Hygroscopicity of the submicrometer aerosol at the high-alpine site Jungfraujoch, 3580 m a.s.l., Switzerland

Data from measurements of hygroscopic growth of submicrometer aerosol with a hygroscopicity tandem differential mobility analyzer (HTDMA) during four campaigns at the high alpine research station Jungfraujoch, Switzerland, are presented. The campaigns took place during the years 2000, 2002, 2004 and 2005, each lasting approximately one month. Hygroscopic growth factors (<i>GF</i>, i.e. the relative change in particle diameter from dry diameter, <i>D</i><sub>0</sub>, to diameter measured at higher relative humidity, RH) are presented for three distinct air mass types, namely for: 1) free tropospheric winter conditions, 2) planetary boundary layer influenced air masses (during a summer period) and 3) Saharan dust events (SDE). The <i>GF</i> values at 85% RH (<i>D</i><sub>0</sub>=100 nm) were 1.40±0.11 and 1.29±0.08 for the first two situations while for SDE a bimodal <i>GF</i> distribution was often found. No phase changes were observed when the RH was varied between 10–90%, and the continuous water uptake could be well described with a single-parameter empirical model. The frequency distributions of the average hygroscopic growth factors and the width of the retrieved growth factor distributions (indicating whether the aerosol is internally or externally mixed) are presented, which can be used for modeling purposes. <br><br> Measurements of size resolved chemical composition were performed with an aerosol mass spectrometer in parallel to the <i>GF</i> measurements. This made it possible to estimate the apparent ensemble mean <i>GF</i> of the organics (<i>GF</i><sub>org</sub>) using inverse ZSR (Zdanovskii-Stokes-Robinson) modeling. <i>GF</i><sub>org</sub> was found to be ~1.20 at <i>a</i><sub>w</sub>=0.85, which is at the upper end of previous laboratory and field data though still in agreement with the highly aged and oxidized nature of the Jungfraujoch aerosol

Forces on Dust Grains Exposed to Anisotropic Interstellar Radiation Fields

Grains exposed to anisotropic radiation fields are subjected to forces due to the asymmetric photon-stimulated ejection of particles. These forces act in addition to the ``radiation pressure'' due to absorption and scattering. Here we model the forces due to photoelectron emission and the photodesorption of adatoms. The ``photoelectric'' force depends on the ambient conditions relevant to grain charging. We find that it is comparable to the radiation pressure when the grain potential is relatively low and the radiation spectrum is relatively hard. The calculation of the ``photodesorption'' force is highly uncertain, since the surface physics and chemsitry of grain materials are poorly understood at present. For our simple yet plausible model, the photodesorption force dominates the radiation pressure for grains with size >~0.1 micron exposed to starlight from OB stars. We find that the anisotropy of the interstellar radiation field is ~10% in the visible and ultraviolet. We estimate size-dependent drift speeds for grains in the cold and warm neutral media and find that micron-sized grains could potentially be moved across a diffuse cloud during its lifetime.Comment: LaTeX(41 pages, 19 figures), submitted to Ap

Design considerations for table-top, laser-based VUV and X-ray free electron lasers

A recent breakthrough in laser-plasma accelerators, based upon ultrashort high-intensity lasers, demonstrated the generation of quasi-monoenergetic GeV-electrons. With future Petawatt lasers ultra-high beam currents of ~100 kA in ~10 fs can be expected, allowing for drastic reduction in the undulator length of free-electron-lasers (FELs). We present a discussion of the key aspects of a table-top FEL design, including energy loss and chirps induced by space-charge and wakefields. These effects become important for an optimized table-top FEL operation. A first proof-of-principle VUV case is considered as well as a table-top X-ray-FEL which may open a brilliant light source also for new ways in clinical diagnostics.Comment: 6 pages, 4 figures; accepted for publication in Appl. Phys.

Coupled wind-forced controls of the Bering–Chukchi shelf circulation and the Bering Strait throughflow: Ekman transport, continental shelf waves, and variations of the Pacific–Arctic sea surface height gradient

