Temperature effects on the 15-85 mu m spectra of olivines and pyroxenes

Far-infrared spectra of laboratory silicates are normally obtained at room temperature even though the grains responsible for astronomical silicate emission bands seen at wavelengths >20 μm are likely to be at temperatures below ∼150 K. In order to investigate the effect of temperature on silicate spectra, we have obtained absorption spectra of powdered forsterite and olivine, along with two orthoenstatites and diopside clinopyroxene, at 3.5±0.5 K and at room temperature (295±2 K). To determine the changes in the spectra the resolution must be increased from ∼1 to 0.25 cm−1 at both temperatures, because a reduction in temperature reduces the phonon density, thereby reducing the width of the infrared peaks. Several bands observed at 295 K split at 3.5 K. At 3.5 K the widths of isolated single bands in olivine, enstatites and diopside are ∼90 per cent of their 295-K widths. However, in forsterite the 3.5-K widths of the 31-, 49- and 69-μm bands are, respectively, 90, 45 and 31 per cent of their 295-K widths. Owing to an increase in phonon energy as the lattice contracts, 3.5-K singlet peaks occur at shorter wavelengths than do the corresponding 295-K peaks; the magnitude of the wavelength shift increases from ∼0–0.2 μm at 25 μm to ∼0.9 μm at 80 μm. In olivines and enstatites the wavelength shifts can be approximated by polynomials of the form ax+bx2 where x=λpk(295 K) and the coefficients a and b differ between minerals; for diopside this formula gives a lower limit to the shift. Changes in the relative absorbances of spectral peaks are also observed. The temperature dependence of λpk and bandwidth shows promise as a means to deduce characteristic temperatures of mineralogically distinct grain populations. In addition, the observed changes in band strength with temperature will affect estimates of grain masses and relative mineral abundances inferred using room-temperature laboratory data. Spectral measurements of a variety of minerals at a range of temperatures are required to quantify these effects fully

The 69-mu m forsterite band as a dust temperature indicator

A band of pure crystalline forsterite (100 per cent Mg2SiO4) occurs at 69.67 μm at room temperature (295 K); for olivines with ≳10 per cent Fe the corresponding feature is at ≳73 μm. The Mg-rich forsterite feature is observed in a variety of ISO LWS spectra, but the corresponding Fe-rich olivine feature is not. For the 10 astronomical sources in our sample, the forsterite band peaks in the 68.9–69.3 μm range and narrows with decreasing peak wavelength. This is consistent with the shortwards shifting of the peak observed when laboratory samples are cooled to 77 K (69.07 μm) and 3.5 K (68.84 μm). The shifted peak is produced by lattice contraction and the sharpening is due to a decrease in phonon density at lower temperatures. However, the astronomical bands are narrower than those of the laboratory samples. By comparing the laboratory and astronomical peak wavelengths, we deduce characteristic forsterite 69-μm band temperatures that are in the 27–84 K range for the eight post-main-sequence objects in our sample. These values are shown to be consistent with the local continuum temperatures derived using a β=1.5 dust emissivity index, similar to derived interstellar values of the opacity index. For the pre-main sequence-objects HD 100546 and MWC 922, the characteristic 69-μm forsterite band temperatures (127±18 and 139±10 K, respectively) are significantly higher than those of the post-main-sequence objects and are more than twice as high as their local continuum temperatures deduced using β=1.5. The assumption of large grains (β=0) can produce agreement between the derived 69-μm and continuum temperatures for one of these objects but not for the other — a spatial separation between the forsterite and continuum-emitting grains may therefore be implied for it. We conclude that observations of the peak wavelength and FWHM of the 69-μm forsterite band show great promise as a new diagnostic of characteristic grain temperatures

A mid-infrared imaging survey of post-AGB stars

Post-AGB stars are key objects for the study of the dramatic morphological changes of low- to intermediate-mass stars on their evolution from the Asymptotic Giant Branch (AGB) towards the planetary nebula stage. There is growing evidences that binary interaction processes may very well have a determining role in the shaping process of many objects, but so far direct evidence is still weak. We aim at a systematic study of the dust distribution around a large sample of post-AGB stars as a probe of the symmetry breaking in the nebulae around these systems. We used imaging in the mid-infrared to study the inner part of these evolved stars to probe direct emission from dusty structures in the core of post-AGB stars in order to better understand their shaping mechanisms. We imaged a sample of 93 evolved stars and nebulae in the mid-infrared using VISIR/VLT, T-Recs/Gemini South and Michelle/Gemini North. We found that all the the proto-planetary nebulae we resolved show a clear departure from spherical symmetry. 59 out of the 93 observed targets appear to be non resolved. The resolved targets can be divided in two categories. The nebulae with a dense central core, that are either bipolar and multipolar. The nebulae with no central core have an elliptical morphology. The dense central torus observed likely host binary systems which triggered fast outflows that shaped the nebulae

Massive-star supernovae as major dust factories

We present late-time optical and mid-infrared observations of the Type II supernova 2003gd in the galaxy NGC 628. Mid-infrared excesses consistent with cooling dust in the ejecta are observed 499 to 678 days after outburst and are accompanied by increasing optical extinction and growing asymmetries in the emission-line profiles. Radiative-transfer models show that up to 0.02 solar masses of dust has formed within the ejecta, beginning as early as 250 days after outburst. These observations show that dust formation in supernova ejecta can be efficient and that massive-star supernovae could have been major dust producers throughout the history of the universe

Membranes combining chitosan and natural-origin nanoliposomes for tissue engineering

Chitosan thin films, elaborated by solvent casting, were functionalized by incorporating nanoliposomes based on natural vegetable (soy based) and marine (salmon derived) lecithin. The marine lecithin used in this study contains a higher percentage of polyunsaturated fatty acids (PUFAs) and polar lipids compared with vegetal lecithin. The physical-chemistry properties of the obtained films were characterized by water contact angle (WCA), Fourier Transform InfraRed spectroscopy (FT-IR), water uptake test, and Torsional Harmonic Atomic Force Microscopy analysis (TH-AFM). The surface wettability, swelling ratio, roughness and local stiffness of the thin films can be modified and controlled by adding nanoliposomes. The WCA decreased with the increase of the amount of nanoliposomes. Equilibrium water uptakes of about 170% were achieved in 24 h for the different formulations. The FT-IR results showed the existence of chemical interactions between chitosan and nanoliposomes. The surface topography of the films were identical in terms of asymmetry and amplitude distribution of roughness measurements but showed a significant increase of asperity height when incorporating soya nanoliposomes. This variation is accompanied with a decrease in the average of surface rigidity and of adhesive force value, resulting in a heterogeneous surface. The behaviour of human mesenchymal stem cells (hMSCs) cultured on the films was investigated. Results showed that the films favor cell proliferation when the concentration of soya and salmon nanoliposomes is below 2 mg mL(-1) and 4 mg mL(-1), respectively. The highest cell proliferation of hMSCs culture was observed when the concentration of salmon nanoliposomes was 1 mg mL(-1). This work provides evidence that nanoliposome-functionalized chitosan thin films could offer adequate cyto-friendly cell culture supports for hMSCs, and may potentially be used as suitable scaffolds for tissue engineering applications