Exchange Narrowing Effects in the EPR Linewidth of Gd Diluted in Ce Compounds

Anomalous thermal behavior on the EPR linewidths of Gd impurities diluted in Ce compounds has been observed. In metals, the local magnetic moment EPR linewidth, \Delta H, is expected to increase linearly with the temperature. In contrast, in Ce_{x}La_{1-x}Os_{2} the Gd EPR spectra show a nonlinear increase. In this work, the mechanisms that are responsible for the thermal behavior of the EPR lines in Ce_{x}La_{1-x}Os_{2} are examined. We show that the exchange interaction between the local magnetic moments and the conduction electrons are responsible for the narrowing of the spectra at low temperatures. At high temperatures, the contribution to the linewidth of the exchange interaction between the local magnetic moments and the $Ce$ ions has an exponential dependence on the excitation energy of the intermediate valent ions. A complete fitting of the EPR spectra for powdered samples is obtained.Comment: 11 pages, 1 figur

Collapse of the Gd3+Gd^{3+} ESR fine structure throughout the coherent temperature of the Gd-doped Kondo Semiconductor CeFe4P12CeFe_{4}P_{12}

Experiments on the $Gd^{3+}$ Electron Spin Resonance (ESR) in the filled skutterudite $Ce_{1-x}Gd_{x}Fe_{4}P_{12}$ ($x \approx 0.001$), at temperatures where the host resistivity manifests a smooth insulator-metal crossover, provides evidence of the underlying Kondo physics associated with this system. At low temperatures (below $T \approx K$), $Ce_{1-x}Gd_{x}Fe_{4}P_{12}$ behaves as a Kondo-insulator with a relatively large hybridization gap, and the $Gd^{3+}$ ESR spectra displays a fine structure with lorentzian line shape, typical of insulating media. The electronic gap is attributed to the large hybridization present in the coherent regime of a Kondo lattice, when Ce 4f-electrons cooperate with band properties at half-filling. Mean-field calculations suggest that the electron-phonon interaction is fundamental at explaining the strong 4f-electron hybridization in this filled skutterudite. The resulting electronic structure is strongly temperature dependent, and at about $T^{*} \approx 160 K$ the system undergoes an insulator-to-metal transition induced by the withdrawal of 4f-electrons from the Fermi volume, the system becoming metallic and non-magnetic. The $Gd^{3+}$ ESR fine structure coalesces into a single dysonian resonance, as in metals. Still, our simulations suggest that exchange-narrowing via the usual Korringa mechanism, alone, is not capable of describing the thermal behavior of the ESR spectra in the entire temperature region ($4.2$ - $300$ K). We propose that temperature activated fluctuating-valence of the Ce ions is the missing ingredient that, added to the usual exchange-narrowing mechanism, fully describes this unique temperature dependence of the $Gd^{3+}$ ESR fine structure observed in $Ce_{1-x}Gd_{x}Fe_{4}P_{12}$.Comment: 19 pages, 6 figure

Nuevo género de avispa agallícola del encino, Kokkocynips Pujade-Villar & Melika, gen. n., con descripción de una nueva especies de México (Hymenoptera, Cynipidae)

A new genus of oak gallwasp, Kokkocynips Pujade-Villar & Melika gen.n., is described from Mexico. Diagnostic characters and generic limits of the new genus are discussed in detail. Galls were found on branches of Quercus acutifolia Née. Diagnostic characters, distribution and biology of the new species are described and illustrated.Se describe un nuevo género de cinípido agallícola, Kokkocynips Pujade-Villar & Melika n. gen. (Hymenoptera: Cynipidae: Cynipini) de México. Se discuten en detalle los caracteres diagnósticos y los límites genéricos de este nuevo género. Las agallas se encuentran en las ramas de Quercus acutifolia Née. Se describen e ilustran los caracteres diagnósticos, su distribución y la biología de la nueva especie

Asymptotic entanglement in a two-dimensional quantum walk

The evolution operator of a discrete-time quantum walk involves a conditional shift in position space which entangles the coin and position degrees of freedom of the walker. After several steps, the coin-position entanglement (CPE) converges to a well defined value which depends on the initial state. In this work we provide an analytical method which allows for the exact calculation of the asymptotic reduced density operator and the corresponding CPE for a discrete-time quantum walk on a two-dimensional lattice. We use the von Neumann entropy of the reduced density operator as an entanglement measure. The method is applied to the case of a Hadamard walk for which the dependence of the resulting CPE on initial conditions is obtained. Initial states leading to maximum or minimum CPE are identified and the relation between the coin or position entanglement present in the initial state of the walker and the final level of CPE is discussed. The CPE obtained from separable initial states satisfies an additivity property in terms of CPE of the corresponding one-dimensional cases. Non-local initial conditions are also considered and we find that the extreme case of an initial uniform position distribution leads to the largest CPE variation.Comment: Major revision. Improved structure. Theoretical results are now separated from specific examples. Most figures have been replaced by new versions. The paper is now significantly reduced in size: 11 pages, 7 figure

Modelagem para otimização da fertilização e calagem na cultura de cana-de-açúcar.

