The NMR of High Temperature Superconductors without Anti-Ferromagnetic Spin Fluctuations

A microscopic theory for the NMR anomalies of the planar Cu and O sites in superconducting La_1.85Sr_0.15CuO_4 is presented that quantitatively explains the observations without the need to invoke anit-ferromagnetic spin fluctuations on the planar Cu sites and its significant discrepancy with the observed incommensurate neutron spin fluctuations. The theory is derived from the recently published ab-initio band structure calculations that correct LDA computations tendency to overestimate the self-coulomb repulsion for the half-filled Cu d_x2-y2 orbital for these ionic systems. The new band structure leads to two bands at the Fermi level with holes in the Cu d_z2 and apical O p_z orbitals in addition to the standard Cu d_x2-y2 and planar O p_sigma orbitals. This band structure is part of a new theory for the cuprates that explains a broad range of experiments and is based upon the formation of Cooper pairs comprised of a k up spin electron from one band and a -k down spin electron from another band (Interband Pairing Model).Comment: In Press, Journal of Physical Chemistry. See also http://www.firstprinciples.com. Minor changes to references and figure readabilit

Thermal Lensing Spectroscopy With Picosecond Pulse Trains and a New Dual Beam Configuration

In this communication, we wish to report on the use of synchronously mode-locked picosecond lasers in a pump-probe configuration for TL spectroscopy. The peak power for these picosecond lasers is very high and, of course, the fundamental of the dye laser (red beam) can be efficiently (~10%) doubled in frequency (U.V. beam) by second harmonic generation in nonlinear crystals. We use this generated U.V. beam as a probe to monitor the very weak absorption of the red beam. An arrangement [4] of the beams involving different waist positions for the pump and probe is used. This arrangement results in an enhancement of sensitivity (at least a factor of three to seven). Also, a different dependence of the signal on the cell position compared to the single beam method is obtained. Finally, we have obtained the Δν = 5 CH-stretching overtone absorption spectrum of liquid toluene with this method (see Figure 1). Suggestions are made regarding new applications of this picosecond pulse thermal lensing technique

A study of the usefulness of Skylab EREP data for earth resources studies in Australia

The author has identified the following significant results. The stereo cover of the Skylab photos, their clarity, and their resolution put them far above the ERTS imagery not only in distinguishing between patterns but also in determining the nature of the country. The following land systems: (1) plains with sand dunes; (2) ridges, foothills, and alluvial plains; (3) dune-covered country with stony hills; and (4) alluvial plains were indistinguishable on the ERTS imagery. However, the same places are clearly distinguishable on the Skylab photos, together with the character of the dunes (parallel, reticulate, or irregular)

Operator Evolution via the Similarity Renormalization Group I: The Deuteron

Similarity Renormalization Group (SRG) flow equations can be used to unitarily soften nuclear Hamiltonians by decoupling high-energy intermediate state contributions to low-energy observables while maintaining the natural hierarchy of many-body forces. Analogous flow equations can be used to consistently evolve operators so that observables are unchanged if no approximations are made. The question in practice is whether the advantages of a softer Hamiltonian and less correlated wave functions might be offset by complications in approximating and applying other operators. Here we examine the properties of SRG-evolved operators, focusing in this paper on applications to the deuteron but leading toward methods for few-body systems. We find the advantageous features generally carry over to other operators with additional simplifications in some cases from factorization of the unitary transformation operator.Comment: 33 pages, 19 figures. Improved figures 17 and 18. Expanded comments on OPE in tex

Operator Evolution via the Similarity Renormalization Group I: The Deuteron

Similarity Renormalization Group (SRG) flow equations can be used to unitarily soften nuclear Hamiltonians by decoupling high-energy intermediate state contributions to low-energy observables while maintaining the natural hierarchy of many-body forces. Analogous flow equations can be used to consistently evolve operators so that observables are unchanged if no approximations are made. The question in practice is whether the advantages of a softer Hamiltonian and less correlated wave functions might be offset by complications in approximating and applying other operators. Here we examine the properties of SRG-evolved operators, focusing in this paper on applications to the deuteron but leading toward methods for few-body systems. We find the advantageous features generally carry over to other operators with additional simplifications in some cases from factorization of the unitary transformation operator.Comment: 33 pages, 19 figures. Improved figures 17 and 18. Expanded comments on OPE in tex

Direct picosecond time resolution of unimolecular reactions initiated by local mode excitation

The concept of local mode (LM) states [1] in large molecules raises the possibilty of inducing chemical reactions from a well-defined initial state (bond-selective chemistry). The results of linewidth and energy measurements in gases, [2(a)] and low temperature solids, [2(b)] however, indicate that the relaxation times for such high energy (> 15000 cm^-1) states can be extremely short, < 1ps. Because of the lack of direct time-resolved measurements, the following fundamental questions have not been unequivocally answered: What are the homogeneous linewidths of LM states and what are the rates of energy relaxation or reaction out of these states? Over the past five years we have made several attempts to observe the picosecond dynamics of LM states. Due to the inherent difficulties associated with making these measurements, such as the very small oscillator strength (σ < 10^-23 cm^2), an extremely sensitive probing technique becomes imperative