Development of a high strength Al-Mg2Si-Mg-Zn based alloy for high pressure die casting

A high strength Al-Mg2Si-Mg-Zn based alloy has been developed for the application in high pressure die casting to provide improved mechanical properties. The effect of various alloying elements on the microstructure and mechanical properties including yield strength, ultimate tensile strength and elongation of the alloy was investigated under the as-cast and heat-treated conditions. The typical composition of the high strength alloy has been optimised to be Al-8.0wt%Mg2Si-6.0wt%Mg-3.5wt%Zn-0.6wt%Mn (Al-11.0wt%Mg-2.9wt%Si-3.5wt%Zn-0.6wt%Mn) with unavoidable trace impurities. The mechanical properties of the alloy were enhanced by a quick solution treatment followed by ageing treatment. The improved tensile properties were at a level of yield strength over 300MPa, the ultimate tensile strength over 420MPa and the elongation over 3% assessed using international standard tensile samples made by high pressure die casting. The microstructure of the die-cast alloy consisted of the primary α-Al phase, Al-Mg2Si eutectics, AlMgZn intermetallics and α-AlFeMnSi intermetallics under the as-cast condition. The AlMgZn intermetallic compound was dissolved into the Al-matrix during solution treatment and subsequently precipitated during ageing treatment for providing the effective improvement of the mechanical properties.The financial support is gratefully acknowledged for the Engineering and Physical Sciences Research Council (EPSRC) (Project number: EP/I038616/1), Technology Strategy Board (TSB) (Project number: 101172) and Jaguar Land Rover (JLR), United Kingdom

Processes and continuous change in a SAT-based planner

AbstractThe TM-LPSAT planner can construct plans in domains containing atomic actions and durative actions; events and processes; discrete, real-valued, and interval-valued fluents; reusable resources, both numeric and interval-valued; and continuous linear change to quantities. It works in three stages. In the first stage, a representation of the domain and problem in an extended version of PDDL+ is compiled into a system of Boolean combinations of propositional atoms and linear constraints over numeric variables. In the second stage, a SAT-based arithmetic constraint solver, such as LPSAT or MathSAT, is used to find a solution to the system of constraints. In the third stage, a correct plan is extracted from this solution. We discuss the structure of the planner and show how planning with time and metric quantities is compiled into a system of constraints. The proofs of soundness and completeness over a substantial subset of our extended version of PDDL+ are presented

On-Chip Matching Networks for Radio-Frequency Single-Electron-Transistors

In this letter, we describe operation of a radio-frequency superconducting single electron transistor (RF-SSET) with an on-chip superconducting LC matching network consisting of a spiral inductor L and its capacitance to ground. The superconducting network has a lower parasitic capacitance and gives a better matching for the RF-SSET than does a commercial chip inductor. Moreover, the superconducting network has negligibly low dissipation, leading to sensitive response to changes in the RF-SSET impedance. The charge sensitivity 2.4*10^-6 e/(Hz)^1/2 in the sub-gap region and energy sensitivity of 1.9 hbar indicate that the RF-SSET is operating in the vicinity of the shot noise limit.Comment: 3 pages, 3 figures, REVTeX 4. To appear in Appl. Phys. Let

Simulations of a Magnetic Fluctuation Driven Large Scale Dynamo and Comparison with a Two-scale Model

Models of large scale (magnetohydrodynamic) dynamos (LSD) which couple large scale field growth to total magnetic helicity evolution best predict the saturation of LSDs seen in simulations. For the simplest so called "{\alpha}2" LSDs in periodic boxes, the electromotive force driving LSD growth depends on the difference between the time-integrated kinetic and current helicity associated with fluctuations. When the system is helically kinetically forced (KF), the growth of the large scale helical field is accompanied by growth of small scale magnetic (and current) helicity which ultimately quench the LSD. Here, using both simulations and theory, we study the complementary magnetically forced(MF) case in which the system is forced with an electric field that supplies magnetic helicity. For this MF case, the kinetic helicity becomes the back-reactor that saturates the LSD. Simulations of both MF and KF cases can be approximately modeled with the same equations of magnetic helicity evolution, but with complementary initial conditions. A key difference between KF and MF cases is that the helical large scale field in the MF case grows with the same sign of injected magnetic helicity, whereas the large and small scale magnetic helicities grow with opposite sign for the KF case. The MF case can arise even when the thermal pressure is approximately smaller than the magnetic pressure, and requires only that helical small scale magnetic fluctuations dominate helical velocity fluctuations in LSD driving. We suggest that LSDs in accretion discs and Babcock models of the solar dynamo are actually MF LSDs.Comment: 12 pages, 34 figure

A Linear Epitope in the N-Terminal Domain of CCR5 and Its Interaction with Antibody.

