Design, construction and performance of passive systems for the treatment of mine and spoil heap drainage

PhD ThesisPassive treatment systems for mine water pollution remediation require no chemical or energy inputs, and should only incur limited maintenance costs if properly constructed. This thesis investigates two such passive treatment systems that have been installed at sites in County Durham, UK. The overall objectives of the investigation were to improve understanding of the operation of passive systems in order to produce more accurate design guidelines, and to develop a new passive treatment option to complement existing technologies. To put the research into context the causes, impacts and extent of mine water pollution in the UK and overseas are outlined. In addition a detailed and up-to-date review of passive treatment research and development is provided, which highlights areas in which further research is required. At Quaking Houses, County Durham, a full-scale compost wetland has been constructed to treat an acidic and metal-rich discharge from the spoil heap of an abandoned coal mine. Over the 27 month study period the discharge had pH >_ 4, and mean iron, manganese and aluminium concentrations of 5.4 mg/L, 3.6 mg/L and 6.2 mg/L respectively. The unique design and construction of the 440 m2 wetland is described. An examination of the performance of the wetland illustrates that it has yielded significant improvements in water quality since its construction. Mean reductions in acidity, iron and aluminium concentrations are all around 50%. Bacterial sulphate reduction may be an important contaminant removal mechanism, but its proportional significance is unclear. Comparison of the system at Quaking Houses with other wetlands reveals that the mean reduction in acidity in terms of mass removal per unit area (5.01 g/m2/d) is comparatively low. However, it is shown that comparing wetland performance on this basis may be misleading where influent contaminant concentrations are relatively low, because contaminant removal is demonstrably influent concentrationdependent. A first-order removal assessment method of performance may be more appropriate, and on this basis the Quaking Houses wetland performs well when compared to systems in the USA. An algorithm for predicting wetland effluent iron concentrations is derived using a linear multiple regression technique. Time series analysis strongly suggests that some effluent water quality variables (and therefore wetland performance measures) are significantly affected by seasonal climate changes. In particular aluminium and acidity removal rates rise with increasing air temperature. This implies that to meet the same effluent water quality targets passive treatment systems in cold climate locations may need to be larger than equivalent systems in warmer climates. At Kimblesworth, also in County Durham, a pilot-scale passive treatment system has been operated for 4 months. The Kimblesworth discharge is a net-alkaline pumped mine water containing up to 2 mg/L iron and up to 1 mg/L manganese. The novel system at this site was designed to rapidly remove iron by oxidation and accretion of iron to high surface area media. The monitoring programme has revealed the system to be very efficient. Iron concentrations are consistently reduced to < 0.5 mg/L, and removal rates are an order of magnitude greater than in wetland systems. Furthermore, lithium tracer tests reveal that the residence time of water in the reactors is just 5- 10 minutes. The results of this research suggest that the technology could be applied at full-scale. The compost wetland at Quaking Houses and the new reactor at Kimblesworth may well complement each other. The Quaking Houses system generates alkalinity and removes metal contaminants, but effluent water still contains marginally elevated concentrations of iron (mean 2.4 mg/L). The Kimblesworth system is shown to be very effective at rapidly removing low concentrations of iron, and thus could conceivably be used as a polishing unit following a compost wetland such as that at Quaking Houses. Alternatively high surface area media reactors such as those at Kimblesworth could be used to treat discharges in topographically difficult locations, where the installation of a wetland is not feasible.Northumbrian Water Kick Start Fund: Engineering and Physical Sciences Research Council (Grant number: GR/L55421): IMC Consulting Engineers Ltd: Coal Authority

The Pilbara experience: an internship with Rio Tinto Iron Ore Project Engineering

The 11kV distribution system at Paraburdoo mine site has been in service for the better part of the last forty years and has come to the end of its service life and requires replacing. These 11kV electricity assets include the 11kV bulk supply switchroom, a significant proportion of the plant distribution, six distribution transformers and a shunt reactor. In addition a new administration/workshop building and wash pad is currently under construction at West Angelas mine site and requires power installed from nearby overhead power lines. The purpose of my internship has been to write a Scope of Works and a Functional Specification for the replacement of the electricity assets at Paraburdoo and the installation of power at West Angelas. This was achieved by assessing the installation requirements, understanding the functionality of the electrical network in which they operate and consulting the relevant Australian Standards applicable to each installation whilst communicating with the project stakeholders in order to facilitate the replacement and installation of these assets at both sites. Specifically the assets at Paraburdoo shall be replaced with contemporary switchgear, transformers and shunt reactors while at West Angelas the new buildings will receive power via new underground cable from nearby take-off poles to a kiosk comprising an LV switchboard

Obituary: Paul Younger 1962-2018

Paul loved geology, rocks and energy, but there was more to him. He revelled in language, adored music and was a man of deep faith

The Role of Contextual Info‐Marks in Navigating a Virtual Rural Environment

Navigation is a task performed in both large and small scale environments. Landmarks within an environment are of great benefit to these navigational tasks, but in large rural environments such landmarks may be sparse. It has been shown that landmarks need not be purely visual and that a change in context for a feature can make it become a landmark against its surroundings (such as being provided with significant meaning). Such meaning could be added through personal experience or by informing the observer via some form of communication. To investigate the effects of providing such contextual information on navigational performance, experiments were conducted in a large rural virtual environment where the delivery method of the information was varied between onscreen and PDA display. Users were instructed to perform a route tracing navigation task. In some instances users were presented with textual information about specific locations within the environment which appeared when they were in the vicinity of the location. Both quantitative and qualitative data were collected and analyzed, with results indicating that although the actual performance in the task was not significantly improved, users felt that their performance was better and the task easier when they were presented with the contextual information

