594 research outputs found
Evidence of strong antiferromagnetic coupling between localized and itinerant electrons in ferromagnetic Sr2FeMoO6
Magnetic dc susceptibility () and electron spin resonance (ESR)
measurements in the paramagnetic regime, are presented. We found a Curie-Weiss
(CW) behavior for (T) with a ferromagnetic K and
, this being lower than that expected for
either or ions. The ESR g-factor , is associated with . We obtained an excellent description
of the experiments in terms of two interacting sublattices: the localized
() cores and the delocalized electrons. The coupled equations
were solved in a mean-field approximation, assuming for the itinerant electrons
a bare susceptibility independent on . We obtained
emu/mol. We show that the reduction of for
arises from the strong antiferromagnetic (AFM) interaction between the two
sublattices. At variance with classical ferrimagnets, we found that is
ferromagnetic. Within the same model, we show that the ESR spectrum can be
described by Bloch-Hasegawa type equations. Bottleneck is evidenced by the
absence of a -shift. Surprisingly, as observed in CMR manganites, no
narrowing effects of the ESR linewidth is detected in spite of the presence of
the strong magnetic coupling. These results provide evidence that the magnetic
order in does not originates in superexchange interactions,
but from a novel mechanism recently proposed for double perovskites
Cohesive energies of cubic III-V semiconductors
Cohesive energies for twelve cubic III-V semiconductors with zincblende
structure have been determined using an ab-initio scheme. Correlation
contributions, in particular, have been evaluated using the coupled-cluster
approach with single and double excitations (CCSD). This was done by means of
increments obtained for localized bond orbitals and for pairs and triples of
such bonds. Combining these results with corresponding Hartree-Fock data, we
recover about 92 \% of the experimental cohesive energies.Comment: 16 pages, 1 figure, late
Study of Magnetic Properties of A_2B^'NbO_6 (A=Ba,Sr, (BaSr): and B^'=Fe and Mn) double perovskites
We have studied the magnetic properties of Ba_2FeNbO_6 and Ba_2MnNbO_6. it is
seen that Ba_2FeNbO_6 is an antiferromagnet with a weak ferromagnetic behaviour
at 5K while Ba_2MnNbO_6 shows two magnetic transitions one at 45 K and the
other at 12K. Electron spin resonance (ESR) measurements at room temperature
show that the Mn compound does not show any Jahn-Teller distortion. It is also
seen that the Neel temperature of the A_2FeNbO_6 (A=Ba,Sr, BaSr) compounds do
not vary significantly. However variations in the average A-site ionic radius
influence the formation of short range correlations that persist above T_N.Comment: 10 oages, 5 figures, MMM, to appear in J.Appl.Phy
The Effect of the Environment on alpha-Al_2O_3 (0001) Surface Structures
We report that calculating the Gibbs free energy of the alpha-Al_2O_3 (0001)
surfaces in equilibrium with a realistic environment containing both oxygen and
hydrogen species is essential for obtaining theoretical predictions consistent
with experimental observations. Using density-functional theory we find that
even under conditions of high oxygen partial pressure, the metal terminated
surface is surprisingly stable. An oxygen terminated alpha-Al_2O_3 (0001)
surface becomes stable only if hydrogen is present on the surface. In addition,
including hydrogen on the surface resolves discrepancies between previous
theoretical work and experimental results with respect to the magnitude and
direction of surface relaxations.Comment: 4 pages including 2 figures. Submitted to Phys. Rev. Lett. Related
publications can be found at http://www.fhi-berlin.mpg.de/th/paper.htm
Elastin-like-recombinamers multilayered nanofibrous scaffolds for cardiovascular applications
Producción CientÃficaCoronary angioplasty is the most widely used technique for removing atherosclerotic plaques in blood vessels. The regeneration of the damaged intima layer after this treatment is still one of the major challenges in the field of cardiovascular tissue engineering. Different polymers have been used in scaffold manufacturing in order to improve tissue regeneration. Elastin-mimetic polymers are a new class of molecules that have been synthesized and used to obtain small diameter fibers with specific morphological characteristics. Elastin-like polymers produced by recombinant techniques and called elastin-like recombinamers (ELRs) are particularly promising due to their high degree of functionalization. Generally speaking, ELRs can show more complex molecular designs and a tighter control of their sequence than other chemically synthetized polymers Rodriguez Cabello et al (2009 Polymer 50 5159–69, 2011 Nanomedicine 6 111–22). For