Which mechanism underlies the water-like anomalies in core-softened potentials?

Using molecular dynamics simulations we investigate the thermodynamic of particles interacting with a continuous and a discrete versions of a core-softened (CS) intermolecular potential composed by a repulsive shoulder. Dynamic and structural properties are also analyzed by the simulations. We show that in the continuous version of the CS potential the density at constant pressure has a maximum for a certain temperature. Similarly the diffusion constant, $D$, at a constant temperature has a maximum at a density $\rho_{\mathrm{max}}$ and a minimum at a density $\rho_{\mathrm{min}}<\rho_{\mathrm{max}}$, and structural properties are also anomalous. For the discrete CS potential none of these anomalies are observed. The absence of anomalies in the discrete case and its presence in the continuous CS potential are discussed in the framework of the excess entropy.Comment: 8 page

Non-adiabatic collapse of a quasi-spherical radiating star

A model is proposed of a collapsing quasi-spherical radiating star with matter content as shear-free isotropic fluid undergoing radial heat-flow with outgoing radiation. To describe the radiation of the system, we have considered both plane symmetric and spherical Vaidya solutions. Physical conditions and thermodynamical relations are studied using local conservation of momentum and surface red-shift. We have found that for existence of radiation on the boundary, pressure on the boundary is not necessary.Comment: 8 Latex pages, No figures, Revtex styl

Adubação não radicular com duas fontes de zinco em Coffea arábica L. "mundo novo" (B.Rodr.) Choussy

A trial was carried out on an eight old coffee plantation with visible zinc problems. The plantation was situated nearly the city of Jaú (22º30'S, 48º30'W). State of São Paulo, Brazil. The soil is classified as medium texture Oxisol of low base saturation (Latossol Vermelho Amarelo - fase arenosa). The pulverization program started in november 1977, followed in march and July 1978 (heavy harvest) and ended in march and July 1979 (light harvest). Is should be mentioned that a well reconized characteristic of arábica coffe is its habit of biennial bearing, a very heavy harvest is most often followed by a light load the next year. The following treatments and amounts of chemicals per cova hole (4 trees) were tested in accordance with a random block design: 1. 1 g of zinc (zinc sulphate, 0.5%) 2. 3 g of nitrogen (urea, 1.3%) 3. 1 g of zinc + 3 g of nitrogen (zinc sulphate 0.5% + urea 1.3%) 4. 0.25 g, 0.50 g, 1.00 g, 2.00 g of zinc plus 0.75 g, 1.50 g, 3.00 g and 6.00 of nitrogen (correspondent to NZN* 15-0-0-5 as 0.75%, 1-5%, 3.0% and 6.0% by v/v). Foliar absorption data were obtained by collecting the 3rd and 4th pairs of the coffee leaves and analysed them for N, P, K, Ca, Mg, S, B, Cu, Fe, Mn, and Zn. The main results may be summarized as follows: 1. The maximum calculated yields of clean coffee were obtained by the applications of 5.84 1 of NZN (1.13%) per hectare. 2. The applications of zinc sulphate (0.5%) and urea (1.3%) together or separate did not affected the coffee bean production. 3. The applications of 15.0 1 of NZN per hectare reduced the coffee yields. 4. Leaf damages and burning symptoms were observed by the applications of urea (1.3%) plus zinc sulphate (0.5%) and larger doses than 7.5 1 of NZN per hectare. 5. Leaf tissue analysis show that the concentrations of the elements were affecred by the age of the leaves and by the yields of the coffee trees. 6. The applications of increasing doses of NZN causes an increase in the concentration of zinc, manganese and boron in the leaves and decreased the concentration in calcium and potassium the leaves. 7. The concentration of zinc in the leaves associated with the heavy harvest, in July, was 70.0 ppm.Em cafezal com 8 anos de idade, com deficiência visível de zinco, situado em um Latossol Amarelo - fase arenosa, do município de Jaú, SP, procederam-se pulverizações em novembro, março e julho de 1978 (grande safra) e março e julho de 1979 (pequena safra), O delineamento experimental foi de blocos ao acaso e constou dos seguintes tratamentos, nas doses por planta: lg de zinco (sulfato de zinco 0,5%), 3g de nitrogênio (uréia 1,3%), lg de zinco + 3g de nitrogênio (sulfato de zinco 0,5% + uréia 1,3%) e 0,25g, 0,50g, 1 ,00g e 2,00g de zinco juntamente com 0,75g, l,50g, 3,00g e 6,00g de nitrogênio (respectivamente NZN 15-0-0-5 * a 0,75%, 3,00% e 6,00% v/v). Na época das pulverizaçoes foram coletadas amostras de 3º e 4º pares de folhas, e determinados os teores de nitrogênio, fósforo, potássio, cálcio, magnésio, boro, cobre, ferro, manganês e zinco. Os resultados mostraram que: a) a produção máxima calculada de café beneficiado foi 3-009,4 kg/ha, obtida com pulverizaçao de 5,84 1 de NZN por hectare (NZN 1 ,17%) ; b) o sulfato de zinco e a uréia, juntos ou isoladamente, não afetaram a produção; c) a dose de 15,0 1 de NZN por hectare diminuiu a produção; d) as aplicações de uréia (1,3%) + sulfato de zinco (0,5%) e de doses de NZN superiores a 7,51/ha provocaram injúrias visíveis nas folhas. Esse efeitos se agravaram com dosagens de 15 1 e 30 1 de NZN por hectare; e) as concentrações dos nutrientes nas folhas foram afetadas de maneira diferente pelas épocas de amostragem e pela produção do cafeeiro; f) a aplicação de doses crescentes de NZN provocou aumento nas concentrações de zinco, manganês e boro e diminuição nas de cálcio e potássio nas folhas, em determinadas épocas da grande ou pequena safra; g) a concentração de zinco em julho, relacionada com a maior produção do cafeeiro, foi 70 ppm

