828 research outputs found
On Calculation of Thermal Conductivity from Einstein Relation in Equilibrium MD
In equilibrium molecular dynamics, Einstein relation can be used to calculate
the thermal conductivity. This method is equivalent to Green-Kubo relation and
it does not require a derivation of an analytical form for the heat current.
However, it is not commonly used as Green-Kubo relationship. Its wide use is
hindered by the lack of a proper definition for integrated heat current (energy
moment) under periodic boundary conditions. In this paper, we developed an
appropriate definition for integrated heat current to calculate thermal
conductivity of solids under periodic conditions. We applied this method to
solid argon and silicon based systems; compared and contrasted with the
Green-Kubo approach.Comment: We updated this manuscript from second version by changing the title
and abstract. This paper is submitted to J. Chem. Phy
The ABCDE primary assessment in the emergency department in medically ill patients:An observational pilot study
Electrical transport measurements in the superconducting state of Bi2212 and Tl2201
Precise measurements of the in-plane microwave surface impedance of
high-quality single crystals of Bi2212 and Tl2201 are used to probe the
relaxation time of nodal quasiparticles in the d-wave superconducting state
through a two-fluid analysis of the microwave conductivity. While this analysis
requires us to posit a form for the frequency-dependent quasiparticle
conductivity, we clearly demonstrate that the extraction of the relaxation rate
is quite insensitive to the assumed shape of the quasiparticle spectrum. The
robustness of the analysis is rooted in the oscillator-strength sum rule and
the fact that we simultaneously measure the real and imaginary parts of the
conductivity. In both Bi2212 and Tl2201 we infer a linear temperature
dependence of the transport relaxation rate 1/tau and a small but finite
zero-temperature intercept. The linear temperature dependence of 1/tau is in
accord with expectations for weak elastic scattering in an unconventional
superconductor with line nodes and a small residual density of states. The same
analysis reveals an onset of inelastic scattering at higher temperatures
similar to that seen in the YBCO superconductors. Finally we extrapolate the
two-fluid model over a range of frequencies up to five times the measurement
frequency, where the extrapolation predicts behaviour that is qualitatively
similar to terahertz conductivity data on Bi2212 thin films. While relaxation
rates in Bi2212 and Tl2201 are substantially higher than in YBCO there are
qualitative similarities between all three materials, and the differences can
likely be attributed to varying levels of static disorder. We therefore
conclude that a universal picture of quasiparticle scattering in the cuprates
is emerging.Comment: 10 pages, 9 figure
An experimental and modeling study on the reactivity of extremely fuel-rich methane/dimethyl ether mixtures
Chemical reactions in stoichiometric to fuel-rich methane/dimethyl ether/air mixtures (fuel air equiva- lence ratio φ=1–20) were investigated by experiment and simulation with the focus on the conversion of methane to chemically more valuable species through partial oxidation. Experimental data from dif- ferent facilities were measured and collected to provide a large database for developing and validating a reaction mechanism for extended equivalence ratio ranges. Rapid Compression Machine ignition delay times and species profiles were collected in the temperature range between 660 and 1052 K at 10 bar and equivalence ratios of φ= 1–15. Ignition delay times and product compositions were measured in a shock tube at temperatures of 630–1500 K, pressures of 20–30 bar and equivalence ratios of φ= 2 and 10. Ad- ditionally, species concentration profiles were measured in a flow reactor at temperatures between 473 and 973 K, a pressure of 6 bar and equivalence ratios of φ= 2, 10, and 20. The extended equivalence ratio range towards extremely fuel-rich mixtures as well as the reaction-enhancing effect of dimethyl ether were studied because of their usefulness for the conversion of methane into chemically valuable species through partial oxidation at these conditions. Since existing reaction models focus only on equivalence ratios in the range of φ= 0.3–2.5, an extended chemical kinetics mechanism was developed that also covers extremely fuel-rich conditions of methane/dimethyl ether mixtures. The measured ignition delay times and species concentration profiles were compared with the predictions of the new mechanism, which is shown to predict well the ignition delay time and species concentration evolution measure- ments presented in this work. Sensitivity and reaction pathway analyses were used to identify the key reactions governing the ignition and oxidation kinetics at extremely fuel-rich conditions
The LAGUNA design study- towards giant liquid based underground detectors for neutrino physics and astrophysics and proton decay searches
The feasibility of a next generation neutrino observatory in Europe is being
considered within the LAGUNA design study. To accommodate giant neutrino
detectors and shield them from cosmic rays, a new very large underground
infrastructure is required. Seven potential candidate sites in different parts
of Europe and at several distances from CERN are being studied: Boulby (UK),
Canfranc (Spain), Fr\'ejus (France/Italy), Pyh\"asalmi (Finland),
Polkowice-Sieroszowice (Poland), Slanic (Romania) and Umbria (Italy). The
design study aims at the comprehensive and coordinated technical assessment of
each site, at a coherent cost estimation, and at a prioritization of the sites
within the summer 2010.Comment: 5 pages, contribution to the Workshop "European Strategy for Future
Neutrino Physics", CERN, Oct. 200
Evaluation of the Manual Enzyme Immunoassay (EMIT) Procedure for Determination of Serum Thyroxine
Peer Reviewe
Ground State Vortex Lattice Structures in d-wave Superconductors
We show in a realistic symmetry gap model for a cuprate
superconductor that the clean vortex lattice has discontinuous structural
transitions (at and near T=0), as a function of the magnetic field along
the c-axis. The transitions arise from the singular nonlocal and anisotropic
susceptibility of the superconductor to the perturbation
caused by supercurrents associated with vortices. The susceptibility, due to
virtual Dirac quasiparticle-hole excitation, is calculated carefully, and leads
to a ground state transition for the triangular lattice from an orientation
along one of the crystal axis to one at 45 to them, i.e, along the gap zero
direction. The field scale is seen to be 5 Tesla , where is the gap maximum, is the
nearest neighbour hopping, is the lattice constant, and is the
flux quantum. At much higher fields () there is a discontinuous
transition to a centred square structure. The source of the differences from
existing calculations, and experimental observability are discussed, the latter
especially in view of the very small (a few degrees per vortex) differences
in the ground state energy.Comment: To be published in Phys. Rev.
Climate adaptation and speciation : particular focus on reproductive barriers in Ficedula flycatchers
Climate adaptation is surprisingly rarely reported as a cause for the build-up of reproductive isolation between diverging populations. In this review, we summarize evidence for effects of climate adaptation on pre- and postzygotic isolation between emerging species with a particular focus on pied (Ficedula hypoleuca) and collared (Ficedula albicollis) flycatchers as a model for research on speciation. Effects of climate adaptation on prezygotic isolation or extrinsic selection against hybrids have been documented in several taxa, but the combined action of climate adaptation and sexual selection is particularly well explored in Ficedula flycatchers. There is a general lack of evidence for divergent climate adaptation causing intrinsic postzygotic isolation. However, we argue that the profound effects of divergence in climate adaptation on the whole biochemical machinery of organisms and hence many underlying genes should increase the likelihood of genetic incompatibilities arising as side effects. Fast temperature-dependent co-evolution between mitochondrial and nuclear genomes may be particularly likely to lead to hybrid sterility. Thus, how climate adaptation relates to reproductive isolation is best explored in relation to fast-evolving barriers to gene flow, while more research on later stages of divergence is needed to achieve a complete understanding of climate-driven speciation.Peer reviewe
- …