549 research outputs found
(1RS,4SR)-3-Dichloromethylene-1,4-dimethyl-2-oxabicyclo[2.2.2]oct-5-ene
X-ray crystallography was used to confirm the structure of the enantio-enriched title compound, C10H12Cl2O, a bicylic enol ether. A bridged boat-like structure is adopted and the dichloromethylene C atom is positioned significantly removed from the core bicyclic unit. In the crystal structure, molecules pack to form sheets approximately perpendicular to the a and c axes
The constraint equations for the Einstein-scalar field system on compact manifolds
We study the constraint equations for the Einstein-scalar field system on
compact manifolds. Using the conformal method we reformulate these equations as
a determined system of nonlinear partial differential equations. By introducing
a new conformal invariant, which is sensitive to the presence of the initial
data for the scalar field, we are able to divide the set of free conformal data
into subclasses depending on the possible signs for the coefficients of terms
in the resulting Einstein-scalar field Lichnerowicz equation. For many of these
subclasses we determine whether or not a solution exists. In contrast to other
well studied field theories, there are certain cases, depending on the mean
curvature and the potential of the scalar field, for which we are unable to
resolve the question of existence of a solution. We consider this system in
such generality so as to include the vacuum constraint equations with an
arbitrary cosmological constant, the Yamabe equation and even (all cases of)
the prescribed scalar curvature problem as special cases.Comment: Minor changes, final version. To appear: Classical and Quantum
Gravit
Arithmeticity vs. non-linearity for irreducible lattices
We establish an arithmeticity vs. non-linearity alternative for irreducible
lattices in suitable product groups, such as for instance products of
topologically simple groups. This applies notably to a (large class of)
Kac-Moody groups. The alternative relies on a CAT(0) superrigidity theorem, as
we follow Margulis' reduction of arithmeticity to superrigidity.Comment: 11 page
Knaster's problem for -symmetric subsets of the sphere
We prove a Knaster-type result for orbits of the group in
, calculating the Euler class obstruction. Among the consequences
are: a result about inscribing skew crosspolytopes in hypersurfaces in , and a result about equipartition of a measures in
by -symmetric convex fans
A compactness theorem for scalar-flat metrics on manifolds with boundary
Let (M,g) be a compact Riemannian manifold with boundary. This paper is
concerned with the set of scalar-flat metrics which are in the conformal class
of g and have the boundary as a constant mean curvature hypersurface. We prove
that this set is compact for dimensions greater than or equal to 7 under the
generic condition that the trace-free 2nd fundamental form of the boundary is
nonzero everywhere.Comment: 49 pages. Final version, to appear in Calc. Var. Partial Differential
Equation
Special fast diffusion with slow asymptotics. Entropy method and flow on a Riemannian manifold
We consider the asymptotic behaviour of positive solutions of the
fast diffusion equation
posed for x\in\RR^d, , with a precise value for the exponent
. The space dimension is so that , and even
for . This case had been left open in the general study \cite{BBDGV} since
it requires quite different functional analytic methods, due in particular to
the absence of a spectral gap for the operator generating the linearized
evolution.
The linearization of this flow is interpreted here as the heat flow of the
Laplace-Beltrami operator of a suitable Riemannian Manifold (\RR^d,{\bf g}),
with a metric which is conformal to the standard \RR^d metric.
Studying the pointwise heat kernel behaviour allows to prove {suitable
Gagliardo-Nirenberg} inequalities associated to the generator. Such
inequalities in turn allow to study the nonlinear evolution as well, and to
determine its asymptotics, which is identical to the one satisfied by the
linearization. In terms of the rescaled representation, which is a nonlinear
Fokker--Planck equation, the convergence rate turns out to be polynomial in
time. This result is in contrast with the known exponential decay of such
representation for all other values of .Comment: 37 page
About curvature, conformal metrics and warped products
We consider the curvature of a family of warped products of two
pseduo-Riemannian manifolds and furnished with metrics of
the form and, in particular, of the type , where are smooth
functions and is a real parameter. We obtain suitable expressions for the
Ricci tensor and scalar curvature of such products that allow us to establish
results about the existence of Einstein or constant scalar curvature structures
in these categories. If is Riemannian, the latter question involves
nonlinear elliptic partial differential equations with concave-convex
nonlinearities and singular partial differential equations of the
Lichnerowicz-York type among others.Comment: 32 pages, 3 figure
Structural and Electronic Instabilities in Polyacenes: Density Matrix Renormalization Group Study of a Long--Range Interacting Model
We have carried out Density Matrix Renormalization Group (DMRG) calculations
on the ground state of long polyacene oligomers within a Pariser-Parr-Pople
(PPP) Hamiltonian. The PPP model includes long-range electron correlations
which are required for physically realistic modeling of conjugated polymers. We
have obtained the ground state energy as a function of the dimerization
and various correlation functions and structure factors for
. From energetics, we find that while the nature of the Peierls'
instabilityin polyacene is conditional and strong electron correlations enhance
the dimerization. The {\it cis} form of the distortion is favoured over the
{\it trans} form. However, from the analysis of correlation functions and
associated structure factors, we find that polyacene is not susceptible to the
formation of a bond order wave (BOW), spin density wave (SDW) or a charge
density wave (CDW) in the ground state.Comment: 31 pages, latex, 13 figure
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