Distinct nonequilibrium plasma chemistry of C2 affecting the synthesis of nanodiamond thin films from C2H2 (1%)/H2/Ar-rich plasmas

6 pages, 5 figures, 6 tables.We show that the concentrations of the species C2 (X 1Σg+), C2 (a 3Πu), and C2H exhibit a significant increase when the argon content grows up to 95% in medium pressure (0.75 Torr) radio frequency (rf) (13.56 MHz) produced C2H2 (1%)/H2/Ar plasmas of interest for the synthesis of nanodiamond thin films within plasma enhanced chemical vapor deposition devices. In contrast, the concentrations of CH3 and C2H2 remain practically constant. The latter results have been obtained with an improved quasianalytic space–time-averaged kinetic model that, in addition, has allowed us to identify and quantify the relative importance of the different underlying mechanisms driving the nonequilibrium plasma chemistry of C2. The results presented here are in agreement with recent experimental results from rf CH4/H2/Ar-rich plasmas and suggest that the growth of nanodiamond thin films from hydrocarbon/Ar-rich plasmas is very sensitive to the contribution of C2 and C2H species from the plasma.This work was partially funded by CICYT (Spain) under a Ramón y Cajal project and under Project No. TIC2002- 03235. One of the authors (F.J.G.V.) acknowledges a Ramón y Cajal contract from the Spanish Ministry of Science and Technology (MCYT). One of the authors (J.M.A.) acknowledges partial support from CICYT (Spain) under Project No. MAT 2002-04085-C02-02.Peer reviewe

Robust symmetric multiplication for programmable analog VLSI array processing

This paper presents an electrically programmable analog multiplier. The circuit performs the multiplication between an input variable and an electrically selectable scaling factor. The multiplier is divided in several blocks: a linearized transconductor, binary weighted current mirrors and a differential to single-ended current adder. This paper shows the advantages introduced using a linearized OTA-based multiplier. The circuit presented renders higher linearity and symmetry in the output current than a previously reported single-transistor multiplier. Its inclusion in an array processor based on CNN allows for a more accurate implementation of the processing model and a more robust weight distribution scheme than those found in previous designs.Office of Naval Research (USA) N-00014- 02-1-0884Ministerio de Ciencia y Tecnología TIC2003-09817-C02-0

Chemical and thermal impacts of sprite streamers in the Earth's mesosphere

A one-dimensional self-consistent model has been developed to study the chemical and thermal effects of a single sprite streamer in the Earth's mesosphere. We have used sprite streamer profiles with three different driving current durations (5 ms, 50 ms, and 100 ms) between 50 and 80 km of altitude and considering a kinetic scheme of air with more than 90 chemical species. Our model predicts strong increases in practically all the concentrations of the species studied at the moment of the streamer head passage. Moreover, their densities remain high during the streamer afterglow phase. The concentration of electrons can reach values of up to 10 cm in the three cases analyzed. The model also predicts an important enhancement, of several orders of magnitude above ambient values, of nitrogen oxides and several metastables species. On the other hand, we found that the 4.26 μm IR emission brightness of CO can reach 10 GR at low altitudes (< 65 km) for the cases of intermediate (50 ms) and long (100 ms) driving currents. These results suggest the possibility of detecting sprite IR emissions from space with the appropriate instrumentation. Finally, we found that the thermal impact of sprites in the Earth's mesosphere is proportional to the driving current duration. This produces variations of more than 40 K (in the extreme case of a 100 ms driving current) at low altitudes (< 55 km) and at about 10 s after the streamer head. Key Points Chemical and thermal impacts of sprites in the mesosphere are calculated The calculated concentration of electrons exhibits a significant enhancement The model predicts an increase in the gas temperature at low altitudes.©2016. American Geophysical Union. All Rights Reserved.This work was supported by the Spanish Ministry of Economy and Competitiveness, MINECO, under projects AYA2011-29936-C05-02 and ESP2013-48032-C5-5-R and by the Junta de Andalucia, Proyecto de Excelencia, FQM-5965. F.C.P.R. acknowledges MINECO for the FPI grant BES-2010-042367. A.L. was supported by a Ramon y Cajal contract, code RYC-2011-07801Peer Reviewe

From carbon nanostructures to new photoluminescence sources: an overview of new perspectives and emerging applications of low pressure PECVD

