Spectrally narrowed edge emission from leaky waveguide modes in organic light-emitting diodes

A dramatic spectral line narrowing of the edge emission at room temperature from tris(quinolinolate) Al (Alq3), N,N′-diphenyl-N,N′-bis(1-naphthylphenyl)-1,1′-biphenyl-4,4′-diamine (NPD), 4,4′-bis(2,2′-diphenyl-vinyl)-,1′-biphenyl (DPVBi), and some guest-host small molecular organic light-emitting diodes(OLEDs), fabricated on indium tin oxide (ITO)-coated glass, is described. In all but the DPVBi OLEDs, the narrowed emission band emerges above a threshold thickness of the emitting layer, and narrows down to a full width at half maximum of only 5–10 nm. The results demonstrate that this narrowed emission is due to irregular waveguide modes that leak from the ITO to the glass substrate at a grazing angle. While measurements of variable stripe length l devices exhibit an apparent weak optical gain 0≤g≤1.86 cm−1, there is no observable threshold current or bias associated with this spectral narrowing. In addition, in the phosphorescent guest-host OLEDs, there is no decrease in the emission decay time of the narrowed edge emission relative to the broad surface emission. It is suspected that the apparent weak optical gain is due to misalignment of the axis of the waveguided mode and the axis of the collection lens of the probe. However, it is not clear if such a misalignment can account for all the effects of the observed evolution of the edge-emission spectra with l

Spectrally narrowed edge emission from organic light-emitting diodes

A dramatic spectrally narrowed edge emission (SNEE) from small molecular organic light-emitting diodes at room temperature, with a full width at half maximum of 5–10nm, is described. The results show that this emission is due to irregular waveguide modes that leak from the indium tin oxide anode to the glass substrate at a grazing angle. Measurements of variable stripe length devices exhibit an apparent weak optical gain, but there is no observable threshold bias associated with this SNEE. Hence this apparent “optical gain” is suspected to result from misalignment of the propagating leaky waveguide mode and the collecting optics

Ligand binding site structure influences the evolution of protein complex function and topology

Summary: It has been suggested that the evolution of protein complexes is significantly influenced by stochastic, non-adaptive processes. Using ligand binding as a proxy of function, we show that the structure of ligand-binding sites significantly influences the evolution of protein complexes. We show that homomers with multi-chain binding sites (MBSs) evolve new functions slower than monomers or other homomers, and those binding cofactors and metals have more conserved quaternary structure than other homomers. Moreover, the ligands and ligand-binding pockets of homologous MBS homomers are more similar than monomers and other homomers. Our results suggest strong evolutionary selection for quaternary structure in cofactor-binding MBS homomers, whereas neutral processes are more important in complexes with single-chain binding sites. They also have pharmacological implications, suggesting that complexes with single-chain binding sites are better targets for selective drugs, whereas MBS homomers are good candidates for broad-spectrum antibiotic and multitarget drug design. : Homomers with ligand binding sites involving multiple protein chains (MBS homomers) evolve new functions slower than other homomers and monomers, and the ones binding cofactors/metals also have more conserved quaternary structure (QS). These complexes are likely to be promising targets for antibiotics and multitarget drugs. Keywords: protein complex evolution, neutral evolution, heteromers, drug design, polypharmacology, homomers, ligand bindin

The intriguing evolutionary dynamics of plant mitochondrial DNA

The mitochondrial genome of plants is-in every respect and for yet unclear reasons-very different from the well-studied one of animals. Thanks to next-generation sequencing technologies, Davila et al. precisely characterized the role played by recombination and DNA repair in controlling mitochondrial variations in Arabidopsis thaliana, thus opening new perspectives on the long-term evolution of this intriguing genome

Shelf-edge frontal structure in the central East China Sea and its impact on low-frequency acoustic propagation

