ELECTROCHEMICAL CORROSION STUDIES CORE 308 SEGMENTS 14R1 & 14R2 TANK 241-AY-102

This document reports the results of electrochemical corrosion tests on AS1S Grade 60 carbon steel coupons exposed to tank 241-AY-102 sludge under conditions similar to those near the bottom of the tank. The tests were performed to evaluate the corrosive behavior of the waste in contact with sludge that does not meet the chemistry control limits of Administrative Control (AC) 5.15, Corrosion Mitigation Program

FINAL ANALYTICAL RESULTS FROM THE EXAMINATION OF CORROSION ON SECTIONS OF CORROSION PROBE REMOVED FROM TANK 241-AN-107 ON 08/10/2006

Tank Farms Operations removed an electrochemical noise probe from Tank 241-AN-107. In the field, the probe was cut into four sections, wrapped, and placed in a 55-gallon drum, This drum was delivered to the 222-S Laboratory. The 222 S Laboratory unpackaged the sections of the AN-107 electrochemical noise probe and examined the material for evidence of corrosion. Each of the four sections contained three C-ring and three bullet specimens. The specimens were examined for pitting corrosion, crevice corrosion, and stress corrosion cracking. No evidence of stress corrosion cracking was found in the stressed C-ring specimens. Minor pitting was evident on some surfaces. Crevice corrosion was the dominant type of corrosion observed

RESULTS OF THE EXAMINATION OF ELECTROCHEMICAL NOISE PROBE SPECIMENS REMOVED FROM TANK 241-AN-107 JUNE 2010

An Integrated Multi-function Corrosion Probe (IMCP) was installed in Tank 241-AN-107 on September 20, 2006. A portion of the probe was retrieved on June 8, 2010 and the sections holding the detectors were delivered to the 222-S Laboratory for analysis. The examination and disassembly of the probe sections encountered a number of challenges. However, disassembly and relevant analyses were successfully completed. The following summarizes our observations. Brittle failure of the fiberglass probe in the middle of detector 2 resulted in the recovery of only three vapor space C-rings and six supernatant bullet specimens. The design of the bullets and how they were attached to the probe made the recovery of the components more difficult. The use of glue/epoxy on the bullets and the attachment of the flat bottom of the bullets to the curved surface of the fiberglass probe body meant that weight loss on cleaning and surface area of the specimens could not be determined with acceptable accuracy. Macrophotography of all specimens reveals that corrosion was slight in the vapor space and extremely slight in the supernatant. The one pre-cracked C-ring recovered from the vapor space still had the stress bulge visible on the polished surface, indicating that crack propagation had not occurred in the tank. No photographs were taken of the C-ring before deployment. No further analysis was conducted on this specimen. A detailed discussion and photographic documentation are provided in this report

RESULTS OF THE EXAMINATION OF ELECTROCHEMICAL NOISE PROBE SPECIMENS REMOVED FROM TANK 241-AN-107 JUNE 2010

An Integrated Multi-function Corrosion Probe (IMCP) was installed in Tank 241-AN-107 on September 20, 2006. A portion of the probe was retrieved on June 8, 2010 and the sections holding the detectors were delivered to the 222-S Laboratory for analysis. The examination and disassembly of the probe sections encountered a number of challenges. However, disassembly and relevant analyses were successfully completed. The following summarizes our observations. Brittle failure of the fiberglass probe in the middle of detector 2 resulted in the recovery of only three vapor space C-rings and six supernatant bullet specimens. The design of the bullets and how they were attached to the probe made the recovery of the components more difficult. The use of glue/epoxy on the bullets and the attachment of the flat bottom of the bullets to the curved surface of the fiberglass probe body meant that weight loss on cleaning and surface area of the specimens could not be determined with acceptable accuracy. Macrophotography of all specimens reveals that corrosion was slight in the vapor space and extremely slight in the supernatant. The one pre-cracked C-ring recovered from the vapor space still had the stress bulge visible on the polished surface, indicating that crack propagation had not occurred in the tank. No photographs were taken of the C-ring before deployment. No further analysis was conducted on this specimen. A detailed discussion and photographic documentation are provided in this report

Type IIn supernovae at z ~ 2 from archival data

Supernovae have been confirmed to redshift z ~ 1.7 for type Ia (thermonuclear detonation of a white dwarf) and to z ~ 0.7 for type II (collapse of the core of the star). The subclass type IIn supernovae are luminous core-collapse explosions of massive stars and, unlike other types, are very bright in the ultraviolet, which should enable them to be found optically at redshifts z ~ 2 and higher. In addition, the interaction of the ejecta with circumstellar material creates strong, long-lived emission lines that allow spectroscopic confirmation of many events of this type at z ~ 2 for 3 - 5 years after explosion. Here we report three spectroscopically confirmed type IIn supernovae, at redshifts z = 0.808, 2.013 and 2.357, detected in archival data using a method designed to exploit these properties at z ~ 2. Type IIn supernovae directly probe the formation of massive stars at high redshift. The number found to date is consistent with the expectations of a locally measured stellar initial mass function, but not with an evolving initial mass function proposed to explain independent observations at low and high redshift.Comment: 8 pages, 2 figures, includes supplementary informatio

The role of government in a partial transition from public to private in the expanding Australian protected area system