the fabrication of small diameter fibers, different ELRs were dissolved in 2,2,2-fluoroethanol (TFE). Dynamic light scattering was used to identify the transition temperature and get a deep characterization of the transition behavior of the recombinamers. In this work, we describe the use of electrospinning technique for the manufacturing of an elastic fibrous scaffold; the obtained fibers were characterized and their cytocompatibility was tested in vitro. A thorough study of the influence of voltage, flow rate and distance was carried out in order to determine the appropriate parameters to obtain fibrous mats without beads and defects. Moreover, using a rotating mandrel, we fabricated a tubular scaffold in which ELRs containing different cell adhesion sequences (mainly REDV and RGD) were collected. The stability of the scaffold was improved by using genipin as a crosslinking agent. Genipin-ELRs crosslinked scaffolds show a good stability and fiber morphology. Human umbilical vein endothelial cells were used to assess the in vitro bioactivity of the cell adhesion domains within the backbone of the ELRs.2018-08-0
Optical signature of erythrocytes by light scattering in microfluidic flows
A camera-based light scattering approach coupled with a viscoelasticity-induced cell migration technique has been used to characterize the morphological properties of erythrocytes in microfluidic flows. We have obtained the light scattering profiles (LSPs) of individual living cells in microfluidic flows over a wide angular range and matched them with scattering simulations to characterize their morphological properties. The viscoelasticity-induced 3D cell alignment in microfluidic flows has been investigated by bright-field and holographic microscopy tracking, where the latter technique has been used to obtain precise cell alignment profiles in-flow. Such information allows variable cell probability control in microfluidic flows at very low viscoelastic polymer concentrations, obtaining cell measurements that are almost physiological. Our results confirm the possibility of precise, label-free analysis of individual living erythrocytes in microfluidic flows
Interplay of superexchange and orbital degeneracy in Cr-doped LaMnO3
We report on structural, magnetic and Electron Spin Resonance (ESR)
investigations in the manganite system LaMn_{1-x}Cr_{x}O_{3} (x<=0.5). Upon
Cr-doping we observe a reduction of the Jahn-Teller distortion yielding less
distorted orthorhombic structures. A transition from the Jahn-Teller distorted
O' to the pseudocubic O phase occurs between 0.3<x<0.4. A clear connection
between this transition and the doping dependence of the magnetic and ESR
properties has been observed. The effective moments determined by ESR seem
reduced with respect to the spin-only value of both Mn^{3+} and Cr^{3+} ions
Electron correlations for ground state properties of group IV semiconductors
Valence energies for crystalline C, Si, Ge, and Sn with diamond structure
have been determined using an ab-initio approach based on information from
cluster calculations. Correlation contributions, in particular, have been
evaluated in the coupled electron pair approximation (CEPA), by means of
increments obtained for localized bond orbitals and for pairs and triples of
such bonds. Combining these results with corresponding Hartree-Fock (HF) data,
we recover about 95 % of the experimental cohesive energies. Lattice constants
are overestimated at the HF level by about 1.5 %; correlation effects reduce
these deviations to values which are within the error bounds of this method. A
similar behavior is found for the bulk modulus: the HF values which are
significantly too high are reduced by correlation effects to about 97 % of the
experimental values.Comment: 22 pages, latex, 2 figure
Nanosized Sodium-Doped Lanthanum Manganites: Role of the Synthetic Route on their Physical Properties
In this paper we present the results of the synthesis and characterisation of
nanocrystalline La1-xNaxMnO3+delta samples. Two synthetic routes were employed:
polyacrylamide-based sol-gel and propellant synthesis. Pure, single phase
materials were obtained with grain size around 35 nm for the sol-gel samples
and around 55 nm for the propellant ones, which moreover present a more broaden
grain size distribution. For both series a superparamagnetic behaviour was
evidenced by means of magnetisation and EPR measurements with peculiar features
ascribable to the different grain sizes and morphology. Preliminary
magnetoresistivity measurements show enhanced low-field (< 1 T)
magnetoresistance values which suggest an interesting applicative use of these
manganites.Comment: 31 Pages 10 Figures to appear in Chem. Mate
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