AbstractWe develop a conceptual model of the closely co-dependent Bering shelf, Bering Strait, and Chukchi shelf circulation fields by evaluating the effects of wind stress over the North Pacific and western Arctic using atmospheric reanalyses, current meter observations, satellite-based sea surface height (SSH) measurements, hydrographic profiles, and numerical model integrations. This conceptual model suggests Bering Strait transport anomalies are primarily set by the longitudinal location of the Aleutian Low, which drives oppositely signed anomalies at synoptic and annual time scales. Synoptic time scale variations in shelf currents result from local wind forcing and remotely generated continental shelf waves, whereas annual variations are driven by basin scale adjustments to wind stress that alter the magnitude of the along-strait (meridional) pressure gradient. In particular, we show that storms centered over the Bering Sea excite continental shelf waves on the eastern Bering shelf that carry northward velocity anomalies northward through Bering Strait and along the Chukchi coast. The integrated effect of these storms tends to decrease the northward Bering Strait transport at annual to decadal time scales by imposing cyclonic wind stress curl over the Aleutian Basin and the Western Subarctic Gyre. Ekman suction then increases the water column density through isopycnal uplift, thereby decreasing the dynamic height, sea surface height, and along-strait pressure gradient. Storms displaced eastward over the Gulf of Alaska generate an opposite set of Bering shelf and Aleutian Basin responses. While Ekman pumping controls Canada Basin dynamic heights (Proshutinsky et al., 2002), we do not find evidence for a strong relation between Beaufort Gyre sea surface height variations and the annually averaged Bering Strait throughflow. Over the western Chukchi and East Siberian seas easterly winds promote coastal divergence, which also increases the along-strait pressure head, as well as generates shelf waves that impinge upon Bering Strait from the northwest

Electron-Ion Recombination on Grains and Polycyclic Aromatic Hydrocarbons

With the high-resolution spectroscopy now available in the optical and satellite UV, it is possible to determine the neutral/ionized column density ratios for several different elements in a single cloud. Assuming ionization equilibrium for each element, one can make several independent determinations of the electron density. For the clouds for which such an analysis has been carried out, these different estimates disagree by large factors, suggesting that some process (or processes) besides photoionization and radiative recombination might play an important role in the ionization balance. One candidate process is collisions of ions with dust grains. Making use of recent work quantifying the abundances of polycyclic aromatic hydrocarbon molecules and other grains in the interstellar medium, as well as recent models for grain charging, we estimate the grain-assisted ion recombination rates for several astrophysically important elements. We find that these rates are comparable to the rates for radiative recombination for conditions typical of the cold neutral medium. Including grain-assisted ion recombination in the ionization equilibrium analysis leads to increased consistency in the various electron density estimates for the gas along the line of sight to 23 Orionis. However, not all of the discrepancies can be eliminated in this way; we speculate on some other processes that might play a role. We also note that grain-assisted recombination of H+ and He+ leads to significantly lower electron fractions than usually assumed for the cold neutral medium.Comment: LaTeX(12 pages, 8 figures, uses emulateapj5.sty, apjfonts.sty); submitted to ApJ; corrected typo

Effects of relative humidity on aerosol light scattering in the Arctic

Aerosol particles experience hygroscopic growth in the ambient atmosphere. Their optical properties – especially the aerosol light scattering – are therefore strongly dependent on the ambient relative humidity (RH). In-situ light scattering measurements of long-term observations are usually performed under dry conditions (RH>30–40%). The knowledge of this RH effect is of eminent importance for climate forcing calculations or for the comparison of remote sensing with in-situ measurements. This study combines measurements and model calculations to describe the RH effect on aerosol light scattering for the first time for aerosol particles present in summer and fall in the high Arctic. For this purpose, a field campaign was carried out from July to October 2008 at the Zeppelin station in Ny-Ålesund, Svalbard. The aerosol light scattering coefficient σ<sub>sp</sub>(λ) was measured at three distinct wavelengths (λ=450, 550, and 700 nm) at dry and at various, predefined RH conditions between 20% and 95% with a recently developed humidified nephelometer (WetNeph) and with a second nephelometer measuring at dry conditions with an average RH<10% (DryNeph). In addition, the aerosol size distribution and the aerosol absorption coefficient were measured. The scattering enhancement factor <i>f</i>(RH, λ) is the key parameter to describe the RH effect on σ<sub>sp</sub>(λ) and is defined as the RH dependent σ<sub>sp</sub>(RH, λ) divided by the corresponding dry σ<sub>sp</sub>(RH<sub>dry</sub>, λ). During our campaign the average <i>f</i>(RH=85%, λ=550 nm) was 3.24±0.63 (mean ± standard deviation), and no clear wavelength dependence of <i>f</i>(RH, λ) was observed. This means that the ambient scattering coefficients at RH=85% were on average about three times higher than the dry measured in-situ scattering coefficients. The RH dependency of the recorded <i>f</i>(RH, λ) can be well described by an empirical one-parameter equation. We used a simplified method to retrieve an apparent hygroscopic growth factor <i>g</i>(RH), defined as the aerosol particle diameter at a certain RH divided by the dry diameter, using the WetNeph, the DryNeph, the aerosol size distribution measurements and Mie theory. With this approach we found, on average, <i>g</i>(RH=85%) values to be 1.61±0.12 (mean±standard deviation). No clear seasonal shift of <i>f</i>(RH, λ) was observed during the 3-month period, while aerosol properties (size and chemical composition) clearly changed with time. While the beginning of the campaign was mainly characterized by smaller and less hygroscopic particles, the end was dominated by larger and more hygroscopic particles. This suggests that compensating effects of hygroscopicity and size determined the temporal stability of <i>f</i>(RH, λ). During sea salt influenced periods, distinct deliquescence transitions were observed. At the end we present a method on how to transfer the dry in-situ measured aerosol scattering coefficients to ambient values for the aerosol measured during summer and fall at this location

