Novel cement curing technique by using controlled release of carbon dioxide coupled with nanosilica

Nanotechnology has attracted a lot of interest in the modification of building materials involving nanoparticles. Among the nanoparticles available, the incorporation of nano-silica draws intense attention due to the similarity of its chemical composition with cement and its pozzolanic properties. In this work, the potential capability to utilise CO2 in improving cement composites properties through carbonation acceleration mechanism was explored. In this study, various type of nano silica was used as a CO2 carrier and incorporated into cement mortar design with different amount of carbonated silica loading, ranging from 0.55 wt% to 2.42 wt% and cured in water and ambient air condition. The aim of this study is to examine the effects on the compressive strength of nano-silica impregnated with CO2 and incorporated into cement mortar. From the results, it was found that at 1.89% silica loading, the hydrophilic silica mortar (HSAM) samples can achieve the highest compressive strength of 34.1 MPa at 7 days and 40.7 MPa at 28 days, with a percentage gain of +38.06% and +17.29% respectively as compared to blank samples. However, the incorporation of silica for more than 1.89 wt% resulted in a negative effect on the compressive strength gain of HSAM samples. By the incorporation of 2.42 wt%, the samples showed a significant drop in compressive strength of −21.46% at 7 days and −17.29% at 28 days. The results proved that nano-silica coupled with CO2 can accelerate curing of cement mortar by means of carbonation

Novel deep eutectic solvent-functionalized carbon nanotubes adsorbent for mercury removal from water

Due to the interestingly tolerated physicochemical properties of deep eutectic solvents (DESs), they are currently in the process of becoming widely used in many fields of science. Herein, we present a novel Hg2+ adsorbent that is based on carbon nanotubes (CNTs) functionalized by DESs. A DES formed from tetra-n-butyl ammonium bromide (TBAB) and glycerol (Gly) was used as a functionalization agent for CNTs. This novel adsorbent was characterized using Raman spectroscopy, Fourier transform infrared (FTIR) spectroscopy, XRD, FESEM, EDX, BET surface area, and Zeta potential. Later, Hg2+ adsorption conditions were optimized using response surface methodology (RSM). A pseudo-second order model accurately described the adsorption of Hg2+. The Langmuir and Freundlich isotherms models described the absorption of Hg2+ on the novel adsorbent with acceptable accuracy. The maximum adsorption capacity was found to be 177.76 mg/g

Comparative analysis of gradient-boosting ensembles for estimation of compressive strength of quaternary blend concrete

Concrete compressive strength is usually determined 28 days after casting via crushing of samples. However, the design strength may not be achieved after this time-consuming and tedious process. While the use of machine learning (ML) and other computational intelligence methods have become increasingly common in recent years, findings from pertinent literatures show that the gradient-boosting ensemble models mostly outperform comparative methods while also allowing interpretable model. Contrary to comparison with other model types that has dominated existing studies, this study centres on a comprehensive comparative analysis of the performance of four widely used gradient-boosting ensemble implementations [namely, gradient-boosting regressor, light gradient-boosting model (LightGBM), extreme gradient boosting (XGBoost), and CatBoost] for estimation of the compressive strength of quaternary blend concrete. Given components of cement, Blast Furnace Slag (GGBS), Fly Ash, water, superplasticizer, coarse aggregate, and fine aggregate in addition to the age of each concrete mixture as input features, the performance of each model based on R2, RMSE, MAPE and MAE across varying training–test ratios generally show a decreasing trend in model performance as test partition increases. Overall, the test results showed that CatBoost outperformed the other models with R2, RMSE, MAE and MAPE values of 0.9838, 2.0709, 1.5966 and 0.0629, respectively, with further statistical analysis showing the significance of these results. Although the age of each concrete mixture was found to be the most important input feature for all four boosting models, sensitivity analysis of each model shows that the compressive strength of the mixtures does increase significantly after 100 days. Finally, a comparison of the performance with results from different ML-based methods in pertinent literature further shows the superiority of CatBoost over reported the methods