Resumo - A disponibilidade de informações necessárias para modelar a demanda por determinados nutrientes a partir da produtividade desejada e o potencial de suprimento do solo à cultura, permitiu o desenvolvimento de um sistema para o cálculo de balanço nutricional e como resultado a recomendação de corretivos e fertilizantes para a cana. É necessário o equilíbrio entre os que (a aplicação da planta), e que pode estar disponível (fonte do solo) é a base para o desenvolvimento do sistema. Os cálculos de equilíbrio de nutrientes indicam a necessidade, ou não, bem como, a quantidade a ser aplicada de calcário e fertilizantes na lavoura

BEHAVIORAL FILTERING OF HUMAN TRAJECTORIES FOR AUTOMATIC-MULTI-TRACK INITIATION

In this paper we describe a new approach for the multitrack initiation problem. We propose an extensive use of the top-view reconstruction of the scene to solve the detection step in tracking pedestrians. We leave a large set of starting hypothetical moving objects free to evolve in the scene for a certain number of frames. The number of trajectories is pre-filtered using distance and direction constraints on a one-step movement of pedestrians. The output trajectories from pre-filtering step are then filtered using a discrete choice model for pedestrian behavior, calibrated on real data. The results show that is possible to use this technique to perform multitarget tracking in real situations. We particularly focus on an application in the context of automatic video surveillance

Matching fields of a long superconducting film

We obtain the vortex configurations, the matching fields and the magnetization of a superconducting film with a finite cross section. The applied magnetic field is normal to this cross section, and we use London theory to calculate many of its properties, such as the local magnetic field, the free energy and the induction for the mixed state. Thus previous similar theoretical works, done for an infinitely long superconducting film, are recovered here, in the special limit of a very long cross section.Comment: Contains a REVTeX file and 4 figure

Metallic islands in the Kondo insulator SmB6_{6}

The predicted interplay between Kondo physics and non-trivial topology in SmB$_{6}$ has stimulated many experimental reports, some of which are in apparent contradiction. The origin of the dispute may lie on the fragility of the Kondo insulating phase in the presence of Sm vacancies (Kondo holes) and/or natural impurities, such as Gd$^{3+}$. In this work, we locally investigated this fragility for Al-flux grown Sm$_{1-x}$Gd$_{x}$B$_{6}$ single crystals (0 $\leq$ $x$ $\leq$ 0.02) by combining electron spin resonance (ESR) and complementary bulk measurements. The Gd$^{3+}$ ESR spectra in a highly dilute regime ($x$ $\sim 0.0004$) display the features of an insulating cubic environment. Remarkably, a metallic ESR lineshape is observed for more concentrated samples ($x$ $\geq$ 0.004), even though these systems are still in a reasonably dilute regime and show insulating $dc$ electrical resistivity. Our data indicate that the Kondo insulating state is destroyed locally around impurities before a global percolation occurs. This result not only explains the discrepancy between $dc$ and $ac$ conductivity, but also provides a scenario to explain the presence of quantum oscillations in magnetization in the absence of quantum oscillations in electrical resistivity.Comment: 8 pages, 4 figures, 1 supplementary information. To be published in Phys. Rev. Researc

Mesoscopic superconductors in the London limit: equilibrium properties and metastability

We present a study of the behaviour of metastable vortex states in mesoscopic superconductors. Our analysis relies on the London limit within which it is possible to derive closed analytical expressions for the magnetic field and the Gibbs free energy. We consider in particular the situation where the vortices are symmetrically distributed along a closed ring. There, we obtain expressions for the confining Bean-Livingston barrier and for the magnetization which turns out to be paramagnetic away from thermodynamic equilibrium. At low temperature, the barrier is high enough for this regime to be observable. We propose also a local description of both thermodynamic and metastable states based on elementary topological considerations; we find structural phase transitions of vortex patterns between these metastable states and we calculate the corresponding critical fields.Comment: 24 pages, 20 figure