Kinetics and thermodynamics of first-order Markov chain copolymerization

We report a theoretical study of stochastic processes modeling the growth of first-order Markov copolymers, as well as the reversed reaction of depolymerization. These processes are ruled by kinetic equations describing both the attachment and detachment of monomers. Exact solutions are obtained for these kinetic equations in the steady regimes of multicomponent copolymerization and depolymerization. Thermodynamic equilibrium is identified as the state at which the growth velocity is vanishing on average and where detailed balance is satisfied. Away from equilibrium, the analytical expression of the thermodynamic entropy production is deduced in terms of the Shannon disorder per monomer in the copolymer sequence. The Mayo-Lewis equation is recovered in the fully irreversible growth regime. The theory also applies to Bernoullian chains in the case where the attachment and detachment rates only depend on the reacting monomer

Redundancy of classical and quantum correlations during decoherence

We analyze the time dependence of entanglement and total correlations between a system and fractions of its environment in the course of decoherence. For the quantum Brownian motion model we show that the entanglement and total correlations have rather different dependence on the size of the environmental fraction. Redundancy manifests differently in both types of correlations and can be related with induced--classicality. To study this we introduce a new measure of redundancy and compare it with the existing one.Comment: 6 pages, 4 figure

Statistical Complexity of Simple 1D Spin Systems

We present exact results for two complementary measures of spatial structure generated by 1D spin systems with finite-range interactions. The first, excess entropy, measures the apparent spatial memory stored in configurations. The second, statistical complexity, measures the amount of memory needed to optimally predict the chain of spin values. These statistics capture distinct properties and are different from existing thermodynamic quantities.Comment: 4 pages with 2 eps Figures. Uses RevTeX macros. Also available at http://www.santafe.edu/projects/CompMech/papers/CompMechCommun.htm

Nonlocal resources in the presence of Superselection Rules

Superselection rules severely alter the possible operations that can be implemented on a distributed quantum system. Whereas the restriction to local operations imposed by a bipartite setting gives rise to the notion of entanglement as a nonlocal resource, the superselection rule associated with particle number conservation leads to a new resource, the \emph{superselection induced variance} of local particle number. We show that, in the case of pure quantum states, one can quantify the nonlocal properties by only two additive measures, and that all states with the same measures can be asymptotically interconverted into each other by local operations and classical communication. Furthermore we discuss how superselection rules affect the concepts of majorization, teleportation and mixed state entanglement.Comment: 4 page

Natural Metric for Quantum Information Theory

We study in detail a very natural metric for quantum states. This new proposal has two basic ingredients: entropy and purification. The metric for two mixed states is defined as the square root of the entropy of the average of representative purifications of those states. Some basic properties are analyzed and its relation with other distances is investigated. As an illustrative application, the proposed metric is evaluated for 1-qubit mixed states.Comment: v2: enlarged; presented at ISIT 2008 (Toronto

Quantum superadditivity in linear optics networks: sending bits via multiple access Gaussian channels

We study classical capacity regions of quantum Gaussian multiple access channels (MAC). In classical variants of such channels, whilst some capacity superadditivity-type effects such as the so called {\it water filling effect} may be achieved, a fundamental classical additivity law can still be identified, {\it viz.} adding resources to one sender is never advantageous to other senders in sending their respective information to the receiver. Here, we show that quantum resources allows violation of this law, by providing two illustrative schemes of experimentally feasible Gaussian MACs.Comment: 4 pages, 2 figure

The classical capacity of quantum thermal noise channels to within 1.45 bits

We find a tight upper bound for the classical capacity of quantum thermal noise channels that is within $1/\ln 2$ bits of Holevo's lower bound. This lower bound is achievable using unentangled, classical signal states, namely displaced coherent states. Thus, we find that while quantum tricks might offer benefits, when it comes to classical communication they can only help a bit.Comment: Two pages plus a bi

Using mutual information to measure order in model glass-formers

Whether or not there is growing static order accompanying the dynamical heterogeneity and increasing relaxation times seen in glassy systems is a matter of dispute. An obstacle to resolving this issue is that the order is expected to be amorphous and so not amenable to simple order parameters. We use mutual information to provide a general measurement of order that is sensitive to multi-particle correlations. We apply this to two glass-forming systems (2D binary mixtures of hard disks with different size ratios to give varying amounts of hexatic order) and show that there is little growth of amorphous order in the system without crystalline order. In both cases we measure the dynamical length with a four-point correlation function and find that it increases significantly faster than the static lengths in the system as density is increased. We further show that we can recover the known scaling of the dynamic correlation length in a kinetically constrained model, the 2-TLG.Comment: 10 pages, 12 Figure

Experimental Observation of Quantum Correlations in Modular Variables

We experimentally detect entanglement in modular position and momentum variables of photon pairs which have passed through $D$-slit apertures. We first employ an entanglement criteria recently proposed in [Phys. Rev. Lett. {\bf 106}, 210501 (2011)], using variances of the modular variables. We then propose an entanglement witness for modular variables based on the Shannon entropy, and test it experimentally. Finally, we derive criteria for Einstein-Podolsky-Rosen-Steering correlations using variances and entropy functions. In both cases, the entropic criteria are more successful at identifying quantum correlations in our data.Comment: 7 pages, 4 figures, comments welcom

Modeling Maxwell's demon with a microcanonical Szilard engine

Following recent work by Marathe and Parrondo [PRL, 104, 245704 (2010)], we construct a classical Hamiltonian system whose energy is reduced during the adiabatic cycling of external parameters, when initial conditions are sampled microcanonically. Combining our system with a device that measures its energy, we propose a cyclic procedure during which energy is extracted from a heat bath and converted to work, in apparent violation of the second law of thermodynamics. This paradox is resolved by deriving an explicit relationship between the average work delivered during one cycle of operation, and the average information gained when measuring the system's energy