Spin of random stationary light

We develop a theoretical foundation for the spin angular momentum (SAM) of random, statistically stationary polychromatic light fields within the framework of classical optical coherence theory. The formulation is valid for fields of arbitrary frequency bandwidth and dimensionality. Both temporal and spectral representations are given, and we further elucidate the relationship between the SAM and the polarization characteristics of such fields as compared to monochromatic light. The special cases of quasimonochromatic light and planar fields are analyzed separately. Generally, our paper offers deeper insights into the SAM and polarization structures as well as their interlinked connections in random stationary light, which could be beneficial in exploiting SAM in stochastic optical near fields and tightly focused beams exhibiting complex polarization character

Descriptors of dimensionality for n × n density matrices

By using the recently introduced parametrization of an n-dimensional density matrix in terms of the indices of population asymmetry and the intrinsic coherences, we define descriptors in both integer and continuous forms of the effective dimension that take place for a complete description of a density matrix, thus providing accurate information beyond the rank of the density matrix. The concepts of dimensional folding, hidden dimensional purity, and dimensional entropy are introduced and discussed in view of the new approach presented. The results are applicable to any physical system represented by a density matrix, such as n-level quantum systems, qutrits, sets of interacting pencils of radiation, classical polarization states, and to transformations of density matrices, as occurs with quantum channels

Comparison of PFAS soil remediation alternatives at a civilian airport using cost-benefit analysis

Contamination of soil and water systems by per-and polyfluoroalkyl substances (PFAS) due to uncontrolled use of aqueous film-forming foams (AFFFs) at firefighting training sites at civilian and military airports is a universal issue and can lead to significant human health and environmental impacts. Remediation of these sites is often complex but necessary to alleviate the PFAS burden and minimise the risks of exposure by eliminating the hotspot/source from which the PFAS spreads. This study presents a probabilistic cost-benefit analysis (CBA) for evaluating PFAS reme-diation alternatives, which includes monetisation of both direct costs and benefits as well as externalities. The method is applied for a case study to compare five remediation alternatives for managing PFAS contaminated soil at Stockholm Arlanda Airport in Sweden. The social profitability, or the net present value (NPV), of each remediation alternative was calculated in comparison to two reference alternatives - 'total excavation' of the site (Alt 0) or 'do nothing'. Sensitivity analyses and model scenarios were tested to account for uncertainties, including small or large PFAS spreading and simulating different values for the magnitude of annual avoided cost of inaction (i.e., aggregate benefit) from PFAS re-mediation. In comparison to total excavation, four of the five studied remediation alternatives resulted in a positive mean NPV. Excavation and stabilization/solidification of the hotspot on-site combined with stabilization using acti-vated carbon for the rest of site (Alt 2) had the highest NPV for both spreading scenarios, i.e., Alt 2 was the most so-cially profitable alternative. Simulations of the annual avoided cost of inaction enabled estimation of the breakeven point at which a remediation alternative becomes socially profitable (NPV > 0) compared to 'do nothing'. Alt 2 had the lowest breakeven point: 7.5 and 5.75 millions of SEK/year for large and small spreading, respectively

Time to revise the paradigm of hantavirus syndromes? Hantavirus pulmonary syndrome caused by European hantavirus

Hantaviruses have previously been recognised to cause two separate syndromes: hemorrhagic fever with renal syndrome in Eurasia, and hantavirus pulmonary syndrome (HPS) in the Americas. However, increasing evidence suggests that this dichotomy is no longer fruitful when recognising human hantavirus disease and understanding the pathogenesis. Herein are presented three cases of severe European Puumala hantavirus infection that meet the HPS case definition. The clinical and pathological findings were similar to those found in American hantavirus patients. Consequently, hantavirus infection should be considered as a cause of acute respiratory distress in all endemic areas worldwide

Sets of orthogonal three-dimensional polarization states and their physical interpretation

The spectral and characteristic decompositions of the polarization matrix provide fruitful frameworks for the physical interpretation of three-dimensional (3D) partially polarized light fields. The decompositions are formulated in terms of the three pure eigenstates, which in turn are represented through their associated orthogonal complex 3D Jones vectors. This mathematical orthogonality does not correspond, in general, to orthogonality of the polarization-ellipse planes of the respective eigenstates. Consequently, due to such inherent mathematical complexity, the geometric and physical interpretation of these sets of orthogonal complex vectors, being essential for the best understanding of the structure and properties of partially polarized 3D light, has not been addressed thoroughly. In this work, the geometric and physical features of sets of three orthonormal 3D Jones vectors are identified and analyzed, allowing one to obtain meaningful interpretations of any given mixed (partially polarized) 3D polarization state in terms of either the spectral or the characteristic decompositions. Among other results, it is found that, given a pure polarization state, any plane in space contains the polarization ellipse of a pure state that is orthogonal to it, and the mathematical expressions for the azimuth and ellipticity of such an ellipse are calculated in terms of the angular parameters determining said plane and the ellipticity of the given state. Furthermore, the spin vectors of the three polarization eigenstates are arranged in a peculiar spatial manner, such that they lie in a common plane. Beyond polarization phenomena, the approach presented also has potential applications in areas where 3 x 3 unitary matrices play a key role, like three-level quantum systems and gates for ternary quantum logic circuits

