7,491 research outputs found
Predictive transient-following control of shunt and series active power filters
Published versio
A novel application of phosphogypsum: Treatment of a diamond mine\'s slimes tailings
Premier Mine\'s current slimes dam is nearing the end of its operational life. This is aggravated by a large volume of poor quality
water in the dam which is not being recycled back into the process. The poor quality water is the result of a stable colloidal suspension formed from the dominant clay species present in the kimberlitic ore body.
The main objective of this test work was to clarify the water to improve the quality for reuse. Phosphogypsum has been identified as an alternative coagulant to clarify the slimes dam water at a relatively low cost. Laboratory- and plant-scale test work was done to investigate the optimum gypsum dosage, as well as to determine the most suitable application technique. The test work showed that gypsum can successfully destabilise the colloidal suspension. However, poor settling rates were achieved. This improved when the gypsum was added in a slurry form in two stages. The addition of flocculants to aid in settling
did not have the desired effect, with resultant high consumption and operating costs.
Toxicity tests indicated no lethality to Daphnia organisms and showed a positive growth in the algae test. The establishment
of a monitoring programme will assist in determining the long-term effects of gypsum on the environment. Water SA Vol.32 (4) 2006: pp.489-49
Higher derivative type II string effective actions, automorphic forms and E11
By dimensionally reducing the ten-dimensional higher derivative type IIA
string theory effective action we place constraints on the automorphic forms
that appear in the effective action in lower dimensions. We propose a number of
properties of such automorphic forms and consider the prospects that E11 can
play a role in the formulation of the higher derivative string theory effective
action.Comment: 34 page
Constraints on Automorphic Forms of Higher Derivative Terms from Compactification
By dimensionally reducing the higher derivative corrections of
ten-dimensional IIB theory on a torus we deduce constraints on the E_{n+1}
automorphic forms that occur in d=10-n dimensions. In particular we argue that
these automorphic forms involve the representation of E_{n+1} with fundamental
weight \lambda^{n+1}, which is also the representation to which the string
charges in d dimensions belong. We also consider a similar calculation for the
reduction of higher derivative terms in eleven-dimensional M-theory.Comment: Minor corrections, to appear in JHE
Inverse molecular design from first principles: Tailoring organic chromophore spectra for optoelectronic applications
The discovery of molecules with tailored optoelectronic properties, such as specific frequency and intensity of absorption or emission, is a major challenge in creating next-generation organic light-emitting diodes (OLEDs) and photovoltaics. This raises the following question: How can we predict a potential chemical structure from these properties? Approaches that attempt to tackle this inverse design problem include virtual screening, active machine learning, and genetic algorithms. However, these approaches rely on a molecular database or many electronic structure calculations, and significant computational savings could be achieved if there was prior knowledge of (i) whether the optoelectronic properties of a parent molecule could easily be improved and (ii) what morphing operations on a parent molecule could improve these properties. In this Perspective, we address both of these challenges from first principles. We first adapt the Thomas-Reiche-Kuhn sum rule to organic chromophores and show how this indicates how easily the absorption and emission of a molecule can be improved. We then show how by combining electronic structure theory and intensity borrowing perturbation theory we can predict whether or not the proposed morphing operations will achieve the desired spectral alteration, and thereby derive widely applicable design rules. We go on to provide proof-of-concept illustrations of this approach to optimizing the visible absorption of acenes and the emission of radical OLEDs. We believe that this approach can be integrated into genetic algorithms by biasing morphing operations in favor of those that are likely to be successful, leading to faster molecular discovery and greener chemistry
On chains in -closed topological pospaces
We study chains in an -closed topological partially ordered space. We give
sufficient conditions for a maximal chain in an -closed topological
partially ordered space such that contains a maximal (minimal) element.
Also we give sufficient conditions for a linearly ordered topological partially
ordered space to be -closed. We prove that any -closed topological
semilattice contains a zero. We show that a linearly ordered -closed
topological semilattice is an -closed topological pospace and show that in
the general case this is not true. We construct an example an -closed
topological pospace with a non--closed maximal chain and give sufficient
conditions that a maximal chain of an -closed topological pospace is an
-closed topological pospace.Comment: We have rewritten and substantially expanded the manuscrip
Holographic non-perturbative corrections to gauge couplings
We give a direct microscopic derivation of the F-theory background that
corresponds to four D7 branes of type I' theory by taking into account the
D-instanton contributions to the emission of the axio-dilaton field in the
directions transverse to the D7's. The couplings of the axio-dilaton to the
D-instanton moduli modify its classical source terms which are shown to be
proportional to the elements of the D7 brane chiral ring. Solving the bulk
field equations with the non-perturbatively corrected sources yields the full
F-theory background. This solution represents the gravitational dual of the
four-dimensional theory living on a probe D3 brane of type I', namely of the
N=2, Sp(1) SYM theory with Nf=4. Our results provide an explicit microscopic
derivation of the non-perturbative gravitational dual of this theory. They also
explain the recent observation that the exact coupling for this theory can be
entirely reconstructed from its perturbative part plus the knowledge of the
chiral ring on the D7 branes supporting its flavor degrees of freedom.Comment: Latex, 39 pages, 6 figure
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Carbonyl sulfide and carbon disulfide: Large-scale distributions over the western Pacific and emissions from Asia during TRACE-P
An extensive set of carbonyl sulfide (OCS) and carbon disulfide (CS 2) observations were made as part of the NASA Transport and Chemical Evolution over the Pacific (TRACE-P) project, which took place in the early spring 2001. TRACE-P sampling focused on the western Pacific region but in total included the geographic region 110°E to 290°E longitude, 5°N to 50°N latitude, and 0-12 km altitude. Substantial OCS and CS2 enhancements were observed for a great many air masses of Chinese and Japanese origin during TRACE-P. Over the western Pacific, mean mixing ratios of long-lived OCS and shorter-lived CS2 showed a gradual decrease by about 10% and a factor of 5-10, respectively, from the surface to 8-10 km altitude, presumably because land-based sources dominated their distribution during February through April 2001. The highest mean OCS and CS 2 levels (580 and 20 pptv, respectively, based on 2.5° × 2.5° latitude bins) were observed below 2 km near the coast of Asia, at latitudes between 25°N and 35°N, where urban Asian outflow was strongest. Ratios of OCS versus CO for continental SE Asia were much lower compared to Chinese and Japanese signatures and were strongly associated with biomass burning/biofuel emissions. We present a new inventory of anthropogenic Asian emissions (including biomass burning) for OCS and CS2 and compare it to emission estimates based on regional relationships of OCS and CS 2 to CO and CO2. The OCS and CS2 results for the two methods compare well for continental SE Asia and Japan plus Korea and also for Chinese CS2 emissions. However, it appears that the inventory underestimates Chinese emissions of OCS by about 30-100%. This difference may be related to the fact that we did not include natural sources such as wetland emissions in our inventory, although the contributions from such sources are believed to be at a seasonal low during the study period. Uncertainties in OCS emissions from Chinese coal burning, which are poorly characterized, likely contribute to the discrepancy. Copyright 2004 by the American Geophysical Union
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