Thermal emission measurements (5-25 microns) of palagonite/Fe-substituted montmorillonite intimate mixtures: Applications to Mars

The emissivity of a Mauna Kea palagonitic soil mixed with an Fe-substituted montmorillonite (FeM) was measured. The emission spectra of all samples were measured at the TES spectroscopy laboratory at Arizona State University. The data were converted to emissivity using blackbody measurements combined with measurements of each sample at different temperatures. This preliminary study has demonstrated that both naturally-occurring palagonites, thought to be good visible to near-IR spectral analogs for Mars, and FeM exhibit complex emissivity spectra at thermal wavelengths. FeM exhibits greater emissivity variations than palagonite, and emissivity peaks observed in the FeM spectrum allows its identification for abundances greater than or equal to 15 percent when mixed with palagonite. Smaller abundances of FeM are potentially identifiable when mixed with palagonite, but this remains to be determined

Thermal emission measurements (5-25 microns) of Hawaiian palagonitic soils with implications for Mars

Careful laboratory studies have shown that the coloring agent in Mars analog Hawaiian palagonitic soils is nanophase iron oxide. We have measured the emissivity of two Mauna Kea palagonitic soils whose transmission spectra exhibit different spectral features and of a thermally-altered volcanic tephra sample that exhibits a wide range of crystallinity and degree of alteration (from black cinders to fully hematitic). Both of these samples may represent analogs for formation mechanisms involving the production of highly-altered secondary weathering products on Mars. The emission spectra of all samples were measured at the TES spectroscopy laboratory at Arizona State University. The data were converted to emissivity using blackbody measurements combined with measurements of each sample at different temperatures

Stochastic Electron Acceleration by Cascading Fast Mode Waves in Impulsive Solar Flares

We present a model for the acceleration of electrons from thermal to ultrarelativistic energies during an energy release fragment in an impulsive solar flare. Long-wavelength low-amplitude fast mode waves are assumed to be generated during the initial flare energy release (by, for example, large-scale restructuring of the magnetic field). These waves nonlinearly cascade to higher wavenumbers and eventually reach the dissipation range, whereupon they are transit-time damped by electrons in the tail of the thermal distribution. The electrons, in turn, are energized out of the tail and into substantially higher energies. We find that for turbulence energy densities much smaller than the ambient magnetic field energy density and comparable to the thermal particle energy density, and for a wide range of initial wavelengths, a sufficient number of electrons are accelerated to hard X-ray-producing energies on observed timescales. We suggest that MHD turbulence unifies electron and proton acceleration in impulsive solar flares, since a preceding study established that a second MHD mode (the shear Alfven wave) preferentially accelerates protons from thermal to gamma-ray line-producing energies

Perspectives of Pedagogical Change within a Broadcast STEM Course

As calls for pedagogical transformation of undergraduate science, technology, engineering, and mathematics (STEM) instruction intensify, the pace of change remains slow. The literature shows that research-based instructional strategies transfer only sporadically into STEM instructional practice. Difficulties associated with implementation and sustainment of instructional change may appear daunting— if not insurmountable—to many STEM change agents and teaching faculty. Subsequently, the path towards systematic and lasting pedagogical transformation in post-secondary STEM stands largely uncharted. To understand how challenges faced by STEM educators engaged in pedagogical change may be overcome, this paper uses qualitative inquiry to explore an emergent process of teacher change. The change process took place during implementation of an online innovation within an undergraduate engineering calculus course taught via synchronous broadcast at a mid-size, Western, public university. The instructional innovation required first year calculus students to participate in an asynchronous, online discussion forum for graded credit. Data, consisting of written reflections and transcribed interviews, were gathered from three STEM faculty members who each played a different role in the change process: a mathematics instructor implementing the online forum within his course; an engineering faculty peer-mentor assisting with the implementation of the online forum; and a STEM education faculty member evaluating the implementation and observing the process of change. Situated within the interpretive research paradigm, this study uses exploratory thematic analysis of narrative data to understand the ways in which contextual factors may influence pedagogical change

Transmission measurements (4000-400 cm(exp -1), 2.5-25 microns) of crystalline ferric oxides and ferric oxyhydroxides: Implications for Mars

Transmission spectra of three ferric oxides (two alpha-Fe2O3 samples and one gamma-Fe2O3 sample) and two ferric oxyhydroxides (alpha-FeOOH and gamma-FeOOH) were measured. This preliminary study has demonstrated that crystalline ferric oxides and ferric oxyhydroxides exhibit complex spectral features at thermal wavelengths. Some of these features suggest that thermal infrared observations of Mars can provide significant insight into the ferric mineralogy of that planet. The results of this study suggest that emissivity spectra of crystalline ferric oxides and ferric oxyhydroxides may prove quite important for the interpretation of thermal infrared spectral observations of Mars

New Promise for Electron Bulk Energization in Solar Flares: Preferential Fermi Acceleration of Electrons over Protons in Reconnection-driven Magnetohydrodynamic Turbulence