Since the 1980s in democratic societies, neoliberal reforms and neofeudal governance have transferred the delivery of many public goods and services from governments to non-government actors. Privatisation is a core neoliberal agenda, but little is known of the nature and extent of its application to nature conservation through reservation. We investigate the degree of privatisation of the expanding protected area system in our case study areas of Australia and Tasmania, hypothesising that governments have: disrupted public agencies managing the protected area estate by repeated reorganisation; diverted public funds from public to private protected areas; and increasingly alienated public reserves for subsidised private profit from tourism. We found frequent restructuring of agencies managing protected areas. Although Federal Government expenditure on private reserves increased markedly in the twenty-first century, so did expenditure on public conservation reserves. All States except Queensland increased public protected area funding. Direct subsidisation of private reserves by government has not had a steady upward trajectory. In contrast, subsidisation of private alienation of public conservation reserves for tourism may have accelerated in the twenty-first century. We conclude that, while Australian governments see value in protected areas as a source of economic development and electoral advantage, they are agnostic on ownership

ANALYSIS RESULTS FOR BUILDING 241 702-AZ A TRAIN

This report presents the analyses results for three samples obtained under RPP-PLAN-28509, Sampling and Analysis Plan for Building 241 702-AZ A Train. The sampling and analysis was done in response to problem evaluation request number PER-2004-6139, 702-AZ Filter Rooms Need Radiological Cleanup Efforts

Exploring differential item functioning in the SF-36 by demographic, clinical, psychological and social factors in an osteoarthritis population

The SF-36 is a very commonly used generic measure of health outcome in osteoarthritis (OA). An important, but frequently overlooked, aspect of validating health outcome measures is to establish if items work in the same way across subgroup of a population. That is, if respondents have the same 'true' level of outcome, does the item give the same score in different subgroups or is it biased towards one subgroup or another. Differential item functioning (DIF) can identify items that may be biased for one group or another and has been applied to measuring patient reported outcomes. Items may show DIF for different conditions and between cultures, however the SF-36 has not been specifically examined in an osteoarthritis population nor in a UK population. Hence, the aim of the study was to apply the DIF method to the SF-36 for a UK OA population. The sample comprised a community sample of 763 people with OA who participated in the Somerset and Avon Survey of Health. The SF-36 was explored for DIF with respect to demographic, social, clinical and psychological factors. Well developed ordinal regression models were used to identify DIF items. Results: DIF items were found by age (6 items), employment status (6 items), social class (2 items), mood (2 items), hip v knee (2 items), social deprivation (1 item) and body mass index (1 item). Although the impact of the DIF items rarely had a significant effect on the conclusions of group comparisons, in most cases there was a significant change in effect size. Overall, the SF-36 performed well with only a small number of DIF items identified, a reassuring finding in view of the frequent use of the SF-36 in OA. Nevertheless, where DIF items were identified it would be advisable to analyse data taking account of DIF items, especially when age effects are the focus of interest

Recent advances in the application of mineral chemistry to exploration for porphyry copper–gold–molybdenum deposits: detecting the geochemical fingerprints and footprints of hypogene mineralization and alteration

In the past decade, significant research efforts have been devoted to mineral chemistrystudies to assist porphyry exploration. These activities can be divided into two majorfields of research: (1) porphyry indicator minerals (PIMs), which are used to identify thepresence of, or potential for, porphyry-style mineralization based on the chemistry ofmagmatic minerals such as zircon, plagioclase and apatite, or resistate hydrothermalminerals such as magnetite; and (2) porphyry vectoring and fertility tools (PVFTs),which use the chemical compositions of hydrothermal minerals such as epidote,chlorite and alunite to predict the likely direction and distance to mineralized centers,and the potential metal endowment of a mineral district. This new generation ofexploration tools has been enabled by advances in and increased access to laserablation-inductively coupled plasma mass spectrometry (LA-ICP-MS), short wavelength infrared (SWIR), visible near-infrared (VNIR) and hyperspectral technologies.PIMs and PVFTs show considerable promise for exploration and are starting to beapplied to the diversity of environments that host porphyry and epithermal depositsglobally. Industry has consistently supported development of these tools, in the case ofPVFTs encouraged by several successful blind tests where deposit centers havesuccessfully been predicted from distal propylitic settings. Industry adoption is steadilyincreasing but is restrained by a lack of the necessary analytical equipment andexpertise in commercial laboratories, and also by the on-going reliance on well-established geochemical exploration techniques (e.g., sediment, soil and rock-chipsampling) that have aided the discovery of near-surface resources over many decades, are now proving less effective in the search for deeply buried mineral resources, and for those concealed under cover

Porphyry Indicator Minerals (PIMS) and Porphyry Vectoring and Fertility Tools (PVFTS) – Indicators of Mineralization Styles and Recorders of Hypogene Geochemical Dispersion Halos

In the past decade, significant research efforts have been devoted to mineral chemistry studies to assist porphyry exploration. These activities can be divided into two major fields of research: (1) porphyry indicator minerals (PIMS), which aims to identify the presence of, or potential for, porphyry-style mineralization based on the chemistry of magmatic minerals such as plagioclase, zircon and apatite, or resistate hydrothermal minerals such as magnetite; and (2) porphyry vectoring and fertility tools (PVFTS), which use the chemical compositions of hydrothermal minerals such as epidote, chlorite and alunite to predict the likely direction and distance to mineralized centres, and the potential metal endowment of a mineral district. This new generation of exploration tools has been enabled by advances in laser ablation-inductively coupled plasma mass spectrometry, short wave length infrared data acquisition and data processing, and the increased availability of microanalytical techniques such as cathodoluminescence. PVFTS and PIMS show considerable promise for porphyry exploration, and are starting to be applied to the diversity of environments that host porphyry and epithermal deposits around the circum-Pacific region. Industry has consistently supported development of these tools, in the case of PVFTS encouraged by several successful “blind tests” where deposit centres have successfully been predicted from distal propylitic settings. Industry adoption is steadily increasing but is restrained by a lack of the necessary analytical equipment and expertise in commercial laboratories.Item freely available with no apparent Creative Commons License or copyright statement. The attached file is the published pdf