The CCR5 receptor plays a role in several key physiological and pathological processes and is an important therapeutic target. Inhibition of the CCR5 axis by passive or active immunisation offers one very selective strategy for intervention. In this study we define a new linear epitope within the extracellular domain of CCR5 recognised by two independently produced monoclonal antibodies. A short peptide encoding the linear epitope can induce antibodies which recognise the intact receptor when administered colinear with a tetanus toxoid helper T cell epitope. The monoclonal antibody RoAb 13 is shown to bind to both cells and peptide with moderate to high affinity (6x10^8 and 1.2x107 M-1 respectively), and binding to the peptide is enhanced by sulfation of tyrosines at positions 10 and 14. RoAb13, which has previously been shown to block HIV infection, also blocks migration of monocytes in response to CCR5 binding chemokines and to inflammatory macrophage conditioned medium. A Fab fragment of RoAb13 has been crystallised and a structure of the antibody is reported to 2.1 angstrom resolution

Formation and sedimentation of Fe-rich intermetallics in Al−Si−Cu−Fe alloy

Formation and sedimentation of Fe-rich intermetallics were studied in a commercial Al−Si−Cu−Fe alloy with extra additions of Mn. It is found that the introduction of extra Mn is an effective approach to lower the Fe level in the equilibrium liquid phase after sedimentation of solid Fe-rich phase at a temperature between its liquidus and solidus. The higher Mn/Fe mass ratio results in the lower Fe content in the retained alloy, during which Mn is also consumed and settled at the bottom of the melt as solid Fe-rich intermetallics. Therefore, the final Fe content in the alloy can be controlled by the Mn content and the holding temperature of the melt. The results confirmed a good agreement of the theoretical calculation and the experimental test with a specially designed 50 mm cylindrical casting. The sedimentation of Fe-rich intermetallics in the Al−Si−Cu−Fe alloy is completed at 600 °C after 10 min. The reduction of Fe content in the retained alloy is 31.4% when m(Mn)/m(Fe)=0.5 and 53.3% when m(Mn)/m(Fe)=1.0 in comparison with that in the original alloy. The settled Fe-rich intermetallics were identified as α-Al15(Fe,Mn)3Si2, which provided the lower balanced Fe concentration in the melt in comparison with other Fe-rich intermetallics.The financial support from TSB (UK) under project No. 101172 is acknowledged. The authors also would like to thank the EPSRC (UK) and Jaguar Cars Ltd. (UK) for financial support under the grant for the EPSRC Centre - LiME

Remote silicate supply regulates spring phytoplankton bloom magnitude in the Gulf of Maine

© The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Zang, Z., Ji, R., Liu, Y., Chen, C., Li, Y., Li, S., & Davis, C. S. Remote silicate supply regulates spring phytoplankton bloom magnitude in the Gulf of Maine. Limnology and Oceanography Letters, 7, (2022): 277-285, https://doi.org/10.1002/lol2.10245.Spring phytoplankton blooms in the Gulf of Maine (GoM) are sensitive to climate-related local and remote forcing. Nutrient supply through the slope water intrusion has been viewed as critical in regulating the GoM spring blooms, with an assumption that nitrogen is the primary limiting nutrient. In recent years, this paradigm has been challenged, with silicate being recognized as another potential limiting nutrient, but the source of silicate and its associated water mass remain difficult to be determined. In this study, a time series of spring bloom magnitude was constructed using a self-organizing map algorithm, and then correlated with the fluctuation of water composition in the deep Northeast Channel. The results reveal the importance of silicate supply from previously less-recognized deep Scotian Shelf Water inflow. This study offers a new hypothesis for spring bloom regulation, providing a better understanding of mechanisms controlling the spring bloom magnitude in the GoM.This study was supported by NOAA Coastal and Ocean Climate Application (COCA) Program (NA17OAR4310273) and NSF Northeast US Shelf-Long-Term Ecological Research (NES-LTER) Program (OCE-1655686)

