308 research outputs found
Optical spectroscopy of the microquasar GRS 1758-258: a possible intermediate mass system?
Context. GRS 1758-258 is one of two prototypical microquasars towards the
Galactic Center direction discovered almost a quarter of a century ago. The
system remains poorly studied in the optical domain due to its counterpart
being a very faint and absorbed target in a crowded region of the sky. Aims.
Our aim is to investigate GRS 1758-258 in order to shed light on the nature of
the stellar binary components. In particular, the main physical parameters of
the donor star, such as the mass or the spectral type, are not yet well
constrained. Methods. GRS 1758-258 has remained so far elusive to optical
spectroscopy owing to its observational difficulties. Here, we use this
traditional tool of stellar astronomy at low spectral resolution with a 10 m
class telescope and a long slit spectrograph. Results. An improved spectrum is
obtained as compared to previous work. The quality of the data does not allow
the detection of emission or absorption features but, nevertheless, we manage
to partially achieve our aims comparing the de-reddened continuum with the
spectral energy distribution expected from an irradiated disc model and
different donor star templates. Conclusions. We tentatively propose that GRS
1758-258 does not host a giant star companion. Instead, a main sequence star
with mid-A spectral type appears to better agree with our data. The main
impacts of this finding are the possibility that we are dealing with an
intermediate mass system and, in this case, the prediction of an orbital period
significantly shorter than previously proposed.Comment: 5 pages, 6 figures, accepted for publication in A&
Microwave-assisted valorization of pig bristles: towards visible light photocatalytic chalcocite composite
Waste valorization for the production of valuable materials is of great importance for sustainable development. Herein, a new green methodology for the synthesis of photocatalytically active copper sulfide (Cu2S) carbon composites using pig bristles is reported. The catalyst was prepared via microwave-assisted methodology using ethylene glycol as the solvent, pig bristles as the sulfur and carbon source, and copper chloride as the metal precursor. Cu2S carbon composites (denoted as pb-Cu2S, where âpbâ stands for âpig bristleâ) were characterized by XRD, N2 physisorption, EDX and UV-Vis spectroscopy. In order to validate the practical utilization of pig bristle-derived chemicals, the photocatalytic degradation of methyl red using pb-Cu2S was investigated under white, blue, green and red visible light irradiation
Real-time evolution of a large-scale relativistic jet
Context. Astrophysical jets are ubiquitous in the Universe on all scales, but
their large-scale dynamics and evolution in time are hard to observe since they
usually develop at a very slow pace.
Aims. We aim to obtain the first observational proof of the expected
large-scale evolution and interaction with the environment in an astrophysical
jet. Only jets from microquasars offer a chance to witness the real-time,
full-jet evolution within a human lifetime, since they combine a 'short', few
parsec length with relativistic velocities.
Methods. The methodology of this work is based on a systematic recalibraton
of interferometric radio observations of microquasars available in public
archives. In particular, radio observations of the microquasar GRS 1758-258
over less than two decades have provided the most striking results.