«Transformatio ad optimum»: medicina estética e transumanismo

Transhumanism is a movement that starts from some humanist ideals to reach the posthuman, having as its basic premise the belief that technology can and should be used to control nature. It means, in the midst of technology man leaves being subject to become one of the objects of the new powers. The aim of this paper is to demonstrate that aesthetic medicine is one of the most notorious of the process that requires medicine not only as an activity of healing, but above all as enhancement, which implies a change in the more intimist human condition. In this sense, medicine is integrated into the broader field of technological convergence and bioart. We use Hans Jonas’s theory of responsibility to analyze how this process becomes an ethical issue, requiring a responsible attitude on the part of its agents.O transumanismo e um movimento que parte de alguns ideais humanistas para alcancar o pos-humano, tendo como premissa basica a crenca de que a tecnologia pode e deve ser usada para controlar a natureza. Isso significa que por meio da tecnologia, o homem deixa de ser o sujeito para tornar-se um dos objetos dos novos poderes. Pretende-se, no presente trabalho, demonstrar que a medicina estetica e um dos exemplos mais notorios do processo que exige da medicina nao apenas uma atividade de cura, mas de melhoramento, o que implicaria uma mudanca na condicao mais intima do ser humano. Nesse sentido, a medicina e integrada ao campo mais amplo da convergencia tecnologica e da bioarte. Apela- -se para a teoria da responsabilidade de Hans Jonas para analisar como tal processo se torna uma questao etica, passando a exigir uma atitude responsavel por parte de seus agentes

Nutrição mineral de plantas ornamentais I : absorção de nutrientes pela cultura de gladíolos

Gladiulus corms nº 3 (Gladiolus communis var. Itapetininga) were germinated in pots containing 7 kg of quertz. After germination the plants were irrigated several times a day with HOAGLAND & ARNON (1950) complete solution. Fifteen days after germination plant were harvested every ten days and subdivided in: aerial part, mother corms, daughter corm and bulbils. The different parts of the plants were weight and analysed for nitrogen, phosphorus, potassium, calcium, magnesium, sulphur, boron, copper, iron, manganese and zinco. It was observed that gladiulus plant show a fast growth period until fifty-five days. After this period is shows only increase in weight until seventy five days. A gladiulus plant at final cicle presents 362.6 mg of N; 78.4 mg of P; 536.4 mg of K;73.4 mg of Ca; 27.9 mg of Mg; 35.9 mg of S; 1,019.4 of B; 94.7 ug of Cu; 1,655.6 ug of Fe; 914.6 ug of Mn and 272.3 ug of Zn.Bulbos de gladíolos (Gladiolus communis, var. Itapetininga) foram postos a germinar em vasos com capacidade de 7 kg de silica. Após a germinação, as plantas foram irrigadas com solução nutritiva completa de HOAGLAND & ARNON (1950). Quinze dias, após a germinação e em períodos de 10 dias subsequentes, plantas foram coletadas e divididas em: parte aérea, bulbo velho, bulbo em formação e bulbilhos. Os materiais foram pesados e analisados para nitrogênio, fosforo, potássio, calcio, magnésio, enxofre, boro, cobre, ferro, manganês e zinco. Foi constatado que o gladíolo tem um crescimento acentuado ate aos 55 dias de idade, sendo que após êste período somente aumenta em peso ate aos 75 dias de idade. Uma planta de gladíolo no fim do ciclo acumula 362,6 mg de nitrogênio, 78,4 mg de fosforo, 586,4 mg de potássio, 78,4 mg de calcio, 27,9 mg de magnesio, 35,9 mg de enxofre, 1019,4 ug de boro, 94,7 ug de cobre, 1655,6 ug de ferro, 914,6 ug de manganês e 272,8 ug de zinco. Foi constatado igualmente que os nutrientes contidos no bulbo velho sao insuficientes para a nutrição da planta