Effect of strain-induced precipitation on the recrystallization kinetics in a model alloy

The effects of Nb addition on the recrystallization kinetics and the recrystallized grain size distribution after cold deformation were investigated by using Fe-30Ni and Fe-30Ni-0.044 wt pct Nb steel with comparable starting grain size distributions. The samples were deformed to 0.3 strain at room temperature followed by annealing at 950 °C to 850 °C for various times; the microstructural evolution and the grain size distribution of non- and fully recrystallized samples were characterized, along with the strain-induced precipitates (SIPs) and their size and volume fraction evolution. It was found that Nb addition has little effect on recrystallized grain size distribution, whereas Nb precipitation kinetics (SIP size and number density) affects the recrystallization Avrami exponent depending on the annealing temperature. Faster precipitation coarsening rates at high temperature (950 °C to 900 °C) led to slower recrystallization kinetics but no change on Avrami exponent, despite precipitation occurring before recrystallization. Whereas a slower precipitation coarsening rate at 850 °C gave fine-sized strain-induced precipitates that were effective in reducing the recrystallization Avrami exponent after 50 pct of recrystallization. Both solute drag and precipitation pinning effects have been added onto the JMAK model to account the effect of Nb content on recrystallization Avrami exponent for samples with large grain size distributions

Reflecting on non-reflective action: An exploratory think-aloud study of self-report habit measures

Objectives. Within health psychology, habit – the tendency to enact action automatically as a learned response to contextual cues – is most commonly quantified using the ‘Self-Report Habit Index’, which assesses behavioural automaticity, or measures combining self-reported behaviour frequency and context stability. Yet, the use of self-report to capture habit has proven controversial. This study used ‘think aloud’ methods to investigate problems experienced when completing these two measures. Design. Cross-sectional survey with think-aloud study. Methods. Twenty student participants narrated their thoughts while completing habit measures applied to four health-related behaviours (active commuting, unhealthy snacking, and one context-free and one context-specific variant of alcohol consumption). Data were coded using thematic analysis procedures. Results. Problems were found in 10% of responses. Notable findings included participants lacking confidence in reporting automaticity, struggling to recall behaviour or cues, differing in interpretations of ‘commuting’, and misinterpreting items. Conclusions. While most responses were unproblematic, and further work is needed to investigate habit self-reports among larger and more diverse samples, findings nonetheless question the sensitivity of the measures, and the conceptualisation of habit underpinning common applications of them. We offer suggestions to minimise these problems

Influence of ocean freshening on shelf phytoplankton dynamics

Author Posting. © American Geophysical Union, 2007. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 34 (2007): L24607, doi:10.1029/2007GL032010.Climate change-induced freshening of the ocean can enhance vertical stratification and alter circulation patterns in ways that influence phytoplankton dynamics. We examined the timing of spring phytoplankton blooms and the magnitude of net primary productivity in the Nova Scotian Shelf (NSS) - Gulf of Maine (GoM) region with respect to seasonal and interannual changes in surface water freshening from 1998 to 2006. The general pattern of temporal westward progression of the phytoplankton bloom corresponds with the gradient of increasing sea surface salinity from the NSS in the east to the western GoM. Increased freshening enhances the spatial gradients in bloom timing by stimulating earlier blooms upstream (NSS), but it has less impact downstream (the western GoM). Strong spatial gradients (increasing westward) of mean chlorophyll concentration and net primary productivity during post-bloom months (May–June) indicate that lower sea surface salinity upstream can likely impede nutrient fluxes from deep water and therefore affect overall productivity.We thank NSF grant OCE-0727033 and NOAA grant NA17RJ1223 to RJ, CSD and RCB, NSF grants OCE- 0606612 and OCE-0726577 to DWT, and NSF grants OCE-0606928 and OCE-0726851 to CC