Results. Significant morphological variations in the extended jet structure
of GRS 1758-258 are reported here that were previously missed. Its northern
radio lobe underwent a major morphological variation that rendered the hotspot
undetectable in 2001 and reappeared again in the following years. The reported
changes confirm the Galactic nature of the source. We tentatively interpret
them in terms of the growth of instabilities in the jet flow. There is also
evidence of surrounding cocoon. These results can provide a testbed for models
accounting for the evolution of jets and their interaction with the
environment.Comment: 5 pages, 3 figures, 2 tables. Accepted for publication in Astronomy
and Astrophysics Letter
A Sustainable Approach for the Synthesis of Catalytically Active Peroxidase-Mimic ZnS Catalysts
Zinc sulfides are emerging as promising catalysts in different fields such as photochemistry or organic synthesis. Nevertheless, the synthesis of ZnS compounds normally requires the utilization of toxic sulfur precursors, e.g., thiourea which is a contaminant and carcinogenic agent. As a result, new green and sustainable synthetic methodologies are needed. Herein, an innovative, simple, and cheap approach for the synthesis of ZnS carbon composites is reported. Zinc acetate dihydrate was employed as metal precursor while wasted pig bristles were employed as carbon and sulfur source. The phase and the morphology of the compounds were analyzed by XRD, XPS, SEM, and EDX and the surface area was determined by nitrogen physisorption. ZnS carbon materials showed remarkable peroxidase-like catalytic activity for two different model reactions: the liquid-phase selective oxidation of benzyl alcohol and toluene to benzaldehyde (conversions up to 63% and 29% and selectivities up to 86% and 87%, respectively) using hydrogen peroxide as oxidant under microwave irradiation
Highly active catalytic Ru/TiO2 nanomaterials for continuous production of Îł-valerolactone
Green energy production from renewable sources is an attractive but challenging topic to face the likely energy crisis scenario in the future. In the current work, a series of versatile Ru/TiO2 catalysts were simply synthesized and employed in continuous flow catalytic transfer hydrogenation of industrially derived methyl levulinate biowaste (from Avantium Chemicals B.V.) to Îł-valerolactone. Different analytical techniques were applied in the characterization of the as-synthesized catalysts, including XRD, SEM, EDX, TEM and XPS etc. The effects of various reaction conditions (e.g. temperature, concentration and flow rate) were investigated. Results suggested that optimum dispersion and distribution of Ru on the TiO2 surface could efficiently promote production of Îł-valerolactone, with 5% Ru/TiO2 catalyst providing excelling catalytic performance and stability as compared to commercial Ru catalysts
Identification of the optical and near-infrared counterpart of GRS 1758-258
Context. Understood to be a microquasar in the Galactic center region, GRS
1758-258 has not yet been unambiguously identified to have an
optical/near-infrared counterpart, mainly because of the high absorption and
the historic lack of suitable astrometric stars, which led to the use of
secondary astrometric solutions. Although it is considered with 1E 1740.7-2942
as the prototypical microquasar in the Galactic center region, the Galactic
origin of both sources has not yet been confirmed. Aims. We attempt to improve
previous astrometry to identify a candidate counterpart to GRS 1758-258. We
present observations with the Gran Telescopio de Canarias (GTC), in which we
try to detect any powerful emission lines that would infer an extragalactic
origin of this source. Methods. We use modern star catalogues to reanalyze
archival images of the GRS 1758-258 field in the optical and near-infrared
wavelengths, and compute a new astrometric solution. We also reanalyzed
archival radio data of GRS 1758-258 to determine a new and more accurate radio
position. Results. Our improved astrometric solution for the GRS 1758-258 field
represents a significant advancement on previous works and allows us to
identify a single optical/near-infrared source, which we propose as the
counterpart of GRS 1758-258. The GTC spectrum of this source is however of low
signal-to-noise ratio and does not rule out a Galactic origin. Hence, new
spectral observations are required to confirm or discard a Galactic nature.Comment: 4 pages, 3 figures, accepted by Astronomy and Astrophysic
Facile mechanochemical modification of g-C3N4 for selective photo-oxidation of benzyl alcohol
Graphitic carbon nitride enriched with ZnO or Fe2O3 were synthesized using a simple one-pot mechanochemical method. By using this method, composite samples were synthetized without the production of any potentially hazardous waste. The synthesized materials were used as catalysts during the selective photo-oxidation of benzyl alcohol. Both composite materials displayed an enhancement of the activity and benzaldehyde selectivity with respect to the pure g-C3N4. The most active catalyst was Fe2O3/g-C3N4. The conversion and benzaldehyde selectivity of this sample were 20 and 70 %, respectively. It showed a considerable increase of the benzaldehyde selectivity compared to the pure g-C3N4 and TiO2 P25 commercial reference. A complete structural and electronic characterization using Scanning Electron Microscopy-Energy Dispersive (SEM-EDX), BET measurements, X-ray diffraction (XRD), X-ray Photoelectron (XPS), and UVâvisible spectroscopies was carried out. The characterization analysis pointed out the leading role of the crystallinity and surface concentration over the activity and benzaldehyde selectivity of the reactio
Candidate counterparts to the soft gamma-ray flare in the direction of LS i +61 303
Context. A short duration burst reminiscent of a soft gamma-ray repeater/anomalous X-ray pulsar behaviour was detected in the direction of LS I +61 303 by the Swift satellite. While the association with this well known gamma-ray binary is likely, a different origin cannot be excluded.
