Retirement incentives, individual heterogeneity and labour transitions of employed and unemployed workers

In this paper we analyze the sensitivity of the labour market decisions of workers close to retirement with respect to the incentives created by public regulations. We improve upon the extensive prior literature on the effect of pension incentives on retirement in two ways. First, by modeling the transitions between employment, unemployment and retirement in a simultaneous manner, paying special attention to the transition from unemployment to retirement (which is particularly important in Spain). Second, by considering the influence of unobserved heterogeneity in the estimation of the effect of our (carefully constructed) incentive variables. Using administrative data, we find that, when properly defined, economic incentives have a strong impact on labour market decisions in Spain. Unemployment regulations are shown to be particularly influential for retirement behaviour, along with the more traditional determinants linked to the pension system. Pension variables also have a major bearing on both workers’ reemployment decisions and on the strategic actions of employers. The quantitative impact of the incentives, however, is greatly affected by the existence of unobserved heterogeneity among workers. Its omission leads to sizable biases in the assessment of the sensitivity to economic incentives, a finding that has clear consequences for the credibility of any model-based policy analysis. We confirm the importance of this potential problem in one especially interesting instance: the reform of early retirement provisions undertaken in Spain in 2002. We use a difference-in-difference approach to measure the behavioural reaction to this change, finding a large overestimation when unobserved heterogeneity is not taken into account.Retirement, unemployment, incentives, Pension system, Unobserved, heterogeneity, Spain.

Yield Components in a Signal Grass-Clitoria Mixture Grazed at Different Herbage Allowance

A Signal grass-Clitoria mixture provides good quality forage in the dry tropic of southern Mexico. However, its response in leaf and stem yields to grazing at different daily herbage allowances is not well documented. The objective of this study was to determine available and residual leaf and stem yields in a Signal grass (Brachiaria decumbens)-Clitoria (Clitoria ternatea) mixture grazed at different daily herbage allowance

Forage Yield and Quality of Signal Grass-Clitoria Mixture Grazed at Different Frequencies

A Signal grass-Clitoria mixture provides good quality forage in the dry tropic of southern Mexico. Grazing frequency is a management tool that determines yield, botanical components and quality of pastures. The objective of this study was to determine forage yield, quality and botanical components in a Signal grass (Brachiaria decumbens)-Clitoria (Clitoria ternatea) mixture when grazed at different frequencies

Trispyrazolylborate Ligands Supported on Vinyl Addition Polynorbornenes and Their Copper Derivatives as Recyclable Catalysts

Polynorbornenes prepared by vinyl addition poly- merization and bearing pendant alkenyl groups serve as skeletons to support trispyrazolylborate ligands (Tpx) built at those alkenyl sites. Reaction with CuI in acetonitrile led to VA-PNB–TpxCu(NCMe) (VA-PBN = vinyl addition polynorbor- nene) with a 0.8–1.4 mmol incorporation of Cu per gram of polymer. The presence of tetracoordinated copper(I) ions was been assessed by FTIR studies on the corresponding VA-PNB-TpxCu(CO) adducts, in agreement with those on discrete TpxCu(CO). The new materials were employed as heteroge- neous catalysts in several carbene- and nitrene-transfer reac- tions, showing a behavior similar to that of the homogene- ous counterparts but also being recycled several times main- taining a high degree of activity and selectivity. This is the first example of supported Tpx ligands onto polymeric sup- ports with catalytic applications.MINECO (CTQ2017-82893-C2-1-R, CTQ2016-80913-P and Red Intecat CTQ2016-81923-REDC)Junta de Castilla y León (VA051P17, VA062G18)European Union (CHAOS COST ACTION CA-15106)

Copper-catalyzed azide-alkyne cycloaddition (CuAAC) by functionalized NHC-based polynuclear catalysts: scope and mechanistic insights