In situ crosslinked electrospun gelatin nanofibers for skin regeneration

Due to its intrinsic similarity to the extracellular matrix, gelatin electrospun nanofibrous meshes are promising scaffold structures for wound dressings and tissue engineering applications. However, gelatin is water soluble and presents poor mechanical properties, which generally constitute relevant limitations to its applicability. In this work, gelatin was in situ crosslinked with 1,4-butanediol diglycidyl ether (BDDGE) at different concentrations (2, 4 and 6 wt%) and incubation time-points (24, 48 and 72 h) at 37 °C. The physico-chemical and biological properties of BDDGE-crosslinked electrospun gelatin meshes were investigated. Results show that by changing the BDDGE concentration it is possible to produce nanofibers crosslinked in situ with well-defined morphology and modulate fiber size and mechanical properties. Crosslinked gelatin meshes show no toxicity towards fibroblasts, stimulating their adhesion, proliferation and synthesis of new extracellular matrix, thereby indicating the potential of this strategy for skin tissue engineering.info:eu-repo/semantics/acceptedVersio

A small universe after all?

The cosmic microwave background radiation allows us to measure both the geometry and topology of the universe. It has been argued that the COBE-DMR data already rule out models that are multiply connected on scales smaller than the particle horizon. Here we show the opposite is true: compact (small) hyperbolic universes are favoured over their infinite counterparts. For a density parameter of Omega_o=0.3, the compact models are a better fit to COBE-DMR (relative likelihood ~20) and the large-scale structure data (sigma_8 increases by ~25%).Comment: 4 pages, RevTeX, 7 Figure

Acumulação diferencial de nutrientes por cinco cultivares de milho (Zea mays L.): I - acumulação de macronutrientes

The objective of the present work was to examine the differences in growth, yield, accumulation and transport of nutrients between the cultivars Agroceres 256, Agroceres 504, Centralmex, H-7974 and Piranão. The experiment was carried out in the municipality of Piracicaba, State of São Paulo, Brazil. The soil type was a sandy oxisol of medium fertility, expect for K which was low. The experimental set-up was a randon block design with four replications. Common cultivation practices were followed, and the fertilizer used consisted of 83 g of a formula: 30-120-70, per meter length at planting, and 33 g of the formula: 50-0-45 per meter length as dressing 22 days after germination. The plant population density was 50,000 per hectare. Plants were collected for analysis at 20 days after germination, and there after at intervals of 20 days up to 120 days. The plants were divided into "stems + leaves", tassels, and ears for chemical analysis of N, P, K, Ca, Mg and S. Conclusions: Growth - The cultivars produce maximum quantities of dry matter of 327 to 381 g per plant at the age of 100 to 106 days. - Differences between cultivars in terms of dry matter accumulation in the vegetative parts of the plant is not necessarily relate to the dry weight of the ear. Accumulation of nutrients - There are no differences in the quantity of N, P and K taken-up by the cultivars, although during the period of rapid growth some differences may appear. - Differences in the accumulation of Ca, Mg and S are detected when the quantities of these nutrients approach the maximum. The cultivar H-7974 presented the highest quantities of Ca and Mg where as Agroceres 504 was richest in S. - The maximum level of nutrients are attained in the following period in days: N (89-100); P (101 -120); K (58-66); Ca (75-94); Mg (100-120) and S (93-95). - The maximum quantities taken-up in mg/plant are:N (3,169-3,878);P (541-642); K (3,850-4,693); Ca (582-782); Mg (654-943); S (444-799). Yield - No differences were found between cultivars for grain production. Transport of nutrients - The re were no differences in the amounts of nutrients in the grain between cultivars. - The transport of nutrients into the ears of the different cultivars are the following order (per hectare harvested, 50,000 plants): N (111-143 kg); P (22-30 kg); K (30-45 kg); Ca (0.7-1.1 kg); Mg (10-12 kg) and S (9-13 kg).No presente trabalho, os autores apresentam os resultados de um ensaio de campo empregando os cultivares Agroceres 256, Agroceres 504, Centralmex, H-7974 e Piranão no sentido de aquilatar diferenças no crescimento, produção e acumulação e exportação de nutrientes. O ensaio foi conduzido num regossol de fertilidade mediana, exceto em relação ao K que é baixo, situado no Município de Piracicaba, SP. O delineamento experimental utilizado foi de blocos ao acaso com 4 repetições. Foram seguidas as práticas culturais comuns, e a adubação constituiu de 83 g da fórmula 30-120-70 por metro linear por ocasião do plantio e 33 g por metro linear da fórmula 50-0-4, em cobertura 22 dias após a germinação. Plantas foram coletadas a partir dos 20 dias após a germinação, em intervalos de 20 dias até os 120 dias. As plantas foram divididas em "colmo + folhas", pendão e espiga e analisadas para N, P, K, Ca, Mg e S. Concluíram os autores que diferenças entre cultivares na acumulação de matéria seca na parte vegetativa não se traduzem, necessariamente, por um aumento de peso da matéria seca na espiga. Os cultivares atingem o máximo da quantidade de nutrientes nas seguintes épocas, em dias: N (89-100); P (101-120); K (58-66); Ca (74-94); Mg (100-120); S (93-95). Verificaram, ainda, que as quantidades máximas extraídas em mg/planta são: N (3169-3878); P (541-642); K (3850-4693); Ca (582-782); Mg (654-943); S (444-799). Finalmente, a exportação de nutrientes nas espigas por hectare (50.000 plantas) colhidas é: N (111-143 kg); P (22-30 kg); Ca (0,7-1,1 kg); Mg (10-12kg); S(9-13kg)

