanization, associated to large quantities of soil OM being transferred to aquatic systems