13 pages, 9 figures.Low-pressure, plasma-enhanced (PE)CVD is a powerful and versatile technique that has been used for thin-film deposition and surface treatment since the early 1960s. However, it is only recently that it has been used in applications other than the different stages of microelectronic circuit fabrication. Now, PECVD is being used in emerging applications due to new materials and process requirements in a wide variety of areas, such as biomedical applications, solar cells, fuel cell development, fusion research, or the synthesis of silicon nanocrystals showing efficient photoluminescence, useful for future solid-state light sources. These new scenarios have stimulated further development of novel PECVD diagnostic techniques, together with fundamental experimental and theoretical studies aimed at a better understanding of some of the basic processes underlying the plasma/surface interaction. This paper gives an overview of some new research areas where PECVD is finding promising applications.FJGV acknowledges partial financial support from CSIC-CAM (Project No. 200550M016 and 200650M016) and MEC (Projects No. MAT2006-13006-C02-01 and ENE2006-14577-C04-03), VJH and IT acknowledge funding from MEC (Projects No. FTN-2003-08228-C03-03, FIS2004-00456 and ENE2006-14577-C04-03).Peer reviewe

Upper D region chemical kinetic modeling of LORE relaxation times

The recovery times of upper D region electron density elevations, caused by lightning-induced electromagnetic pulses (EMP), are modeled. The work was motivated from the need to understand a recently identified narrowband VLF perturbation named LOREs, an acronym for LOng Recovery Early VLF events. LOREs associate with long-living electron density perturbations in the upper D region ionosphere; they are generated by strong EMP radiated from large peak current intensities of +/- CG (cloud to ground) lightning discharges, known also to be capable of producing elves. Relaxation model scenarios are considered first for a weak enhancement in electron density and then for a much stronger one caused by an intense lightning EMP acting as an impulsive ionization source. The full nonequilibrium kinetic modeling of the perturbed mesosphere in the 76 to 92 km range during LORE-occurring conditions predicts that the electron density relaxation time is controlled by electron attachment at lower altitudes, whereas above 79 km attachment is balanced totally by associative electron detachment so that electron loss at these higher altitudes is controlled mainly by electron recombination with hydrated positive clusters H+(H2O)(n) and secondarily by dissociative recombination with NO+ ions, a process which gradually dominates at altitudes > 88 km. The calculated recovery times agree fairly well with LORE observations. In addition, a simplified (quasi-analytic) model build for the key charged species and chemical reactions is applied, which arrives at similar results with those of the full kinetic model. Finally, the modeled recovery estimates for lower altitudes, that is < 79 km, are in good agreement with the observed short recovery times of typical early VLF events, which are known to be associated with sprites.This work was supported by the Spanish Ministry of Science and Innovation, MINECO under projects ESP2013-48032-C5-5-R, FIS2014-61774-EXP, and ESP2015-69909-C5-2-R, and by the EU through the FEDER program. A.L. acknowledges support by a Ramon y Cajal contract, code RYC-2011-07801.Peer reviewe

Gobal and regional chemical influence of sprites: Reconciling modeling results and measurements

Mesospheric electrical discharges, known as sprites, formed by fast-propagating streamers, have been shown to create localized enhancements of atmospheric constituents such as N, O, NOx, N2O, and HOx, as indicated by both, modeling results and space-based measurements. In this study, we incorporate the occurrence rate of sprites into a chemistry-climate model using meteorological parameters as a proxy. Additionally, we introduce the injection of chemical species by sprites into the model, based on electrodynamical modeling of individual sprite streamers and observations from space. Our modeling results show a good agreement between the simulated sprite distribution and observed data on a global scale. While the global influence of sprites on the atmospheric chemistry is found to be negligible, our findings reveal their measurable chemical influence at regional scale, particularly for the concentration of HNO3 and HNO4 within the mesosphere. The simulations also suggest that sprites could be responsible for the observed NO2 anomalies at an altitude of 52 km above thunderstorms, as reported by MIPAS. Finally, a projected simulation reveals that the occurrence rate of sprites could increase at a rate of 14 % per 1 K rise in the global temperature

Centralized multivariable control by simplified decoupling

This paper presents a generalized formulation of simplified decoupling to n×n processes that allows for different configurations depending on the decoupler elements set to unity. To apply this decoupling method, the realizability conditions are stated. Then, from the previous decoupling in combination with a decentralized control, the formulation of a centralized control by simplified decoupling is developed. After reducing the controller, this last proposed method is modified to a multivariable PID control. From an implementation point of view, the windup problem is addressed for these methods, and an anti-windup scheme for multivariable PID controllers is proposed. Comparisons with other works demonstrate the effectiveness of these methodologies, through the use of several simulation examples and an experimental lab process