1,700 research outputs found
Comment on “Diffusion measurements with the pulsed gradient nonlinear spin echo method” [J. Chem. Phys. 112
Comment on diffusion measurements with the pulsed gradient nonlinear spin echo method was presented. An approximation in the derivation of the effect of molecular diffusion on the results of the CRAZED experiment was also studied. The discussion of spin evolution after the second gradient pulse was also carried out.SCOPUS: ar.jinfo:eu-repo/semantics/publishe
Magic composite pulses
I describe composite pulses during which the average dipolar interactions
within a spin ensemble are controlled while realizing a global rotation. The
construction method used is based on the average Hamiltonian theory and rely on
the geometrical properties of the spin-spin dipolar interaction only. I present
several such composite pulses robust against standard experimental defects in
NRM: static or radio-frequency field miscalibration, fields inhomogeneities.
Numerical simulations show that the magic sandwich pulse sequence, a pulse
sequence that reverse the average dipolar field while applied, is plagued by
defects originating from its short initial and final \pi/2 radio-frequency
pulses. Using the magic composite pulses instead of \pi/2 pulses improves the
magic sandwich effect. A numerical test using a classical description of NMR
allows to check the validity of the magic composite pulses and estimate their
efficiency.Comment: 22 pages, 6 figure
Multiple quantum NMR dynamics in a gas of spin-carrying molecules in fluctuating nanopores
The effect of Gaussian fluctuations of nanopores filled with a gas of
spin-carrying molecules () on the multiple quantum (MQ) NMR dynamics is
investigated at different variances and correlation times of the fluctuations.
We show that the fluctuations smooth out the evolution of MQ NMR coherence
intensities which rapidly oscillate as functions of time in the absence of
fluctuations. The growth and decay of the MQ coherence clusters in the
fluctuating nanopore are also investigated.Comment: 10 pages, 3 figure
Quasi-equilibrium states in thermotropic liquid crystals studied by multiple quantum NMR
We study the nature of the quasiinvariants in nematic 5CB and measure their
relaxation times by encoding the multiple quantum coherences of the states
following the JB pulse pair on two orthogonal bases, Z and X. The experiments
were also performed in powder adamantane at 301 K which is used as a reference
compound having only one dipolar quasiinvariant. We show that the evolution of
the quantum states during the build up of the quasi-equilibrium state in 5CB
prepared under the S condition is similar to the case of adamantane and that
their quasi-equilibrium density operators have the same tensor structure. In
contrast, the second constant of motion, whose explicit operator form is not
known, involves a richer composition of multiple quantum coherences on the X
basis of even order, in consistency with the truncation inherent in its
definition. We exploited the exclusive presence coherences 4, 6, 8, besides 0
and 2 under the W condition to measure the spin-lattice relaxation time T_{W}
accurately, so avoiding experimental difficulties that usually impair dipolar
order relaxation measurement such as Zeeman contamination at high fields, and
also superposition of the different quasiinvariants. This procedure opens the
possibility of measuring the spin-lattice relaxation of a quasiinvariant
independent of the Zeeman and S reservoirs, so incorporating a new relaxation
parameter useful for studying the complex molecular dynamics in mesophases. In
fact, we report the first measurement of T_{W} in a liquid crystal at high
magnetic fields. The comparison of the obtained value with the one
corresponding to a lower field (16 MHz) points out that the relaxation of the
W-order strongly depends on the intensity of the external magnetic field,
similarly to the case of the S reservoir, indicating that the relaxation of the
W-quasiinvariant is also governed by the cooperative molecular motions.Comment: 7 figures. http://www.famaf.unc.edu.ar/series/AFis2005.ht
NMR Techniques for Quantum Control and Computation
Fifty years of developments in nuclear magnetic resonance (NMR) have resulted
in an unrivaled degree of control of the dynamics of coupled two-level quantum
systems. This coherent control of nuclear spin dynamics has recently been taken
to a new level, motivated by the interest in quantum information processing.
NMR has been the workhorse for the experimental implementation of quantum
protocols, allowing exquisite control of systems up to seven qubits in size.
Here, we survey and summarize a broad variety of pulse control and tomographic
techniques which have been developed for and used in NMR quantum computation.
Many of these will be useful in other quantum systems now being considered for
implementation of quantum information processing tasks.Comment: 33 pages, accepted for publication in Rev. Mod. Phys., added
subsection on T_{1,\rho} (V.A.6) and on time-optimal pulse sequences
(III.A.6), redid some figures, made many small changes, expanded reference
The cis/trans interconversion of the calcium regulating hormone calcitonin is catalyzed by cyclophilin
AbstractThe cytosolic peptidyl-prolyl cis/trans isomerase cyclophilin from pig kidney can accelerate catalytically the cis/trans isomerization of prolyl peptide bonds. One- and two-dimensional 1H NMR spectroscopy was used to prove that the polypeptide hormone calcitonin is a substrate for cyclophilin. Isomerization of only one of the two prolyl peptide bonds is catalyzed significantly. The efficiency of catalysis was calculated by lineshape analysis and NOESY spectroscopy. Cyclosporin A completely blocks the effect of the enzyme on the conformational dynamics of the polypeptide
Non-Linear Signal Detection Improvement by Radiation Damping in Single-Pulse NMR Spectra
When NMR lines overlap and at least one of them is affected by radiation damping, the resonance line shapes of all lines are no longer Lorentzian. We report the appearance of narrow signal distortions, which resemble hole-burnt spectra. This new experimental phenomenon facilitates the detection of tiny signals hidden below the main resonance. Theoretical analysis based on modified Maxwell–Bloch equations shows that the presence of strong transverse magnetization creates a feedback through the coil, which influences the magnetization of all spins with overlapping resonance lines. In the time domain this leads to cross-precession terms between magnetization densities, which ultimately cause non-linear behavior. Numerical simulations corroborate this interpretation
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