902 research outputs found
The impact of maritime English communication training for non-native English language speakers concerning the competency of seafarers : Iraqi maritime sector case study
Bayesian inference for synaptic connectivity rules in anatomically realistic cortical connectomes
First passage time distribution for a random walker on a random forcing energy landscape
We present an analytical approximation scheme for the first passage time
distribution on a finite interval of a random walker on a random forcing energy
landscape. The approximation scheme captures the behavior of the distribution
over all timescales in the problem. The results are carefully checked against
numerical simulations.Comment: 16 page
Photoionization in the time and frequency domain
Ultrafast processes in matter, such as the electron emission following light
absorption, can now be studied using ultrashort light pulses of attosecond
duration (s) in the extreme ultraviolet spectral range. The lack of
spectral resolution due to the use of short light pulses may raise serious
issues in the interpretation of the experimental results and the comparison
with detailed theoretical calculations. Here, we determine photoionization time
delays in neon atoms over a 40 eV energy range with an interferometric
technique combining high temporal and spectral resolution. We spectrally
disentangle direct ionization from ionization with shake up, where a second
electron is left in an excited state, thus obtaining excellent agreement with
theoretical calculations and thereby solving a puzzle raised by seven-year-old
measurements. Our experimental approach does not have conceptual limits,
allowing us to foresee, with the help of upcoming laser technology, ultra-high
resolution time-frequency studies from the visible to the x-ray range.Comment: 5 pages, 4 figure
Folding of a donor–acceptor polyrotaxane by using noncovalent bonding interactions
Mechanically interlocked compounds, such as bistable catenanes and bistable rotaxanes, have been used to bring about actuation in nanoelectromechanical systems (NEMS) and molecular electronic devices (MEDs). The elaboration of the structural features of such rotaxanes into macromolecular materials might allow the utilization of molecular motion to impact their bulk properties. We report here the synthesis and characterization of polymers that contain π electron-donating 1,5-dioxynaphthalene (DNP) units encircled by cyclobis(paraquat-p-phenylene) (CBPQT4+), a π electron-accepting tetracationic cyclophane, synthesized by using the copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC). The polyrotaxanes adopt a well defined “folded” secondary structure by virtue of the judicious design of two DNP-containing monomers with different binding affinities for CBPQT4+. This efficient approach to the preparation of polyrotaxanes, taken alongside the initial investigations of their chemical properties, sets the stage for the preparation of a previously undescribed class of macromolecular architectures
Characterization of uncertainties in atmospheric trace gas inversions using hierarchical Bayesian methods
We present a hierarchical Bayesian method for atmospheric trace gas
inversions. This method is used to estimate emissions of trace gases as well
as "hyper-parameters" that characterize the probability density functions
(PDFs) of the a priori emissions and model-measurement covariances. By
exploring the space of "uncertainties in uncertainties", we show that the
hierarchical method results in a more complete estimation of emissions and
their uncertainties than traditional Bayesian inversions, which rely heavily
on expert judgment. We present an analysis that shows the effect of
including hyper-parameters, which are themselves informed by the data, and
show that this method can serve to reduce the effect of errors in assumptions
made about the a priori emissions and model-measurement uncertainties. We
then apply this method to the estimation of sulfur hexafluoride (SF6)
emissions over 2012 for the regions surrounding four Advanced Global
Atmospheric Gases Experiment (AGAGE) stations. We find that improper
accounting of model representation uncertainties, in particular, can lead to
the derivation of emissions and associated uncertainties that are unrealistic
and show that those derived using the hierarchical method are likely to be
more representative of the true uncertainties in the system. We demonstrate
through this SF6 case study that this method is less sensitive to
outliers in the data and to subjective assumptions about a priori emissions
and model-measurement uncertainties than traditional methods
Recent and future trends in synthetic greenhouse gas radiative forcing
Atmospheric measurements show that emissions of hydrofluorocarbons (HFCs) and hydrochlorofluorocarbons are now the primary drivers of the positive growth in synthetic greenhouse gas (SGHG) radiative forcing. We infer recent SGHG emissions and examine the impact of future emissions scenarios, with a particular focus on proposals to reduce HFC use under the Montreal Protocol. If these proposals are implemented, overall SGHG radiative forcing could peak at around 355 mW m[superscript −2] in 2020, before declining by approximately 26% by 2050, despite continued growth of fully fluorinated greenhouse gas emissions. Compared to “no HFC policy” projections, this amounts to a reduction in radiative forcing of between 50 and 240 mW m[superscript −2] by 2050 or a cumulative emissions saving equivalent to 0.5 to 2.8 years of CO2 emissions at current levels. However, more complete reporting of global HFC emissions is required, as less than half of global emissions are currently accounted for.Natural Environment Research Council (Great Britain) (Advanced Research Fellowship NE/I021365/1)United States. National Aeronautics and Space Administration (Upper Atmospheric Research Program Grant NNX11AF17G)United States. National Oceanic and Atmospheric Administratio
The impact of neuron morphology on cortical network architecture
The neurons in the cerebral cortex are not randomly interconnected. This specificity in wiring can result from synapse formation mechanisms that connect neurons, depending on their electrical activity and genetically defined identity. Here, we report that the morphological properties of the neurons provide an additional prominent source by which wiring specificity emerges in cortical networks. This morphologically determined wiring specificity reflects similarities between the neurons’ axo-dendritic projections patterns, the packing density, and the cellular diversity of the neuropil. The higher these three factors are, the more recurrent is the topology of the network. Conversely, the lower these factors are, the more feedforward is the network’s topology. These principles predict the empirically observed occurrences of clusters of synapses, cell type-specific connectivity patterns, and nonrandom network motifs. Thus, we demonstrate that wiring specificity emerges in the cerebral cortex at subcellular, cellular, and network scales from the specific morphological properties of its neuronal constituents
Initial solidification dynamics of spreading droplets
When a droplet is brought in contact with an undercooled surface, it wets the
substrate and solidifies at the same time. The interplay between the phase
transition effects and the contact-line motion, leading to its arrest, remains
poorly understood. Here we reveal the early solidification patterns and
dynamics of spreading hexadecane droplets. Total internal reflection (TIR)
imaging is employed to temporally and spatially resolve the early
solidification behaviour. With this, we determine the conditions leading to the
contact-line arrest. We quantify the overall nucleation behaviour,
\textit{i.e.} the nucleation rate and the crystal growth speed, and show its
sensitivity to the applied undercooling of the substrate. By combining the
Johnson-Mehl-Avrami-Kolmogorov nucleation theory and scaling relations for the
spreading, we can calculate the temporal evolution of the solid area fraction,
which is in good agreement with our observations. We also show that for strong
enough undercooling it is the rapid growth of the crystals which determines the
eventual arrest of the spreading contact line.Comment: 5 pages, 5 figure
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