Radiative Torques on Interstellar Grains. III. Dynamics with Thermal Relaxation

In the previous papers in this series, we found that radiative torques can play a major role in the alignment of grains with the interstellar magnetic field. Since the radiative torques can drive the grains to suprathermal rotational speeds, in previous work we made the simplifying assumption that the grain principal axis of greatest moment of inertia is always parallel to the grain angular momentum. This enabled us to describe many of the features of the grain dynamics. However, this assumption fails when the grains enter periods of thermal rotation, which occur naturally in the radiative torque alignment scenario. In the present paper, we relax this assumption and explore the consequences for the grain dynamics. We develop a treatment to follow the grain dynamics including thermal fluctuations and ``thermal flipping'', and show results for one illustrative example. By comparing with a treatment without thermal fluctuations, we see that inclusion of thermal fluctuations can lead to qualitative changes in the grain dynamics. In a future installment in this series, we will use the more complete dynamical treatment developed here to perform a systematic study of grain alignment by radiative torques.Comment: 54 pages, 16 figures, submitted to Ap

The St. Lawrence polynya and the Bering shelf circulation : new observations and a model comparison

Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 111 (2006): C09023, doi:10.1029/2005JC003268.Using 14 year-long instrumented moorings deployed south of St. Lawrence Island, along with oceanographic drifters, we investigate the circulation over the central Bering shelf and the role of polynyas in forming and disseminating saline waters over the shelf. We focus also on evaluating the Gawarkiewicz and Chapman [1995] model of eddy production within coastal polynyas. Principal results include: 1) The northern central shelf near-surface waters exhibit westward flow carrying low-salinity waters from the Alaskan coast in fall and early winter, with consequences for water mass formation and biological production. 2) Within the St. Lawrence polynya, the freshening effect of winter advection is about half as large as the salting effect of surface brine flux resulting from freezing. 3) Brine production over the Bering shelf occurs primarily offshore, rather than within coastal polynyas, even though ice production per unit area is much larger within the polynyas. 4) We find little evidence for the geostrophic flow adjustment predicted by recent polynya models. 5) In contrast to the theoretical prediction that dense water from the polynya is carried offshore by eddies, we find negligible cross-shelf eddy density fluxes within and surrounding the polynya and very low levels of eddy energy that decreased from fall to winter, even though dense water accumulated within the polynya and large cross-shore density gradients developed. 6) It is possible that dense polynya water was advected downstream of our array before appreciable eddy fluxes materialized.This work was supported by National Science Foundation grant OCE9730697 to the University of Alaska and grant OCE9730823 to the University of Washington. S. M. acknowledges the support of the National Science Foundation under OCE9811097 and of NASA under grant NNG04GM69G. The University of Hamburg contributions were funded by the Bundesminister für Bildung und Wissenschaft. Funding for the drifter deployment was made possible by the North Pacific Research Board, grant NPMRI T2130. Manuscript preparation was additionally supported by Office of Naval Research grants N00014-99-1-0345 and N00014-02-1-0305 to the University of Washington

Radiative Torques on Interstellar Grains: II. Grain Alignment

Radiative torques on irregular dust grains, in addition to producing superthermal rotation, play a direct dynamical role in the alignment of interstellar dust with the local magnetic field. The equations governing the orientation of spinning, precessing grains are derived; H_2 formation torques and paramagnetic dissipation are included in the dynamics. Stationary solutions (constant alignment angle and spin rate) are found; these solutions may be stable ("attractors") or unstable ("repellors"). The equations of motion are numerically integrated for three exemplary irregular grain geometries, exposed to anisotropic radiation with the spectrum of interstellar starlight. The resulting "trajectory maps" are classified as "noncyclic", "semicyclic", or "cyclic", with examples of each given. We find that radiative torques result in rapid grain alignment, even in the absence of paramagnetic dissipation. It appears that radiative torques due to starlight can account for the observed alignment of interstellar grains with the Galactic magnetic field.Comment: 34 pages, 21 eps figures, uses aaspp4.sty . Submitted to Ap.