Soot oxidation rates in gas turbine engines

A basis is proposed for extrapolating soot oxidation rate measurements obtained in laboratory flames to the more extreme operating conditions of gas turbine combustion chambers. The proposal is based on the observation that, within probable experimental uncertainty, the limited soot oxidation measurements correlate with the more extensive measurements of the surface oxidation rates of macroscopic samples of pyrographite. The soot oxidation rates thus determined for the conditions of a typical gas turbine combustion chamber are considerably lower than estimates which were based on simple extrapolations of the flame data

A stochastic model of turbulent mixing with chemical reaction: Nitric oxide formulation in a plug-flow burner

A stochastic model of turbulent mixing was developed for a reactor in which mixing is represented by n-body fluid particle interactions. The model was used to justify the assumption (made in previous investigations of the role of turbulent mixing on burner generated thermal nitric oxide and carbon monoxide emissions) that for a simple plug flow reactor, composition nonuniformities can be described by a Gaussian distribution function in the local fuel:air equivalence ratio. Recent extensions of this stochastic model to include the combined effects of turbulent mixing and secondary air entrainment on thermal generation of nitric oxide in gas turbine combustors are discussed. Finally, rate limited upper and lower bounds of the nitric oxide produced by thermal fixation of molecular nitrogen and oxidation of organically bound fuel nitrogen are estimated on the basis of the stochastic model for a plug flow burner; these are compared with experimental measurements obtained using a laboratory burner operated over a wide range of test conditions; good agreement is obtained

Shock-tube measurements of carbon to oxygen atom ratios for incipient soot formation with C2H2, C2H4 and C2H6 fuels

The critical atomic carbon to oxygen ratios, Phi sub C, for incipient soot formation in shock heated acetylene, ethylene, ethane/oxygen/ argon mixtures was measured over the temperature range 2000 K to 2500 K for reactant partial pressures between 0.1 and 0.4 atoms. Absorption of light from a He-Ne laser at 6328A was was used to detect soot. It was observed that the values of Phi sub C for all three fuels increased uniformly with temperature such that at the highest temperatures Phi sub C was considerably greater than unity, i.e. greater than the value of about unity at which solid carbon should have been precipitated on a thermochemical equilibrium basis. Observations were made over periods extending up to about one millisecond, which was well in excess of the time required for the major heat release of the combustion reactions. The relevance of these experimental findings to the problem of soot formation in gas turbine combustion chambers is discussed

Shock-tube measurements of the vibration- vibration energy exchange probability for the CO-N2 system

Measuring vibration-vibration energy exchange probability in nitrogen-carbon dioxide-argon mixtures in shock tube

Vibrational relaxation measurements of carbon monoxide in a shock-tube expansion wave

Infrared measurement on vibrational relaxation rate of carbon monoxide in argon shock tube wav

Enhanced dust heating in the bulges of early-type spiral galaxies

Stellar density and bar strength should affect the temperatures of the cool (T ~ 20–30 K) dust component in the inner regions of galaxies, which implies that the ratio of temperatures in the circumnuclear regions to the disk should depend on Hubble type. We investigate the differences between cool dust temperatures in the central 3 kpc and disk of 13 nearby galaxies by fitting models to measurements between 70 and 500 μm. We attempt to quantify temperature trends in nearby disk galaxies, with archival data from Spitzer/MIPS and new observations with Herschel/SPIRE, which were acquired during the first phases of the Herschel observations for the KINGFISH (Key Insights on Nearby Galaxies: a Far-Infrared Survey with Herschel) sample. We fit single-temperature modified blackbodies to far-infrared and submillimeter measurements of the central and disk regions of galaxies to determine the temperature of the component(s) emitting at those wavelengths. We present the ratio of central-region-to-disk-temperatures of the cool dust component of 13 nearby galaxies as a function of morphological type. We find a significant temperature gradient in the cool dust component in all galaxies, with a mean center-to-disk temperature ratio of 1.15 ± 0.03. The cool dust temperatures in the central ~3 kpc of nearby galaxies are 23 (±3)% hotter for morphological types earlier than Sc, and only 9 (±3)% hotter for later types. The temperature ratio is also correlated with bar strength, with only strongly barred galaxies having a ratio over 1.2. The strong radiation field in the high stellar density of a galactic bulge tends to heat the cool dust component to higher temperatures, at least in early-type spirals with relatively large bulges, especially when paired with a strong bar

