GaN-Based Detector Enabling Technology for Next Generation Ultraviolet Planetary Missions

The ternary alloy AlN-GaN-InN system provides several distinct advantages for the development of UV detectors for future planetary missions. First, (InN), (GaN) and (AlN) have direct bandgaps 0.8, 3.4 and 6.2 eV, respectively, with corresponding wavelength cutoffs of 1550 nm, 365 nm and 200 nm. Since they are miscible with each other, these nitrides form complete series of indium gallium nitride (In(sub l-x)Ga(sub x)N) and aluminum gallium nitride (Al(sub l-x)Ga(sub x)N) alloys thus allowing the development of detectors with a wavelength cut-off anywhere in this range. For the 2S0-365 nm spectral wavelength range AlGaN detectors can be designed to give a 1000x solar radiation rejection at cut-off wavelength of 325 nm, than can be achieved with Si based detectors. For tailored wavelength cut-offs in the 365-4S0 nm range, InGaN based detectors can be fabricated, which still give 20-40x better solar radiation rejection than Si based detectors. This reduced need for blocking filters greatly increases the Detective Quantum efficiency (DQE) and simplifies the instrument's optical systems. Second, the wide direct bandgap reduces the thermally generated dark current to levels allowing many observations to be performed at room temperature. Third, compared to narrow bandgap materials, wide bandgap semiconductors are significantly more radiation tolerant. Finally, with the use of an (AI, In)GaN array, the overall system cost is reduced by eliminating stringent Si CCD cooling systems. Compared to silicon, GaN based detectors have superior QE based on a direct bandgap and longer absorption lengths in the UV

The Research Data Centre of the Centre for European Economic Research (ZEW-FDZ)

Das Zentrum für Europäische Wirtschaftsforschung (ZEW) in Mannheim stellt eine Reihe seiner Forschungsdatensätze externen Wissenschaftlern zur Verfügung. Das ZEW folgt damit den Empfehlungen der „Kommission zur Verbesserung der informationellen Infrastruktur zwischen Wissenschaft und Statistik“ und unterstützt so die Weiterentwicklung der empirischen Wirtschafts- und Sozialforschung. Im November 2012 ist das ZEW-FDZ vom Rat für Sozial und Wirtschaftsdaten (RatSWD) akkreditiert worden. Bei den im ZEW-FDZ angebotenen ZEW Forschungsdaten handelt es sich um Mikrodaten von ZEW Unternehmensbefragungen, ZEW Expertenbefragungen oder ZEW Personenbefragungen. Die Daten einiger ZEW-Befragungen werden externen Wissenschaftlern in einer faktisch anonymisierten Form als Scientific-Use-Files zur Verfügung gestellt. Neben der Nutzung der Scientific-Use-Files können externe Forscher einen Antrag auf Nutzung von formal anonymisierten ZEW-Daten stellen, mit denen sie in den FDZ-Räumen des ZEW arbeiten dürfen. Formal anonymisiert bedeutet, dass die Datensätze weder Namen noch Adressen, aber ansonsten alle Originalangaben der Befragten enthalten. Die formal anonymisierten Daten befinden sich dazu auf einem Stand-alone-Rechner ohne Netzwerkanbindung, von dem keine Daten heruntergeladen werden können. Für das Mannheimer Innovationspanel (MIP) wurden zudem absolut anonymisierte Education-Use-Files für die Nutzung in der Lehre erstellt. Das ZEW-FDZ schließt an die bisherige Praxis des ZEW an, eigene Erhebungsdaten an externe Wissenschaftler weiterzugeben. Vor dem Start des ZEW-FDZ im Januar 2013, stellte das ZEW etwa 280 Wissenschaftlern vom ZEW erhobene Forschungsdaten zur Verfügung; die meisten sind Nutzer des Mannheimer Innovationspanels (250). Das ZEW wird sein Datenangebot für externe Wissenschaftler laufend erweitern. Dies gilt auch für Daten zukünftiger Erhebunge

Vapor Pressure of Ionic Liquids

We argue that the extremely low vapor pressures of room temperature ionic liquids near their triple points are due to the combination of strong ionic characters and of low melting temperatures.Comment: Initially submitted manuscript of article M. Bier and S. Dietrich, Mol. Phys. 108, 211 (2010) [Corrigendum: Mol. Phys. 108, 1413 (2010)

Why Are Alkali Halide Solid Surfaces Not Wetted By Their Own Melt?