Hydraulic performance and iron removal in wetlands and lagoons treating ferruginous coal mine waters

A study of hydraulic residence time has been conducted for several UK Coal Authority mine water treatment systems to evaluate the impact of residence time on the overall hydraulic performance and iron removal within the systems. A series of tracer tests were conducted within the Coal Authority mine water treatment wetlands and lagoons to measure actual hydraulic residence time. The tracer residence time distributions (RTDs) were analysed based on a tanks-in-series (TIS) model to yield the mean residence time and corresponding hydraulic characteristics of the systems. The relationship between iron retention and residence time was tested against a first-order removal model. The mean hydraulic efficiency is 69 % for the wetlands compared to 24 % for the lagoons, mainly attributable to comparatively greater volumetric efficiency within the wetland systems. The mean number of TIS, n, is 3.9 for the wetlands and 2.1 for the lagoons, illustrating considerably different flow patterns between wetlands and lagoons. There is also a notable difference of treatment efficiency for iron; mean of 81 % and 47 % for wetlands and lagoons, respectively. Generally, it appears that system hydraulic efficiency (derived from the principle of TIS model) corresponds with iron retention in the treatment systems

Optimization of NTP System Truss to Reduce Radiation Shield Mass

The benefits of nuclear thermal propulsion are numerous and relevant to the current NASA mission goals involving but not limited to the crewed missions to mars and the moon. They do however also present new and unique challenges to the design and logistics of launching/operating spacecraft. One of these challenges, relevant to this discussion, is the significant mass of the shielding which is required to ensure an acceptable radiation environment for the spacecraft and crew. Efforts to reduce shielding mass are difficult to accomplish from material and geometric design points of the shield itself, however by increasing the distance between the nuclear engines and the main body of the spacecraft the required mass of the shielding is lessened considerably. The mass can be reduced significantly per unit length, though any additional mass added by the structure to create this distance serves to offset those savings, thus the design of a lightweight structure is ideal. The challenges of designing the truss are bounded by several limiting factors including; the loading conditions, the capabilities of the launch vehicle, and achieving the ideal truss length when factoring for the overall mass reduced. Determining the overall set of mass values for a truss of varying length is difficult since to maintain an optimally designed truss the geometry of the truss or its members must change. Thus the relation between truss mass and length for these loading scenarios is not linear, and instead has relation determined by the truss design. In order to establish a mass versus length trend for various truss designs to compare with the mass saved from the shield versus length, optimization software was used to find optimal geometric properties that still met the design requirements at established lengths. By solving for optimal designs at various lengths, mass trends could be determined. The initial design findings show a clear benefit to extending the engines as far from the main structure of the spacecraft as the launch vehicle's payload volume would allow when comparing mass savings verse the additional structure

Measuring the reactivity of a silicon-terminated probe

It is generally accepted that the exposed surfaces of silicon crystals are highly reactive due to the dangling bonds which protrude into the vacuum. However, surface reconstruction can not only modify the reactivity of bulk silicon crystals, but plays a key role in determining the properties of silicon nanocrystals. In this study we probe the reactivity of silicon clusters at the end of a scanning probe tip by examining their interaction with closed shell fullerene molecules. Counter to intuitive expectations, many silicon clusters do not react strongly with the fullerene cage, and we find that only specific highly oriented clusters have sufficient reactivity to break open the existing carbon-carbon bonds

Managing Dynamic Enterprise and Urgent Workloads on Clouds Using Layered Queuing and Historical Performance Models

The automatic allocation of enterprise workload to resources can be enhanced by being able to make what-if response time predictions whilst different allocations are being considered. We experimentally investigate an historical and a layered queuing performance model and show how they can provide a good level of support for a dynamic-urgent cloud environment. Using this we define, implement and experimentally investigate the effectiveness of a prediction-based cloud workload and resource management algorithm. Based on these experimental analyses we: i.) comparatively evaluate the layered queuing and historical techniques; ii.) evaluate the effectiveness of the management algorithm in different operating scenarios; and iii.) provide guidance on using prediction-based workload and resource management

Simulated structure and imaging of NTCDI on Si(1 1 1)-7 × 7 : a combined STM, NC-AFM and DFT study

The adsorption of naphthalene tetracarboxylic diimide (NTCDI) on Si(1 1 1)-7 × 7 is investigated through a combination of scanning tunnelling microscopy (STM), noncontact atomic force microscopy (NC-AFM) and density functional theory (DFT) calculations. We show that NTCDI adopts multiple planar adsorption geometries on the Si(1 1 1)-7 × 7 surface which can be imaged with intramolecular bond resolution using NC-AFM. DFT calculations reveal adsorption is dominated by covalent bond formation between the molecular oxygen atoms and the surface silicon adatoms. The chemisorption of the molecule is found to induce subtle distortions to the molecular structure, which are observed in NC-AFM images