6,345 research outputs found

    Denaturation transition of stretched DNA

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    We generalize the Poland-Scheraga model to consider DNA denaturation in the presence of an external stretching force. We demonstrate the existence of a force-induced DNA denaturation transition and obtain the temperature-force phase diagram. The transition is determined by the loop exponent cc for which we find the new value c=4ν−1/2c=4\nu-1/2 such that the transition is second order with c=1.85<2c=1.85<2 in d=3d=3. We show that a finite stretching force FF destabilizes DNA, corresponding to a lower melting temperature T(F)T(F), in agreement with single-molecule DNA stretching experiments.Comment: 5 pages, 3 figure

    Structural and magnetic properties of an InGaAs/Fe3_3Si superlattice in cylindrical geometry

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    The structure and the magnetic properties of an InGaAs/Fe3Si superlattice in a cylindrical geometry are investigated by electron microscopy techniques, x-ray diffraction and magnetometry. To form a radial superlattice, a pseudomorphic InGaAs/Fe3As bilayer has been released from its substrate self-forming into a rolled-up microtube. Oxide-free interfaces as well as areas of crystalline bonding are observed and an overall lattice mismatch between succeeding layers is determined. The cylindrical symmetry of the final radial superlattice shows a significant effect on the magnetization behavior of the rolled-up layers

    Immobilisation of glycosidases from commercial preparation on magnetic beads: Part 2: Aroma enhancement in wine using immobilised glycosidases

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    Most of the terpenes in wines are conjugated to various sugars, representing a significant reservoir of aromatic precursors. To promote the release of these terpenes, certain enzymes, such as β-glucosidase, α-arabinosidase and α-rhamnosidase, are necessary. A simple and cost-effective procedure for the immobilisation of multiple glycosidase activities (β-D-glucopyranosidase, α-L-arabinofuranosidase, α-L-rhamnopyranosidase and β-D-xylopyranosidase) from commercial Aspergillus niger preparation onto magnetic beads as carriers was developed as reported in Part 1 (Ferner et al. 2016).The aim of this work was to analyse a possible application of this immobilised biocatalyst due to its well-known advantages over soluble enzyme preparations – that is, control of the reaction process and preparation of enzyme-free products. Volatile compounds were analysed by gas chromatography (mass spectrometric detection). After the treatment of the model wine with different glycosides and white wine with immobilised glycosidases, the amount of free terpenes was significantly increased with respect to that of the control wine.The results of this study are of considerable interest for possible future applications of immobilised enzymes in the wine-making industry

    Gill Function in an Elasmobranch

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    Highly efficient oxygen uptake in elasmobranchs, as indicated by frequent excess of PaO2 over PEO2 has previously been ascribed to the operation of multicapillary rather than counter-current gas exchange by the gills. Analysis of models shows that, at maximum efficiency, a multicapillary system cannot account for values of PaO2 greater than (PIO2+PEO2)/2. In Port Jackson sharks Heterodontus portusjacksoni) PaO2 commonly exceeds (PIO2+PEO2)/2, which indicates the operation of a functional counter-current at the respiratory surface. The anatomical basis of this counter-current is provided by the demonstration that a continuous flow of water passes between the secondary lamellae into septal canals and thence via the parabranchial cavities to the exterior

    The 63^{63}Ni(n,γ\gamma) cross section measured with DANCE

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    The neutron capture cross section of the s-process branch nucleus 63^{63}Ni affects the abundances of other nuclei in its region, especially 63^{63}Cu and 64^{64}Zn. In order to determine the energy dependent neutron capture cross section in the astrophysical energy region, an experiment at the Los Alamos National Laboratory has been performed using the calorimetric 4π\pi BaF2_2 array DANCE. The (n,γ\gamma) cross section of 63^{63}Ni has been determined relative to the well known 197^{197}Au standard with uncertainties below 15%. Various 63^{63}Ni resonances have been identified based on the Q-value. Furthermore, the s-process sensitivity of the new values was analyzed with the new network calculation tool NETZ.Comment: 11 pages, 13 page

    Local implicit modeling of blood vessels for interactive simulation

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    International audienceIn the context of computer-based simulation, contact management requires an accurate, smooth, but still efficient surface model for the blood vessels. A new implicit model is proposed, consisting of a tree of local implicit surfaces generated by skeletons ({\em blobby models}). The surface is reconstructed from data points by minimizing an energy, alternating with an original blob selection and subdivision scheme. The reconstructed models are very efficient for simulation and were shown to provide a sub-voxel approximation of the vessel surface on 5 patients

    Optimization of a high work function solution processed vanadium oxide hole-extracting layer for small molecule and polymer organic photovoltaic cells

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    We report a method of fabricating a high work function, solution processable vanadium oxide (V2Ox(sol)) hole-extracting layer. The atmospheric processing conditions of film preparation have a critical influence on the electronic structure and stoichiometry of the V2Ox(sol), with a direct impact on organic photovoltaic (OPV) cell performance. Combined Kelvin probe (KP) and ultraviolet photoemission spectroscopy (UPS) measurements reveal a high work function, n-type character for the thin films, analogous to previously reported thermally evaporated transition metal oxides. Additional states within the band gap of V2Ox(sol) are observed in the UPS spectra and are demonstrated using X-ray photoelectron spectroscopy (XPS) to be due to the substoichiometric nature of V2Ox(sol). The optimized V2Ox(sol) layer performance is compared directly to bare indium–tin oxide (ITO), poly(ethyleneoxythiophene):poly(styrenesulfonate) (PEDOT:PSS), and thermally evaporated molybdenum oxide (MoOx) interfaces in both small molecule/fullerene and polymer/fullerene structures. OPV cells incorporating V2Ox(sol) are reported to achieve favorable initial cell performance and cell stability attributes

    Size effect on magnetism of Fe thin films in Fe/Ir superlattices

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    In ferromagnetic thin films, the Curie temperature variation with the thickness is always considered as continuous when the thickness is varied from nn to n+1n+1 atomic planes. We show that it is not the case for Fe in Fe/Ir superlattices. For an integer number of atomic planes, a unique magnetic transition is observed by susceptibility measurements, whereas two magnetic transitions are observed for fractional numbers of planes. This behavior is attributed to successive transitions of areas with nn and n+1n+1 atomic planes, for which the TcT_c's are not the same. Indeed, the magnetic correlation length is presumably shorter than the average size of the terraces. Monte carlo simulations are performed to support this explanation.Comment: LaTeX file with Revtex, 5 pages, 5 eps figures, to appear in Phys. Rev. Let
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