Nitrogen atom detection in low-pressure flames by two-photon laser-excited fluorescence

Bittner J, Lawitzki A, Meier U, Kohse-Höinghaus K. Nitrogen atom detection in low-pressure flames by two-photon laser-excited fluorescence. Applied Physics, B. 1991;52(2):108-116.Nitrogen atoms have been detected in stoichiometric flat premixed H2/O2/N2 flames at 33 and 96 mbar doped with small amounts of NH3, HCN, and (CN)2 using two-photon laser excitation at 211 nm and fluorescence detection around 870 nm. The shape of the fluorescence intensity profiles versus height above the burner surface is markedly different for the different additives. Using measured quenching rate coefficients and calibrating with the aid of known N-atom concentrations in a discharge flow reactor, peak N-atom concentrations in these flames are estimated to be on the order of 10 12–5×10 13 cm –3; the detection limit is about 1×10 11 cm –3

Pathways to sex-based differentiation in criminal court sentencing

Using a matched sampling method, this research examined the process of sex-based differentiation in sentencing outcomes for 194 men and 194 women, sentenced over a seven-year period in Christchurch, New Zealand. Consistent with past research, our results showed that judicial processing treated women more leniently than men. Path analyses revealed that judges were less likely to sentence women than men to imprisonment terms because of gendered information and decisions made earlier in the judicial process, such as criminal history, length of custodial remands, and pre-sentence recommendations by probation officers. In contrast, judges exercised considerable leniency towards women (compared with men) in setting the length of prison terms, even after statistically controlling for all sex-differentiated factors such as criminal history. Explanations and implications are discussed

Assessing trend and variation of Arctic sea-ice extent during 1979–2012 from a latitude perspective of ice edge

Arctic sea-ice extent (in summer) has been shrinking since the 1970s. However, we have little knowledge of the detailed spatial variability of this shrinking. In this study, we examine the (latitudinal) ice extent along each degree of longitude, using the monthly Arctic ice index data sets (1979–2012) from the National Snow and Ice Data Center. Statistical analysis suggests that: (1) for summer months (July–October), there was a 34-year declining trend in sea-ice extent at most regions, except for the Canadian Arctic Archipelago, Greenland and Svalbard, with retreat rates of 0.0562–0.0898 latitude degree/year (or 6.26–10.00 km/year, at a significance level of 0.05); (2) for sea ice not geographically muted by the continental coastline in winter months (January–April), there was a declining trend of 0.0216–0.0559 latitude degree/year (2.40–6.22 km/year, at a significance level of 0.05). Regionally, the most evident sea-ice decline occurred in the Chukchi Sea from August to October, Baffin Bay and Greenland Sea from January to May, Barents Sea in most months, Kara Sea from July to August and Laptev Sea and eastern Siberian Sea in August and September. Trend analysis also indicates that: (1) the decline in summer ice extent became significant (at a 0.05 significance level) since 1999 and (2) winter ice extent showed a clear changing point (decline) around 2000, becoming statistically significant around 2005. The Pacific–Siberian sector of the Arctic accounted for most of the summer sea-ice decline, while the winter recovery of sea ice in the Atlantic sector tended to decrease

Development challenges and opportunities confronting economies in transition

comparative, development, economic development, economies in transition, international, social development, social indicators, social progress, social transformation, sustainable development,