Nutrição mineral do cajueiro (Anacardium occidentale L.): II - deficiências dos micronutrientes - nota prévia

Young cashewnut trees were cultivated in purify nutrient solutions in order to identify symptoms of malnutrition. The treatments were: complete solution, -B, -Cu, -Fe, -Mn, -Zn, -Mo. The deficiencies were comproved by chemical analysis of the leaves. Chemical composition of the leaves, expressed in ppm, on dry matter basis is:Na presente nota prévia, os autores relatam as observações iniciais acerca da sintomatologia de carência dos micro nutrientes, obtida em casa-de-vegetação. Observaram que as carências de B e Fe são de fácil identificação ; sendo que as carências em Cu e Zn são complexas e de difícil obtenção. Não conseguiram obter o quadro sintomatológico para o Mo e Mn. Os autores apresentam, em primeira aproximação, os níveis adequados e de carência pela análise foliar

Nutrição mineral de hortaliças: XXVI - absorção de macro e micronutrientes pelo espinafre (Tetragonia expansa Murr.)

Spinach plants were cultivated under field conditions. All manegement practice were observed. Periodically plants were harvested and analysed for N, P, K, Ca, Mg, S, B, Cu, Fe, Mn, Mo and Zn. - The variety presented a continuous growth expressed, in dry matter, until 120 days. - The greatest demand for nutrients occurs between 93 and 106 days. - The maximum absorption of the nutrients by leaves is around the period of 93 to 106 days. - The absorption of Fe by the spinach plants is continuous until at the end of the plant life. - At 90 days the spinach leaves presented the following concentration: N- 2.54%; P- 0.21%; K- 5.64%; Ca- 1.06%; Mg- 0.83%; S- 0.35%; B- 66 ppm; Cu- 15 ppm; Fe- 364 ppm; Mn- 297 ppm; Zn- 139 ppm and Mo- 0.83 ppm. - One plant and 22,222 spinach plants (one ha.) remove the following quantities in nutrients:O presente trabalho teve como finalidade, estudar alguns aspectos da nutrição mineral do espinafre (Tetragonia expansa Murr.) no que concerne à composição química e a avaliação das quantidades de nutrientes extraídos e exportados pela cultura, nas diversas etapas de seu desenvolvimento. Para isto foi instalado um experimento de campo usando as práticas culturais normais. Amostragens periódicas foram feitas de acordo com o desenvolvimento das plantas. Conclui-se que: - a máxima produção de matéria seca das tolhas ocorre nos 93 dias e a época de maior exigência corresponde aos 63 dias; - a época de extração máxima dos nutrientes pelas folhas está entre 93 a 106 dias; - as quantidades extraídas pela parte aérea aos 90 dias, por ha, são: N- 39,7 kg; P- 4,7 kg; K- 120,6 kg; Ca- 24,8 kg; Mg- 16,0 kg; S-5,7 kg; B- 149,4 g; Cu- 34,4 g; Fe- 592,8 g; Mn- 462,2 g; Zn- 147,9 g; Mo- 2,2 g