Alkali halide (100) crystal surfaces are anomalous, being very poorly wetted by their own melt at the triple point. We present extensive simulations for NaCl, followed by calculations of the solid-vapor, solid-liquid, and liquid-vapor free energies showing that solid NaCl(100) is a nonmelting surface, and that its full behavior can quantitatively be accounted for within a simple Born-Meyer-Huggins-Fumi-Tosi model potential. The incomplete wetting is traced to the conspiracy of three factors: surface anharmonicities stabilizing the solid surface; a large density jump causing bad liquid-solid adhesion; incipient NaCl molecular correlations destabilizing the liquid surface. The latter is pursued in detail, and it is shown that surface short-range charge order acts to raise the surface tension because incipient NaCl molecular formation anomalously reduces the surface entropy of liquid NaCl much below that of solid NaCl(100).Comment: 4 pages, 3 figure

Assessing the operating temperature of multi-junction solar cells with novel rear side layer stack and local electrical contacts

Sub-bandgap sunlight provides a source of heat generation in solar cells that is detrimental to performance, especially in space applications where heat dissipation is limited. In this work we assess the impact that an advanced rear-side contact scheme for multi-junction solar cells has on the cell temperature. Our results show that this scheme reduces the optical power absorption below the bandgap of germanium by 81% compared to a standard, full metallization design. Measurements of the electrical and thermal power fluxes performed in vacuum demonstrate that this lower near-infrared light absorption results in 8% less heat dissipated in the cell with the novel rear-side contact scheme when operating at 25 ºC. Modelling of the operating temperature for both cells when fully encapsulated with glass indicates that this effect will also result in a reduction of the operating temperature of 9 ºC for the novel design

Stellar Kinematics and Structural Properties of Virgo Cluster Dwarf Early-Type Galaxies from the SMAKCED Project. I. Kinematically Decoupled Cores and Implications for Infallen Groups in Clusters

We present evidence for kinematically decoupled cores (KDCs) in two dwarf early-type (dE) galaxies in the Virgo cluster, VCC 1183 and VCC 1453, studied as part of the SMAKCED stellar absorption-line spectroscopy and imaging survey. These KDCs have radii of 1.8'' (0.14 kpc) and 4.2'' (0.33 kpc), respectively. Each of these KDCs is distinct from the main body of its host galaxy in two ways: (1) inverted sense of rotation; and (2) younger (and possibly more metal-rich) stellar population. The observed stellar population differences are probably associated with the KDC, although we cannot rule out the possibility of intrinsic radial gradients in the host galaxy. We describe a statistical analysis method to detect, quantify the significance of, and characterize KDCs in long-slit rotation curve data. We apply this method to the two dE galaxies presented in this paper and to five other dEs for which KDCs have been reported in the literature. Among these seven dEs, there are four significant KDC detections, two marginal KDC detections, and one dE with an unusual central kinematic anomaly that may be an asymmetric KDC.The frequency of occurence of KDCs and their properties provide important constraints on the formation history of their host galaxies. We discuss different formation scenarios for these KDCs in cluster environments and find that dwarf-dwarf wet mergers or gas accretion can explain the properties of these KDCs. Both of these mechanisms require that the progenitor had a close companion with a low relative velocity. This suggests that KDCs were formed in galaxy pairs residing in a poor group environment or in isolation whose subsequent infall into the cluster quenched star formation.Comment: 14 pages, accepted for publication in Ap

Selenium interactions with algae: Chemical processes at biological uptake sites, bioaccumulation, and intracellular metabolism

Selenium (Se) uptake by primary producers is the most variable and important step in determining Se concentrations at higher trophic levels in aquatic food webs. We gathered data available about the Se bioaccumulation at the base of aquatic food webs and analyzed its relationship with Se concentrations in water. This important dataset was separated into lotic and lentic systems to provide a reliable model to estimate Se in primary producers from aqueous exposure. We observed that lentic systems had higher organic selenium and selenite concentrations than in lotic systems and selenate concentrations were higher in lotic environments. Selenium uptake by algae is mostly driven by Se concentrations, speciation and competition with other anions, and is as well influenced by pH. Based on Se species uptake by algae in the laboratory, we proposed an accurate mechanistic model of competition between sulfate and inorganic Se species at algal uptake sites. Intracellular Se transformations and incorporation into selenoproteins as well as the mechanisms through which Se can induce toxicity in algae has also been reviewed. We provided a new tool for risk assessment strategies to better predict accumulation in primary consumers and consequently to higher trophic levels, and we identified some research needs that could fill knowledge gaps