Nanomaterials characteristics and current utilization status in rigid pavements: mechanical features and sustainability. a review

Rigid pavements are recognized as one of the most widely means by which people and goods move around for popular aims and certain objectives. Nowadays, the utilization of rigid pavements is becoming an urgent demand and an increasing need, for these pavements require less maintenance and less renovation compared to other types. As a result, the structures are becoming more economical and more profitable. However, during its lifespan, normal rigid pavement is facing many challenges and difficulties. Its initial erection cost is extremely higher compared to asphalt pavements, its higher sensitivity to dynamic stresses, its higher susceptibility to temperature variations caused cracking, and further to its greater contribution to global carbon dioxide emissions. Past works of literature have been dealing with these drawbacks through employing efficient materials as alternatives to replace cement and/or aggregates in the concrete pavement mixtures. In recent years, the application of nanomaterials has received considerable interest to enhance the mechanical performance of construction materials which can also be available for rigid pavement constructions. Despite its poor performance in the fresh conditions, the addition of nanomaterials to rigid pavements has shown significant improvements in static properties like compressive and tensile strengths; dynamic properties like fatigue flexure and impact strengths. This enhancement is mainly due to the role of nanomaterials which acting as nano reinforcements and nanofillers within the concrete pavement blends. This review paper presents and discusses the behavior of nano-modified rigid pavements under different external loads. The effect of nano-SiO2, nano-CaCO3, nano-Al2O3, nano-TiO2, nano-clay and nanotubes are focused. Besides, as a promising sustainable structure, the influence of nano-SiO2 on the hardened properties of recycled rigid pavement is deeply discussed (both in normal and supplementary cementitious structures). Mechanical characteristics and optimal percentages are reviewed. A better comprehension of the characteristics of the nanostrengthening rigid pavements can provide an academic base for future works and engineering applications of developed concrete materials in the pavement construction industry

Nanomaterials in recycled aggregates concrete applications: mechanical properties and durability. A review

The use of recycled aggregates concrete (RAC) contributes effectively to reduce CO2 emissions from concrete manufacturing process while also protecting natural resources by utilizing existing available concrete as an aggregates source for a new one. Studies on the behaviour of RAC have revealed negative effects on concrete strength and microstructure development, resulting in deterioration of mechanical and durability properties. As a result, numerous practical studies have been implemented to enhance the RAC properties using various treatment techniques such as chemical, physical and heating treatments. However, most of these techniques are ineffective compared to conventional concrete applications due to poor mechanical performance of RAC, insufficient environmental requirements, and prolonged treatment times. Recently, the use of nanomaterials has been given significant concern in RAC research. Their nano-sized particles can help to reduce micropores formation by acting as a filling agent to produce a high-density microstructure, thereby enhancing the mechanical properties and durability of RAC. This had led to a wide range of studies being published on improving RAC properties by using nanomaterials. However, relatively few literatures had been conducted on the effects of different types of nanomaterials on the performance of RAC exposed to various types of loads and various external environmental impacts. Besides, the conditions used by authors in these literatures limit comparisons, and in some cases contradictory findings are observed. Thus, this paper aims to bridge the knowledge gap between researchers. This would allow the potential of nanotechnology in innovations to be applied in appropriate areas of RAC applications to benefit the general public good. This paper aims to provide a critical review and comprehensive conclusions on the performance of nano-modified RAC under external loads, environmental impacts and other various conditions. The effects of nanomaterials on the compressive, tensile, and flexural strength of RAC are discussed. The nanomaterials considered are nano-SiO2, nano-CaCO3, nano-TiO2, nano-Clay, nano-Al2O3, and nano-Carbon. Durability characteristics including water absorption, chloride penetration, fire exposure, abrasion resistance, acid and carbonation diffusions are extensively discussed. Microstructure characteristics using SEM, XRD, EDS, and micro-hardness of nano-modified RAC are addressed as well

Compressive and Flexural Strengths of Bio-Recycled Concrete Incorporated with Kenaf Fibre

