552 research outputs found
Crystal engineering using functionalized adamantane
We performed a first principles investigation on the structural, electronic,
and optical properties of crystals made of chemically functionalized adamantane
molecules. Several molecular building blocks, formed by boron and nitrogen
substitutional functionalizations, were considered to build zincblende and
wurtzite crystals, and the resulting structures presented large bulk moduli and
cohesive energies, wide and direct bandgaps, and low dielectric constants
(low- materials). Those properties provide stability for such
structures up to room temperature, superior to those of typical molecular
crystals. This indicates a possible road map for crystal engineering using
functionalized diamondoids, with potential applications ranging from space
filling between conducting wires in nanodevices to nano-electro-mechanical
systems
Point defect interactions with extended defects in semiconductors
FAPESP - FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULOCNPQ - CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICOWe performed a theoretical investigation of the interaction of point defects (vacancy and self-interstitials) with an intrinsic stacking fault in silicon using ab initio total-energy calculations. Defects at the fault and in the crystalline environment display a different behavior, which is evidenced by changes in formation energy and electronic structure. The formation energies for the vacancy and the [110]-split interstitial are lower at the intrinsic stacking fault than those in the crystal, indicating that in nonequilibrium conditions, intrinsic stacking faults can act, together with other extended defects, as a sink for point defects, and also that in equilibrium conditions, there can be a higher concentration of such defects at the fault than that in bulk silicon. [S0163-1829(99)03631-0].We performed a theoretical investigation of the interaction of point defects (vacancy and self-interstitials) with an intrinsic stacking fault in silicon using ab initio total-energy calculations. Defects at the fault and in the crystalline environment display a different behavior, which is evidenced by changes in formation energy and electronic structure. The formation energies for the vacancy and the [110]-split interstitial are lower at the intrinsic stacking fault than those in the crystal, indicating that in nonequilibrium conditions, intrinsic stacking faults can act, together with other extended defects, as a sink for point defects, and also that in equilibrium conditions, there can be a higher concentration of such defects at the fault than that in bulk silicon.60747114714FAPESP - FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULOCNPQ - CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICOFAPESP - FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULOCNPQ - CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICOSem informaçãoSem informaçãoThe authors acknowledge partial support from the Brazilian funding agencies FAPESP and CNPq. Computer calculations were performed at the facilities of CENAPAD-SP
A study of the Higgs and confining phases in Euclidean SU(2) Yang-Mills theories in 3d by taking into account the Gribov horizon
We study SU(2) three-dimensional Yang-Mills theories in presence of Higgs
fields in the light of the Gribov phenomenon. By restricting the domain of
integration in the functional integral to the first Gribov horizon, we are able
to discuss a kind of transition between the Higgs and the confining phase in a
semi-classical approximation. Both adjoint and fundamental representation for
the Higgs field are considered, leading to a different phase structure.Comment: 12 pages. Version accepted for publication in the EPJ
Finite temperature molecular dynamics study of unstable stacking fault free energies in silicon
We calculate the free energies of unstable stacking fault (USF)
configurations on the glide and shuffle slip planes in silicon as a function of
temperature, using the recently developed Environment Dependent Interatomic
Potential (EDIP). We employ the molecular dynamics (MD) adiabatic switching
method with appropriate periodic boundary conditions and restrictions to atomic
motion that guarantee stability and include volume relaxation of the USF
configurations perpendicular to the slip plane. Our MD results using the EDIP
model agree fairly well with earlier first-principles estimates for the
transition from shuffle to glide plane dominance as a function of temperature.
We use these results to make contact to brittle-ductile transition models.Comment: 6 pages revtex, 4 figs, 16 refs, to appear in Phys. Rev.
Comparison between classical potentials and ab initio for silicon under large shear
The homogeneous shear of the {111} planes along the direction of bulk
silicon has been investigated using ab initio techniques, to better understand
the strain properties of both shuffle and glide set planes. Similar
calculations have been done with three empirical potentials, Stillinger-Weber,
Tersoff and EDIP, in order to find the one giving the best results under large
shear strains. The generalized stacking fault energies have also been
calculated with these potentials to complement this study. It turns out that
the Stillinger-Weber potential better reproduces the ab initio results, for the
smoothness and the amplitude of the energy variation as well as the
localization of shear in the shuffle set
Quasiharmonic elastic constants corrected for deviatoric thermal stresses
The quasiharmonic approximation (QHA), in its simplest form also called the
statically constrained (SC) QHA, has been shown to be a straightforward method
to compute thermoelastic properties of crystals. Recently we showed that for
non-cubic solids SC-QHA calculations develop deviatoric thermal stresses at
high temperatures. Relaxation of these stresses leads to a series of
corrections to the free energy that may be taken to any desired order, up to
self-consistency. Here we show how to correct the elastic constants obtained
using the SC-QHA. We exemplify the procedure by correcting to first order the
elastic constants of MgSiO-perovskite and MgSiO-post-perovskite, the
major phases of the Earth's lower mantle. We show that this first order
correction is quite satisfactory for obtaining the aggregated elastic averages
of these minerals and their velocities in the lower mantle. This type of
correction is also shown to be applicable to experimental measurements of
elastic constants in situations where deviatoric stresses can develop, such as
in diamond anvil cells.Comment: 4 figures, 1 table, submitted to Phys. Rev. B, July 200
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