115 research outputs found
Magnetoplasmon resonances in polycrystalline bismuth as seen via terahertz spectroscopy
We report the magnetic field-dependent far-infrared reflectivity of
polycrystalline bismuth. We observe four distinct absorptions that we attribute
to magnetoplasmon resonances, which are collective modes of an electron-hole
liquid in magnetic field and become optical and acoustic resonances of the
electron-hole system in the small-field limit. The acoustic mode is expected
only when the masses of distinct components are very different, which is the
case in bismuth. In a polycrystal, where the translational symmetry is broken,
a big shift of spectral weight to acoustic plasmon is possible. This enables us
to detect an associated plasma edge. Although the polycrystal sample has grains
of randomly distributed orientations, our reflectivity results can be explained
by invoking only two, clearly distinct, series of resonances. In the limit of
zero field, the optical modes of these two series converge onto plasma
frequencies measured in monocrystal along the main optical axes.Comment: Accepted in PR
Polarization of macrophages toward M2 phenotype is favored by reduction in iPLA2β (group VIA phospholipase A2)*
Macrophages are important in innate and adaptive immunity. Macrophage participation in inflammation or tissue repair is directed by various extracellular signals and mediated by multiple intracellular pathways. Activation of group VIA phospholipase A2 (iPLA2β) causes accumulation of arachidonic acid, lysophospholipids, and eicosanoids that can promote inflammation and pathologic states. We examined the role of iPLA2β in peritoneal macrophage immune function by comparing wild type (WT) and iPLA2β−/− mouse macrophages. Compared with WT, iPLA2β−/− macrophages exhibited reduced proinflammatory M1 markers when classically activated. In contrast, anti-inflammatory M2 markers were elevated under naïve conditions and induced to higher levels by alternative activation in iPLA2β−/− macrophages compared with WT. Induction of eicosanoid (12-lipoxygenase (12-LO) and cyclooxygenase 2 (COX2))- and reactive oxygen species (NADPH oxidase 4 (NOX4))-generating enzymes by classical activation pathways was also blunted in iPLA2β−/− macrophages compared with WT. The effects of inhibitors of iPLA2β, COX2, or 12-LO to reduce M1 polarization were greater than those to enhance M2 polarization. Certain lipids (lysophosphatidylcholine, lysophosphatidic acid, and prostaglandin E2) recapitulated M1 phenotype in iPLA2β−/− macrophages, but none tested promoted M2 phenotype. These findings suggest that (a) lipids generated by iPLA2β and subsequently oxidized by cyclooxygenase and 12-LO favor macrophage inflammatory M1 polarization, and (b) the absence of iPLA2β promotes macrophage M2 polarization. Reducing macrophage iPLA2β activity and thereby attenuating macrophage M1 polarization might cause a shift from an inflammatory to a recovery/repair milieu
Surface state charge dynamics of a high-mobility three dimensional topological insulator
We present a magneto-optical study of the three-dimensional topological
insulator, strained HgTe using a technique which capitalizes on advantages of
time-domain spectroscopy to amplify the signal from the surface states. This
measurement delivers valuable and precise information regarding the surface
state dispersion within <1 meV of the Fermi level. The technique is highly
suitable for the pursuit of the topological magnetoelectric effect and axion
electrodynamics.Comment: Published version, online Sept 23, 201
Negative Thermal Expansion Near the Precipice of Structural Stability in Open Perovskites
Negative thermal expansion (NTE) describes the anomalous propensity of materials to shrink when heated. Since its discovery, the NTE effect has been found in a wide variety of materials with an array of magnetic, electronic and structural properties. In some cases, the NTE originates from phase competition arising from the electronic or magnetic degrees of freedom but we here focus on a particular class of NTE which originates from intrinsic dynamical origins related to the lattice degrees of freedom, a property we term structural negative thermal expansion (SNTE). Here we review some select cases of NTE which strictly arise from anharmonic phonon dynamics, with a focus on open perovskite lattices. We find that NTE is often present close in proximity to competing structural phases, with structural phase transition lines terminating near T=0 K yielding the most prominent displays of the SNTE effect. We further provide a theoretical model to make precise the proposed relationship among the signature behavior of SNTE, the proximity of these systems to structural quantum phase transitions and the effects of phase fluctuations near these unique regions of the structural phase diagram. The effects of compositional disorder on NTE and structural phase stability in perovskites are discussed
Mott insulating negative thermal expansion perovskite TiF3
We characterize perovskite TiF_3, a material which displays significant
negative thermal expansion at elevated temperatures above its
cubic-to-rhombohedral structural phase transition at 330 K. We find the optical
response favors an insulating state in both structural phases, which we show
can be produced in density functional theory calculations only through the
introduction of an on-site Coulomb repulsion. Analysis of the magnetic
susceptibility data gives a S=1/2 local moment per Ti+3 ion and an
antiferromagnetic exchange coupling. Together, these results show that TiF_3 is
a strongly correlated electron system, a fact which constrains possible
mechanisms of strong negative thermal expansion in the Sc_1-xTi_xF3 system. We
consider the relative strength of the Jahn-Teller and electric dipole
interactions in driving the structural transition.Comment: 8 pages, 4 figures, in review Physical Review
The Kondo Dynamics of YbIn(1-x)AgxCu4
We present an infrared/optical study of the dynamics of the strongly
correlated electron system YbIn(1-x)AgxCu4 as a function of doping and
temperature for x ranging from 0 to 1, and T between 20 and 300 K. This study
reveals information about the unusual phase transition as well as the phases
themselves. Scaling relations emerge from the data and are investigated in
detail using a periodic Anderson model based calculation. We also provide a
picture in which to view both the low and high-energy x-dependent features of
the infrared data, including identification of high energy, temperature
dependent features.Comment: 12 pages, 11 figures, submitted Phys. Rev.
- …