Theory of band gap bowing of disordered substitutional II-VI and III-V semiconductor alloys

For a wide class of technologically relevant compound III-V and II-VI semiconductor materials AC and BC mixed crystals (alloys) of the type A(x)B(1-x)C can be realized. As the electronic properties like the bulk band gap vary continuously with x, any band gap in between that of the pure AC and BC systems can be obtained by choosing the appropriate concentration x, granted that the respective ratio is miscible and thermodynamically stable. In most cases the band gap does not vary linearly with x, but a pronounced bowing behavior as a function of the concentration is observed. In this paper we show that the electronic properties of such A(x)B(1-x)C semiconductors and, in particular, the band gap bowing can well be described and understood starting from empirical tight binding models for the pure AC and BC systems. The electronic properties of the A(x)B(1-x)C system can be described by choosing the tight-binding parameters of the AC or BC system with probabilities x and 1-x, respectively. We demonstrate this by exact diagonalization of finite but large supercells and by means of calculations within the established coherent potential approximation (CPA). We apply this treatment to the II-VI system Cd(x)Zn(1-x)Se, to the III-V system In(x)Ga(1-x)As and to the III-nitride system Ga(x)Al(1-x)N.Comment: 14 pages, 10 figure

Clauser-Horne inequality for electron counting statistics in multiterminal mesoscopic conductors

In this paper we derive the Clauser-Horne (CH) inequality for the full electron counting statistics in a mesoscopic multiterminal conductor and we discuss its properties. We first consider the idealized situation in which a flux of entangled electrons is generated by an entangler. Given a certain average number of incoming entangled electrons, the CH inequality can be evaluated for different numbers of transmitted particles. Strong violations occur when the number of transmitted charges on the two terminals is the same ($Q_1=Q_2$), whereas no violation is found for $Q_1\ne Q_2$. We then consider two actual setups that can be realized experimentally. The first one consists of a three terminal normal beam splitter and the second one of a hybrid superconducting structure. Interestingly, we find that the CH inequality is violated for the three terminal normal device. The maximum violation scales as 1/M and $1/M^2$ for the entangler and normal beam splitter, respectively, 2$M$ being the average number of injected electrons. As expected, we find full violation of the CH inequality in the case of the superconducting system.Comment: 26 pages, 9 figures. Ref. adde

Geometric Spin Hall Effect of Light at Polarizing Interfaces

The geometric Spin Hall Effect of Light (geometric SHEL) amounts to a polarization-dependent positional shift when a light beam is observed from a reference frame tilted with respect to its direction of propagation. Motivated by this intriguing phenomenon, the energy density of the light beam is decomposed into its Cartesian components in the tilted reference frame. This illustrates the occurrence of the characteristic shift and the significance of the effective response function of the detector. We introduce the concept of a tilted polarizing interface and provide a scheme for its experimental implementation. A light beam passing through such an interface undergoes a shift resembling the original geometric SHEL in a tilted reference frame. This displacement is generated at the polarizer and its occurrence does not depend on the properties of the detection system. We give explicit results for this novel type of geometric SHEL and show that at grazing incidence this effect amounts to a displacement of multiple wavelengths, a shift larger than the one introduced by Goos-H\"anchen and Imbert-Fedorov effects.Comment: 6 pages, 4 figure

Highly unsaturated fatty acid synthesis in marine fish: Cloning, functional characterization, and nutritional regulation of fatty acyl delta6 desaturase of Atlantic cod (Gadus morhua L.)

Fish contain high levels of the n-3 highly unsaturated fatty acids (HUFA), eicosapentaenoic (EPA) and docosahexaenoic (DHA) acids that are crucial to the health of higher vertebrates. Biosynthesis of HUFA requires enzyme-mediated desaturation of fatty acids. Here we report cloning and functional characterisation of a ∆6 fatty acyl desaturase of Atlantic cod (Gadus morhua), and describe its tissue expression and nutritional regulation. PCR primers were designed based on the sequences of conserved motifs in available fish desaturases and used to isolate a cDNA fragment from liver of cod. The full-length cDNA was obtained by Rapid Amplification of cDNA Ends (RACE). The cDNA for the putative fatty acyl desaturase was shown to comprise 1980bp which included a 5’-UTR of 261bp and a 3’-UTR of 375bp. Sequencing revealed that the cDNA included an ORF of 1344 bp that specified a protein of 447 amino acids. The protein sequence included three histidine boxes, two transmembrane regions, and an N-terminal cytochrome b5 domain containing the haem-binding motif HPGG, all of which are characteristic of microsomal fatty acid desaturases. The cDNA displayed Δ6 desaturase activity in a heterologous yeast expression system. Quantitative real time PCR assay of gene expression in cod showed that the ∆6 desaturase gene, was highly expressed in brain, relatively highly expressed in liver, kidney, intestine, red muscle and gill, and expressed at much lower levels in white muscle, spleen and heart. In contrast, the abundance of a cod fatty acyl elongase transcript was high in brain and gill, with intermediate levels in kidney, spleen, intestine and heart, and relatively low expression in liver. The expression of the Δ6 desaturase gene and the PUFA elongase gene may be under a degree of nutritional regulation, with levels being marginally increased in livers and intestine of fish fed a vegetable oil blend by comparison with levels in fish fed fish oil. However, this was not reflected in increased Δ6 desaturase activity in hepatocytes or enterocytes, which showed very little highly unsaturated fatty acid biosynthesis activity irrespective of diet. The study described has demonstrated that Atlantic cod express a fatty acid desaturase gene with functional Δ6 activity in a yeast expression system. This is consistent with an established hypothesis that the poor ability of marine fish to synthesise HUFA is not due to lack of a Δ6 desaturase, but rather to deficiencies in other parts of the biosynthetic pathway. However, further studies are required to determine why the Δ6 desaturase appears to be barely functional in cod under the conditions tested

Opportunities for Proxemic Interactions in Ubicomp (Keynote)

Abstract. In this keynote presentation, I describe and illustrate proxemic interactions as realized in several projects in my laboratory. My goal is to advocate proxemics as a more natural way of mediating inter-entity interactions in ubiquitous computing environments, while still cautioning about the many pitfalls around its use

A Management Survey by the Naval Officers in the Management Engineering Program

This management survey provides the opportunity for the officers to apply the theoretical and practical concepts and philosophies to an existing and successful industrial concern. It is inevitable that the past experiences and specializations of the officers will be superimposed on their recent scholastic development in their respective survey areas. Major effort has been directed towards molding these concepts into a combined, practicable, and objective approach to the survey. Arrangements for the study were made by the Department of Management Engineering, Rensselaer Polytechnic Institute.Master Table of Contents. VOLUME I: Foreword; Summary of Major Recommendations; Chapter I--Organization; Chapter II — Industrial Relations; Chapter III—Plant Protection; Chapter IV—Plant Property; Chapter V-Office Procedures. VOLUME II: Chapter VI—Accounting; Chapter VII—Traffic; Chapter VIII-Engineering; Chapter IX--Sales, Service, and Advertising Chapter X—Quality Control. VOLUME III: Chapter XI—Manufacturing (Part One); VOLUME IV; Chapter XI (Part Two); hapter XII—Bibliographyhttp://www.archive.org/details/managementsurvey00cla