805 research outputs found

    Nutrient stimulation of bacterioplankton growth in Tuamotu atoll lagoons

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    High strain-rate effects from blast loads on laminated glass: An experimental investigation of the post-fracture bending moment capacity based on time–temperature mapping of interlayer yield stress

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    To enhance the resilience of buildings, laminated glass panels are increasingly used in glazed façades. These ductile panels provide a superior blast resistance to that provided by monolithic glass panels, due to the improved residual capacity offered by the polymer interlayer following the fracture of the glass layers. The complex interaction between the attached glass fragments and the interlayer is still only partially understood. To help address this, this paper investigates experimentally the post-fracture bending moment capacity of laminated glass. Three-point bending tests are performed at low temperature on specimens pre-fractured before testing, to ensure controlled and repeatable fracture patterns. The low temperature simulates the effects of the high strain-rates that result from short-duration blast loads by taking advantage of the time-temperature dependency of the viscoelastic interlayer. In these experiments, polyvinyl butyral is considered as the interlayer, this being the most common interlayer for laminated glass used in building facades. A new time-temperature mapping equation is derived from experimental results available in the literature, to relate the temperatures and strain-rates that result in the same interlayer yield stress. The results of the low-temperature tests demonstrate an enhancement of the ultimate load capacity of the fractured glass by two orders of magnitude, compared to that at room temperature. This suggests an improved post-fracture bending moment capacity associated with the now stiffer interlayer working in tension and the glass fragments working in compression. Due to the time-temperature dependency of the interlayer, a similar enhancement is therefore anticipated at the high strain-rates associated with typical blast loading. Finally, the assumed composite bending action is further supported by the results from additional specimens with thicker PVB and glass layers, which result in enhanced capacity consistent with the bending theory of existing analytical models.EPSRC Grant Reference No. EP/L016095/1 and ICE Research and Development Enabling Fun

    Rapid pretreatment of Miscanthus using the low-cost ionic liquid triethylammonium hydrogen sulfate at elevated temperatures

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    Deconstruction with low-cost ionic liquids (ionoSolv) is a promising method to pre-condition lignocellulosic biomass for the production of renewable fuels, materials and chemicals. This study investigated process intensification strategies for the ionoSolv pretreatment of Miscanthus X giganteus using the low-cost ionic liquid triethylammonium hydrogen sulfate ([TEA][HSO4]) in the presence of 20 wt% water, using high temperatures and a high solid to solvent loading of 1:5 g/g. The temperatures investigated were 150, 160, 170 and 180°C. We discuss the effect of pretreatment temperature on lignin and hemicellulose removal, cellulose degradation and enzymatic saccharification yields. We report that very good fractionation can be achieved across all investigated temperatures, including an enzymatic saccharification yield exceeding 75% of the theoretical maximum after only 15 min of treatment at 180°C. We further characterised the recovered lignins which established some tunability of the hydroxyl group content, subunit composition, connectivity and molecular weight distribution in the isolated lignin while maintaining maximum saccharification yield. This drastic reduction of pretreatment time at increased biomass loading without a yield penalty is promising for the development of a commercial ionoSolv pretreatment process
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