Ventricular Tachycardia in the Absence of Structural Heart Disease

In up to 10% of patients who present with ventricular tachycardia (VT), obvious structural heart disease is not identified. In such patients, causes of ventricular arrhythmia include right ventricular outflow tract (RVOT) VT, extrasystoles, idiopathic left ventricular tachycardia (ILVT), idiopathic propranolol-sensitive VT (IPVT), catecholaminergic polymorphic VT (CPVT), Brugada syndrome, and long QT syndrome (LQTS). RVOT VT, ILVT, and IPVT are referred to as idiopathic VT and generally do not have a familial basis. RVOT VT and ILVT are monomorphic, whereas IPVT may be monomorphic or polymorphic. The idiopathic VTs are classified by the ventricle of origin, the response to pharmacologic agents, catecholamine dependence, and the specific morphologic features of the arrhythmia. CPVT, Brugada syndrome, and LQTS are inherited ion channelopathies. CPVT may present as bidirectional VT, polymorphic VT, or catecholaminergic ventricular fibrillation. Syncope and sudden death in Brugada syndrome are usually due to polymorphic VT. The characteristic arrhythmia of LQTS is torsades de pointes. Overall, patients with idiopathic VT have a better prognosis than do patients with ventricular arrhythmias and structural heart disease. Initial treatment approach is pharmacologic and radiofrequency ablation is curative in most patients. However, radiofrequency ablation is not useful in the management of inherited ion channelopathies. Prognosis for patients with VT secondary to ion channelopathies is variable. High-risk patients (recurrent syncope and sudden cardiac death survivors) with inherited ion channelopathies benefit from implantable cardioverter-defibrillator placement. This paper reviews the mechanism, clinical presentation, and management of VT in the absence of structural heart disease

Star Formation in Collision Debris: Insights from the modeling of their Spectral Energy Distribution

During galaxy-galaxy interactions, massive gas clouds can be injected into the intergalactic medium which in turn become gravitationally bound, collapse and form stars, star clusters or even dwarf galaxies. The objects resulting from this process are both "pristine", as they are forming their first generation of stars, and chemically evolved because the metallicity inherited from their parent galaxies is high. Such characteristics make them particularly interesting laboratories to study star formation. After having investigated their star-forming properties, we use photospheric, nebular and dust modeling to analyze here their spectral energy distribution (SED) from the far-ultraviolet to the mid-infrared regime for a sample of 7 star-forming regions. Our analysis confirms that the intergalactic star forming regions in Stephan's Quintet, around Arp 105, and NGC 5291, appear devoid of stellar populations older than 10^9 years. We also find an excess of light in the near-infrared regime (from 2 to 4.5 microns) which cannot be attributed to stellar photospheric or nebular contributions. This excess is correlated with the star formation rate intensity suggesting that it is probably due to emission by very small grains fluctuating in temperature as well as the polycyclic aromatic hydrocarbons (PAH) line at 3.3 micron. Comparing the attenuation via the Balmer decrement to the mid-infrared emission allows us to check the reliability of the attenuation estimate. It suggests the presence of embedded star forming regions in NGC 5291 and NGC 7252. Overall the SED of star-forming regions in collision debris (and Tidal Dwarf Galaxies) resemble more that of dusty star-forming regions in galactic disks than to that of typical star-forming dwarf galaxies.Comment: 22 pages, 24 figures, accepted for publication in A

COLA. III. Radio Detection of Active Galactic Nucleus in Compact Moderate Luminosity Infrared Galaxies

We present results from 4.8 GHz Very Large Array (VLA) and global very long baseline interferometry (VLBI) observations of the northern half of the moderate FIR luminosity (median L_(IR) = 10^(11.01) L_☉) COLA sample of star-forming galaxies. VLBI sources are detected in a high fraction (20/90) of the galaxies observed. The radio luminosities of these cores (~10^(21) W Hz^(–1)) are too large to be explained by radio supernovae or supernova remnants and we argue that they are instead powered by active galactic nuclei (AGNs). These sub-parsec scale radio cores are preferentially detected toward galaxies whose VLA maps show bright 100-500 parsec scale nuclear radio components. Since these latter structures tightly follow the FIR to radio-continuum correlation for star formation, we conclude that the AGN-powered VLBI sources are associated with compact nuclear starburst environments. The implications for possible starburst-AGN connections are discussed. The detected VLBI sources have a relatively narrow range of radio luminosity consistent with models in which intense compact Eddington-limited starbursts regulate the gas supply onto a central supermassive black hole. The high incidence of AGN radio cores in compact starbursts suggests little or no delay between the starburst phase and the onset of AGN activity