Aims. We explore the error box of this unexpected flaring event and establish the radio, near-infrared and X-ray sources in our search for any peculiar alternative counterpart.
Methods. We carried out a combined analysis of archive Very Large Array radio data of LS I +61 303 sensitive to both compact and extended emission. We also reanalysed previous near infrared observations with the 3.5 m telescope of the Centro AstronĂłmico Hispano Alemn and X-ray observations with the Chandra satellite.
Results. Our deep radio maps of the LS I +61 303 environment represent a significant advancement on previous work and 16 compact radio sources in the LS I +61 303 vicinity are detected. For some detections, we also identify near infrared and X-ray counterparts. Extended emission features in the field are also detected and confirmed. The possible connection of some of these sources with the observed flaring event is considered. Based on these data, we are unable to claim a clear association between the Swift-BAT flare and any of the sources reported here. However, this study represents the most sophisticated attempt to determine possible alternative counterparts other than LS I +61 303.Facultad de Ciencias AstronĂłmicas y GeofĂsica
Counterpart candidates to the unidentified Fermi source 0FGL J1848.6-0138
Aims: We aim to contribute to the identification of the counterpart for one of the bright sources of gamma-rays in the catalogue obtained and released by the Fermi collaboration. Methods: Our work is based on a extensive identification of sources from different wavelength catalogues and databases. Results: As a first result, we report the finding of a few counterpart candidates inside the 95% confidence error box of the Fermi LAT unidentified gamma-ray source 0FGL J1848.6-0138. The globular cluster GLIMPSE-C01 is remarkably distinctive being among the most peculiar objects consistent with both the position uncertainty in the gamma-ray source and a conceivable physical scenario for gamma-ray production. The Fermi-observed spectrum is compared with theoretical predictions in the literature and the association is found to be plausible but not yet certain because of its low X-ray to gamma-ray luminosity ratio. Other competing counterparts are also discussed. In particular, we pay special attention to a possible Pulsar Wind Nebula inside the Fermi error box, whose nature is yet to be confirmed. Conclusions: Both a globular cluster and an infrared source resembling a Pulsar Wind Nebula were found to be in positional agreement with 0FGL J1848.6-0138. In addition, other interesting objects in the field are also reported. Future gamma-ray observations will reduce the position uncertainty and we hope eventually confirm one of the counterpart candidates reported here. If GLIMPSE-C01 is confirmed together with the possible Fermi detection of the well known globular cluster 47 Tuc, then this would provide strong support to theoretical predictions that globular clusters are possible gamma-ray sources.Facultad de Ciencias AstronĂłmicas y GeofĂsica
Candidate counterparts to the soft gamma-ray flare in the direction of LS i +61 303
Context. A short duration burst reminiscent of a soft gamma-ray repeater/anomalous X-ray pulsar behaviour was detected in the direction of LS I +61 303 by the Swift satellite. While the association with this well known gamma-ray binary is likely, a different origin cannot be excluded.
Aims. We explore the error box of this unexpected flaring event and establish the radio, near-infrared and X-ray sources in our search for any peculiar alternative counterpart.
Methods. We carried out a combined analysis of archive Very Large Array radio data of LS I +61 303 sensitive to both compact and extended emission. We also reanalysed previous near infrared observations with the 3.5 m telescope of the Centro AstronĂłmico Hispano Alemn and X-ray observations with the Chandra satellite.
Results. Our deep radio maps of the LS I +61 303 environment represent a significant advancement on previous work and 16 compact radio sources in the LS I +61 303 vicinity are detected. For some detections, we also identify near infrared and X-ray counterparts. Extended emission features in the field are also detected and confirmed. The possible connection of some of these sources with the observed flaring event is considered. Based on these data, we are unable to claim a clear association between the Swift-BAT flare and any of the sources reported here. However, this study represents the most sophisticated attempt to determine possible alternative counterparts other than LS I +61 303.Facultad de Ciencias AstronĂłmicas y GeofĂsica
- âŠ