Author Posting. © IEEE, 2004. This article is posted here by permission of IEEE for personal use, not for redistribution. The definitive version was published in IEEE Journal of Oceanic Engineering 29 (2004): 1011-1031, doi:10.1109/JOE.2004.840842.Two field programs, both parts of the Asian Seas International Acoustics Experiment (ASIAEX), were carried out in the central East China Sea (28 to 30 N, 126 30 to 128 E) during April 2000 and June 2001. The goal of these programs was to study the interactions between the shelf edge environment and acoustic propagation at a wide range of frequencies and spatial scales. The low-frequency across-slope propagation was studied using a synthesis of data collected during both years including conductivity- temperature-depth (CTD) and mooring data from 2000, and XBT, thermistor chain, and wide-band source data from 2001. The water column variability during both years was dominated by the Kuroshio Current flowing from southwest to northeast over the continental slope. The barotropic tide was a mixed diurnal/semidiurnal tide with moderate amplitude compared to other parts of the Yellow and East China Sea. A large amplitude semidiurnal internal tide was also a prominent feature of the data during both years. Bursts of high-frequency internal waves were often observed, but these took the form of internal solitons only once, when a rapid off-shelf excursion of the Kuroshio coincided with the ebbing tide. Two case studies in the acoustic transmission loss (TL) over the continental shelf and slope were performed. First, anchor station data obtained during 2000 were used to study how a Kuroshio warm filament on the shelf induced variance in the transmission loss (TL) along the seafloor in the NW quadrant of the study region. The corresponding modeled single-frequency TL structure explained the significant fine-scale variability in time primarily by the changes in the multipath/multimode interference pattern. The interference was quite sensitive to small changes in the phase differences between individual paths/modes induced by the evolution of the warm filament. Second, the across-slope sound speed sections from 2001 were used to explain the observed phenomenon of abrupt signal attenuation as the transmission range lengthened seaward across the continental shelf and slope. This abrupt signal degradation was caused by the Kuroshio frontal gradients that produced an increasingly downward-refracting sound-speed field seaward from the shelf break. This abrupt signal dropout was explained using normal mode theory and was predictable and source depth dependent. For a source located above the turning depth of the highest-order shelf-trapped mode, none of the propagating modes on the shelf were excited, causing total signal extinction on the shelf

Pan-Antarctic analysis aggregating spatial estimates of Adélie penguin abundance reveals robust dynamics despite stochastic noise

© The Author(s), 2017. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Nature Communications 8 (2017): 832, doi:10.1038/s41467-017-00890-0.Colonially-breeding seabirds have long served as indicator species for the health of the oceans on which they depend. Abundance and breeding data are repeatedly collected at fixed study sites in the hopes that changes in abundance and productivity may be useful for adaptive management of marine resources, but their suitability for this purpose is often unknown. To address this, we fit a Bayesian population dynamics model that includes process and observation error to all known Adélie penguin abundance data (1982–2015) in the Antarctic, covering >95% of their population globally. We find that process error exceeds observation error in this system, and that continent-wide “year effects” strongly influence population growth rates. Our findings have important implications for the use of Adélie penguins in Southern Ocean feedback management, and suggest that aggregating abundance across space provides the fastest reliable signal of true population change for species whose dynamics are driven by stochastic processes.H.J.L., C.C.-C., G.H., C.Y., and K.T.S. gratefully acknowledge funding provided by US National Aeronautics and Space Administration Award No. NNX14AC32G and U.S. National Science Foundation Office of Polar Programs Award No. NSF/OPP-1255058. S.J., L.L., M.M.H., Y.L., and R.J. gratefully acknowledge funding provided by US National Aeronautics and Space Administration Award No. NNX14AH74G. H.J.L., C.Y., S.J., Y.L., and R.J. gratefully acknowledge funding provided by U.S. National Science Foundation Office of Polar Programs Award No. NSF/PLR-1341548. S.J. gratefully acknowledges support from the Dalio Explore Fund

Overview of results from the Asian Seas International Acoustics Experiment in the East China Sea

Author Posting. © IEEE, 2004. This article is posted here by permission of IEEE for personal use, not for redistribution. The definitive version was published in IEEE Journal of Oceanic Engineering 29 (2004): 920-928, doi:10.1109/JOE.2005.843159.The Asian Seas International Acoustics Experiment (ASIAEX) included two major field programs, one in the South China Sea and the other in the East China Sea (ECS). This paper presents an overview of research results from ASIAEX ECS conducted between May 28 and June 9, 2001. The primary emphasis of the field program was shallow-water acoustic propagation, focused on boundary interaction and geoacoustic inversion. The study area's central point was located at 29/spl deg/ 40.67'N, 126/spl deg/ 49.39'E, which is situated 500 km east of the Chinese coastline off Shanghai. The acoustic and supporting environmental measurements are summarized, along with research results to date, and references to papers addressing specific issues in more detail are given.This work was supported by the U.S. Office of Naval Research under Code 321 OA and by sponsoring agencies within China. Primary guidance and sponsorship for ASIAEX East China Sea came from the U.S. Office of Naval Research and significant financial support was also received from sponsoring agencies within China