Self-Assembly of Polyion–Surfactant Ion Complex Salts in Mixtures with Water and n-Alcohols

Phase behavior and structural features were investigated for "complex salts", consisting of the cationic hexadecyltrimethylammonium (CTA) surfactant with polyacrylate (PA(n), n = 30 or 6000) counterions, mixed with water and different n-alcohols (ethanol, butanol, hexanol, octanol, and decanol). The liquid crystalline structures formed were identified by small-angle X-ray scattering measurements, which provided information about the changes in the geometry of the aggregates as functions of the concentration and chain length of the added n-alcohol. The obtained results were compared with a previous work on similar ternary mixtures of the same cationic surfactant but with the monomeric bromide counterion, CTABr (Fontell, K; Khan, A.; Lindstrom, B.; Maciejewska, D.; Puang-Ngem, S. Colloid Polym. Sc., 1991, 269, 727). In general, the same phases were detected in systems with the complex salts CTAPA(n) as in systems with CTABr, but the swelling of the various liquid crystalline phases by water was much more limited in the complex salt systems. An isotropic alcoholic phase was observed with all alcohols and the size of this region of the phase diagram increased for the shorter alcohols, except for ethanol. For mixtures with octanol and ethanol, in particular, the extensions of the disordered isotropic phases were larger for the complex salt with the shorter polyacrylate ions

Tunable variation of optical properties of polymer capped gold nanoparticles

Optical properties of polymer capped gold nanoparticles of various sizes (diameter 3-6 nm) have been studied. We present a new scheme to extract size dependent variation of total dielectric function of gold nanoparticles from measured UV-Vis absorption data. The new scheme can also be used, in principle, for other related systems as well. We show how quantum effect, surface atomic co - ordination and polymer - nanoparticle interface morphology leads to a systematic variation in inter band part of the dielectric function of gold nanoparticles, obtained from the analysis using our new scheme. Careful analysis enables identification of the possible changes to the electronic band structure in such nanoparticles.Comment: 13 pages,7 figures, 1 tabl

Chemical changes in PCPDTBT:PCBM solar cells using XPS and TOF-SIMS and use of inverted device structure for improving lifetime performance

Analysis of the degradation routes for poly[(4,4-bis(2-ethylhexyl)-cyclopenta-[2,1-b;3,4-b′]dithiophene)-2,6-diyl-alt-2,1,3-benzothiadiazole-4,7-diyl] (PCPDTBT)-based solar cells under illumination and in the presence of air have been conducted using a combination of X-ray Photoelectron Spectroscopy (XPS), Time-Of-Flight Secondary Ion Mass Spectrometry (TOF-SIMs) and solar cell device data. After ageing, XPS studies show that PCPDTBT appears as an oxygen-containing polymer, with data indicating that a break-up in the aromatic rings, formation of sulphates at the thiophene ring, chain scission in the polymer backbone and also loss of side chains. XPS studies have also been conducted on Phenyl-C71-butyric acid methyl ester (PC71BM) films and show a breakage of the fullerene cage, loss of molecular shape and oxidation of carbon atoms in the fullerene cage and side chains after ageing. XPS studies on active layers blends of PCPDTBT and PCBM also show significant changes in the vertical composition during ageing, with increased enrichment of PCPDTBT observed at the top surface and that the use of a processing additive (ODT) has a negative impact on the morphological stability. Based on these studies, it shown that inverted structures are better suited than non-inverted devices for PCPDTBT:PCBM solar cells. An additional advantage of inverted devices is shown using TOF-SIMS; electrode degradation during ageing experiments leads to migration of indium and tin ions into the active layer in non-inverted devices, but is eliminated for inverted devices.HW would like to thank Bangor University for financial support through his “125 scholarship” from the University. ZD is supported from the “SteelPV” project, which is funded from the EC’s Research Fund for Coal and Steel (RFCS) research programme under grant agreement number RFSR-CT-2014-00014. Finally, JK would like to thank the Royal Academy of Engineering for funding via the Newton Research Collaboration Programme (NRCP/1415/28)