Copper(I) Cu2(µ-Br)2(tBuImCH2pyCH2L)]n (L = OMe, NEt2, NHtBu) compounds supported by flexible functionalized NHC-based polydentate ligands have been prepared in a one-pot procedure by reacting the corresponding imidazolium salt with an excess of copper powder and Ag2O. An X-ray diffraction analysis has revealed that Cu2(µ-Br)2(tBuImCH2pyCH2NEt2)]n is a linear coordination polymer formed by bimetallic Cu(µ-Br)]2 units linked by the lutidine-based NHC-py-NEt2 ligand, which acts as a heteroditopic ligand with a 1¿C-2¿2N, N' coordination mode. We propose that the polymeric compounds break down in the solution into more compact tetranuclear Cu2(µ-Br)2(tBuImCH2pyCH2L)]2 compounds with a coordination mode identical to the functionalized NHC ligands. These compounds have been found to exhibit high catalytic activity in the Cu-catalyzed azide-alkyne cycloaddition (CuAAC) reaction. In particular, Cu2(µ-Br)2(tBuImCH2pyCH2NEt2)]2 efficiently catalyzes the click reaction of a range of azides and alkynes, under an inert atmosphere at room temperature in neat conditions at a very low catalyst loading, to quantitatively afford the corresponding 1, 4-disubstituted 1, 2, 3-triazole derivatives in a few minutes. The cycloaddition reaction of benzyl azide to phenylacetylene can be performed at 25-50 ppm catalyst loading by increasing the reaction time and/or temperature. Reactivity studies have shown that the activation of the polynuclear catalyst precursor involves the alkyne deprotonation by the NHC moiety of the polydentate ligand to afford a copper(I)-alkynyl species bearing a functionalized imidazolium ligand. DFT calculations support the participation of the dinuclear species (CuBr)2(µ-tBuImCH2pyCH2NEt2)], resulting from the fragmentation of the tetranuclear compound, as the catalytically active species. The proposed reaction pathway proceeds through zwitterionic dinuclear intermediates and entails the active participation of both copper atoms, as well as the NHC moiety as an internal base, which activates the reacting alkyne via deprotonation

Algal lipids reveal unprecedented warming rates in alpine areas of SW Europe during the industrial period

Alpine ecosystems of the southern Iberian Peninsula are among the most vulnerable and the first to respond to modern climate change in southwestern Europe. While major environmental shifts have occurred over the last similar to 1500 years in these alpine ecosystems, only changes in the recent centuries have led to abrupt environmental responses, but factors imposing the strongest stress have been unclear until now. To understand these environmental responses, this study, for the first time, has calibrated an algal lipid-derived temperature proxy (based on long-chain alkyl diols) to instrumental historical data extending alpine temperature reconstructions to 1500 years before present. These novel results highlight the enhanced effect of greenhouse gases on alpine temperatures during the last similar to 200 years and the long-term modulating role of solar forcing. This study also shows that the warming rate during the 20th century (similar to 0.18 degrees C per decade) was double that of the last stages of the Little Ice Age (similar to 0.09 degrees C per decade), even exceeding temperature trends of the high-altitude Alps during the 20th century. As a consequence, temperature exceeded the preindustrial record in the 1950s, and it has been one of the major forcing processes of the recent enhanced change in these alpine ecosystems from southern Iberia since then. Nevertheless, other factors reducing the snow and ice albedo (e.g., atmospheric deposition) may have influenced local glacier loss, since almost steady climate conditions predominated from the middle 19th century to the first decades of the 20th century.Peer reviewe

Evaluación del comportamiento sísmico de la estructura original y modificada del Mercado de Verónicas en Murcia (España)

In this manuscript, it is presented, a case-study about the assessment of the seismic behaviour of Veronicas Market. Its structure, initially constituted by steel trusses supported on masonry walls, was subsequently modified by the addition of a mezzanine supported on reinforced concrete piers. Applying the capacity spectrum method, based on an updated nonlinear finite element model, the performance levels of both the original and modified structure have been compared to assess the effects originated by the change in the transmission mechanism of the seismic loads.En este artículo, se presenta, un caso en estudio sobre la evaluación del comportamiento sísmico del Mercado de Verónicas. Su estructura, originalmente constituida por cerchas metálica apoyadas sobre muros de fábrica fue posteriormente modificada por la incorporación de una entreplanta con pilares de hormigón armado. Aplicando el método del espectro de capacidad, con base en un modelo calibrado no-lineal de elementos finitos, se han comparado los niveles de desempeño de la estructura original y modificada para valorar los efectos originados por el cambio en el mecanismo de transmisión de las cargas sísmicas

Variation in assignment of the COPD patients into a GOLD group according to symptoms severity

Introduction: The Global Organization of Lung Disease (GOLD) classifies patients with chronic obstructive pulmonary disease (COPD) taking into account the symptoms. The modified Medical Research Council’s dyspnea scale (mMRC) and the COPD assessment test (CAT) are used to assess these symptoms. In this study, we analyze the concordance of GOLD classification using mMRC and CAT. Patients and Methods: This is an observational study of a cohort of 169 patients with COPD, who were classified following the GOLD 2017 recommendations, using both mMRC and CAT. A concordance analysis was applied, and a ROC curve was generated to identify the CAT score that best concorded with the mMRC scale. Results: The concordance for the GOLD groups classified by CAT and mMRC was moderate (kappa 0.492). For mMRC score of 1 and 2, a CAT score of =9 and =16 showed the maximum value of the Youden index, respectively. By reclassifying the patients with the new cut-off points obtained, the best concordance was obtained between the cut-off point for CAT of 16 and for mMRC of 2, followed by CAT of 9 and mMRC of 1. Conclusion: Because of the deficient concordance between CAT and mMRC, we propose the use of new cut-off points in future updates of the GOLD strategy