The hard X-ray luminosity of impulsive solar flares indicates that electrons in the low corona are bulk energized to energies of order 25 keV. LaRosa & Moore pointed out that the required bulk energization could be produced by cascading MHD turbulence generated by Alfvénic outflows from sites of strongly driven reconnection. LaRosa, Moore, & Shore proposed that the compressive component of the cascading turbulence dissipates into the electrons via Fermi acceleration. However, for this to be a viable electron bulk energization mechanism, the rate of proton energization by the same turbulence cannot exceed the electron energization rate. In this paper we estimate the relative efficiency of electron and proton Fermi acceleration in the compressive MHD turbulence expected in the reconnection outflows in impulsive solar flares. We find that the protons pose no threat to the electron energization. Particles extract energy from the MHD turbulence by mirroring on magnetic compressions moving along the magnetic field at the Alfvén speed. The mirroring rate, and hence the energization rate, is a sensitive function of the particle velocity distribution. In particular, there is a lower speed limit Vmin ≍ VA, below which the pitch-angle distribution of the particles is so highly collapsed to the magnetic field in the frame of the magnetic compressions that there is no mirroring and hence no Fermi acceleration. For coronal conditions, the proton thermal speed is much less than the Alfvén speed and proton Fermi acceleration is negligible. In contrast, nearly all of the electrons are super-Alfvénic, so their pitch-angle distribution is nearly isotropic in the frame of the magnetic compressions. Consequently, the electrons are so vigorously mirrored that they are Fermi accelerated to hard X-ray energies in a few tenths of a second by the magnetic compressions on scales of 105-103 cm in the cascading MHD turbulence. We conclude that dissipation of reconnection-generated MHD turbulence by electron Fermi acceleration plausibly accounts for the electron bulk energization in solar flares

A Survey of Theories of the Family

This review explores the theory of household technology and the associated possibilities for distributing utility among household members. It also explores decision theory within the household, drawing on standard consumer decision theory. The review discusses models of equilbrium in which families are formed by persons voluntarily choosing mates. This theory is analogous to ``Tiebout theory'' in urban economics, where the objects of choice include not only the amount of public goods supplied in each city, but also which individuals live in each place. An aspect of family life that has fewer parallels in the economics of market economies is intrafamilial affection. The final section of this paper reviews a growing theoretical literature on love, altruism and the family.Center for Research on Economic and Social Theory, Department of Economics, University of Michiganhttp://deepblue.lib.umich.edu/bitstream/2027.42/101098/1/ECON082.pd

Comparison of an enzyme-linked immunosorbent assay (ELISA) to gas chromatography (GC) - measurement of polychlorinated biphenyls (PCBs) in selected US fish extracts

The analysis of PCBs in fish tissues by immunoassay methods was evaluated using fish collected from a US monitoring program, the National Contaminant Biomonitoring Program of the US Department of Interior, Fish and Wildlife Service. Selected composite whole fish samples, which represented widely varying concentrations and sources of PCBs, were extracted and subjected to congener PCB analysis by gas chromatography (GC) and total PCB analysis using an ELISA (ePCBs) calibrated against technical Aroclor 1248. PCB congener patterns in these fishes were different from the patterns found in commercial Aroclors or their combinations as demonstrated by principal component analysis of normalized GC congener data. The sum of the PCB congeners measured by GC (total-PCBs) ranged from 37 to 4600 ng/g (wet weight). Concentrations of PCBs as determined by the ELISA method were positively correlated with total-PCBs and the ePCBs/total-PCBs ratios for individual samples ranged from 1 to 6. Ratios of ePCBs/total- PCBs for dilutions of Aroclors 1242, 1254, and 1260 and for matrix spikes range from 0.6 for 1242 to 2.5 for 1254 and 1260. These results suggest that higher chlorinated PCB congeners have higher anffinity for the anti-PCB antibodies. Partial least squares with latent variable analysis of GC and ELISA data of selected Aroclors and fish samples also support the conclusion that ELISA derived PCB concentrations are dependent on the degree of chlorination. © 1999 Elsevier Science Ltd. All rights reserved

Near-Infrared Spectral Geometric Albedos of Charon and Pluto: Constraints on Charon's Surface Composition

The spectral geometric albedos of Charon and Pluto are derived at near-infrared wavelengths (1.4-2.5 jAm) from measurements obtained in 1987. Comparisons of these to theoretical calculations are used to place constraints on the identity and relative abundances of surface ices on Charon. These compari- sons suggest that widespread regions of pure CH4 ice do not occur on Charon and that if CH4 is abundant on Charon then it is large grained (-5 mm) and is likely mixed at the granular level with H20 ice, and possibly C02 ice

Comparison of an enzyme-linked immunosorbent assay (ELISA) to gas chromatography (GC) - measurement of polychlorinated biphenyls (PCBs) in selected US fish extracts

The analysis of PCBs in fish tissues by immunoassay methods was evaluated using fish collected from a US monitoring program, the National Contaminant Biomonitoring Program of the US Department of Interior, Fish and Wildlife Service. Selected composite whole fish samples, which represented widely varying concentrations and sources of PCBs, were extracted and subjected to congener PCB analysis by gas chromatography (GC) and total PCB analysis using an ELISA (ePCBs) calibrated against technical Aroclor 1248. PCB congener patterns in these fishes were different from the patterns found in commercial Aroclors or their combinations as demonstrated by principal component analysis of normalized GC congener data. The sum of the PCB congeners measured by GC (total-PCBs) ranged from 37 to 4600 ng/g (wet weight). Concentrations of PCBs as determined by the ELISA method were positively correlated with total-PCBs and the ePCBs/total-PCBs ratios for individual samples ranged from 1 to 6. Ratios of ePCBs/total- PCBs for dilutions of Aroclors 1242, 1254, and 1260 and for matrix spikes range from 0.6 for 1242 to 2.5 for 1254 and 1260. These results suggest that higher chlorinated PCB congeners have higher anffinity for the anti-PCB antibodies. Partial least squares with latent variable analysis of GC and ELISA data of selected Aroclors and fish samples also support the conclusion that ELISA derived PCB concentrations are dependent on the degree of chlorination. © 1999 Elsevier Science Ltd. All rights reserved