ABSTRACTKenaf fiber (KF) has been applied in concrete to compensate for the weak tensile strength. Similarly, recycled concrete aggregate (RCA) is applied to reduce problems associated with waste concrete materials. However, both KF and RCA reduce the compressive strength (fck) of concrete. This study involves addition of calcite-producing bacillus subtilis bacteria to recycled aggregate concrete (RAC) incorporated with KF. The bacteria is added to concrete with varying proportions of RCA and KF to produce bio-fibrous recycled concrete (BFRC). The proportions of RCA are 0%, 25% 50% and 75% replacement of coarse aggregate, while KF are 0.2%, 0.5% and 1% of concrete. W/C of 0.45, 0.5, and 0.6 are applied to evaluate the effects of different w/c ratios. The properties evaluated are the fck and the flexural strength (ft) of the concrete samples at 28 days. The results showed that 0.2% KF in bio-concrete (BC) increases the fck by 12%; however, increasing above 0.2% decreases fck. KF in BC increases ft by 60%. Furthermore, 0.5% KF content resulted in highest ft of BRC. Increasing RCA content in bio-recycled concrete and BFRC decreases fck by 30% and 33%, respectively, as well as ft by 13% and 18%, respectively

Investigating the mechanical properties and durability of Asphalt mixture modified with Epoxidized Natural Rubber (ENR) under short and long-term aging conditions

Modifiers such as fibers, fillers, natural and synthetic polymer extenders, oxidants and anti-oxidants, and anti-stripping agents are added to produce modified asphalt. However, polymers are the most widely utilized modifiers to enhance the function of asphalt mixtures. The objective of this research was to evaluate the mechanical properties and durability of epoxidized natural rubber (ENR)-modified asphalt mix under short- and long-term aging conditions. The physical and rheological characteristics of the base asphalt and ENR-modified asphalt (ENRMA) were tested. In order to evaluate the mechanical properties and durability of the modified mixtures, the resilient modulus of the ENR–asphalt mixtures under unaged, and short- and long-term aging conditions at various temperatures and frequencies was obtained. Furthermore, the resistance to moisture damage of asphalt mixtures was investigated. The findings showed that the stiffness of the ENR–asphalt mixes increased because of the mutual influence of short- and long-term aging on the mixes. In addition, ENR reduced the susceptibility to moisture damage. The stiffness of the mixes was influenced by the temperature and frequencies. By using mathematical modelling via the multivariable power least squares method, it was found that temperature was the dominant factor among all other factors. The results suggested that the durability of asphalt pavements is improved by using ENR

Effect of Carbon Nanofibers on Physical, Adhesion and Rheological Properties of Liquid Epoxidized Natural Rubber Modified Asphalt

This study aimed to evaluate the effects of carbon nanofibers (CNFs) on the performance of liquid epoxidized natural rubber (LENR)-modified asphalt. The physical, adhesion and rheological properties were determined by several tests such as penetration, elastic recovery, ring and ball softening point, Brookfield rotational viscometer, AFM and dynamic shear rheometer. LENR was used at concentrations of 3, 6, and 9%, while CNFs were used at contents of 0.3, 0.4, and 0.5% by weight of asphalt. Conventional test results showed that the increases in LENR and LENR/CNFs composite contents in binder leads to an increase in the hardness and consistency and a reduction in the temperature susceptibility of base asphalt. Adhesion results revealed that the addition of CNFs significantly increases the adhesion and bonding properties of base and rubberized binders. Rheological properties analysis exhibited that LENR improved the viscoelastic properties and permanent deformation resistance of asphalt at different temperatures and frequencies. On the other hand, it was found that the addition of CNFs significantly improves the stiffness, elasticity, and hardness of LENR-modified binders. The 6% LENR and 0.4% CNFs were found to be the optimum to enhance the physical, adhesion, and rheological properties of asphalt in this study. Thus, it can be stated that the addition of CNFs is promising to improve the performance of rubberized binders for high temperature applications