753 research outputs found
A variationally computed line list for hot NH3
We present 'BYTe', a comprehensive 'hot' line list for the ro-vibrational
transitions of ammonia, 14NH3, in its ground electronic state. This line list
has been computed variationally using the program suite TROVE, a new
spectroscopically-determined potential energy surface and an ab initio dipole
moment surface. BYTe, is designed to be used at all temperatures up to 1500K.
It comprises 1137650964 transitions in the frequency range from 0 to 12000
cm-1, constructed from 1366519 energy levels below 18000 cm-1 having J values
below 36. Comparisons with laboratory data confirm the accuracy of the line
list which is suitable for modelling a variety of astrophysical problems
including the atmospheres of extrasolar planets and brown dwarfs.Comment: the paper has been submitted to MNRA
Comet C/2004 Q2 (MACHHOLZ): Parent Volatiles, a Search for Deuterated Methane, and Constraint on the CH4 Spin Temperature
High-dispersion (l/dl ~ 25,000) infrared spectra of Comet C/2004 Q2
(Machholz) were acquired on Nov. 28-29, 2004, and Jan. 19, 2005 (UT dates) with
NIRSPEC at the Keck-2 telescope on Mauna Kea. We detected H2O, CH4, C2H2, C2H6,
CO, H2CO, CH3OH, HCN, and NH3 and we conducted a sensitive search for CH3D. We
report rotational temperatures, production rates, and mixing ratios (with
respect to H2O) at heliocentric distances of 1.49 AU (Nov. 2004) and 1.21 AU
(Jan. 2005). We highlight three principal results: (1) The mixing ratios of
parent volatiles measured at 1.49 AU and 1.21 AU agree within confidence
limits, consistent with homogeneous composition in the mean volatile release
from the nucleus of C/2004 Q2. Notably, the relative abundance of C2H6/C2H2 is
substantially higher than those measured in other comets, while the mixing
ratios C2H6/H2O, CH3OH/H2O, and HCN/H2O are similar to those observed in
comets, referred to as "organics-normal". (2) The spin temperature of CH4 is >
35-38 K, an estimate consistent with the more robust spin temperature found for
H2O. (3) We obtained a 3s upper limit of CH3D/CH4 < 0.020 (D/H < 0.005). This
limit suggests that methane released from the nucleus of C/2004 Q2 is not
dominated by a component formed in extremely cold (near 10 K) environments.
Formation pathways of both interstellar and nebular origin consistent with the
measured D/H in methane are discussed. Evaluating the relative contributions of
these pathways requires further modeling of chemistry including both gas-phase
and gas-grain processes in the natal interstellar cloud and in the
protoplanetary disk.Comment: Accepted by The Astrophysical Journa
Volatile Composition and Outgassing in C/2018 Y1 (IWAMOTO): Extending Detection Limits for High-Resolution IR Cometary Spectroscopy at the NASA-IRTF
We used iSHELL, the powerful high-resolution ( /~ 40,000) cross-dispersed IR spectrograph at the NASA-IRTF to measure the native ice composition and outgassing of moderately bright, long-period comet C/2018 Y1 (Iwamoto) (hereafter Y1) within weeks of its discovery. We measured production rates for H2O, and production rates and abundance ratios relative to H2O for eight trace molecules, including the most complete measure of cometary CH4 achieved to date. Compared with mean abundances measured among comets, our study revealed enriched CH3OH and C2H6 yet depleted CO and C2H2, perhaps indicating highly efficient H- atom addition on interstellar grains prior to their incorporation into the nucleus. The combined high spectral resolving power and broad spectral coverage of iSHELL allowed characterizing cometary composition using only three instrument settings, and its long-slit coverage allowed comparing the spatial distributions of molecular emissions and dust continuum
IRCS/Subaru Observations of Water in the Inner Coma of Comet 73P-B/Schwassmann-Wachmann 3: Spatially Resolved Rotational Temperatures and Ortho-Para Ratios
Comet 73P-B/Schwassmann-Wachmann 3 was observed with IRCS/Subaru at
geocentric distance of 0.074 AU on UT 10 May 2006. Multiple H2O emission lines
were detected in non-resonant fluorescence near 2.9 microns. No significant
variation in total H2O production rate was found during the (3 hour) duration
of our observations. H2O rotational temperatures and ortho-to-para abundance
ratios were measured for several positions in the coma. The temperatures
extracted from two different time intervals show very similar spatial
distributions. For both, the rotational temperature decreased from ~110 K to
~90 K as the projected distance from the nucleus increased from ~5 to ~30 km.
We see no evidence for OPR change in the coma. The H2O ortho-para ratio is
consistent with the statistical equilibrium value (3.0) for all spatially
resolved measurements. This implies a nuclear spin temperature higher than ~ 45
K.Comment: accepted for Icaru
Effect of an isoflavones-containing red clover preparation and alkaline supplementation on bone metabolism in ovariectomized rats
The aim of this study was to test the combined effect of a quality-controlled red clover extract (RCE) standardized to contain 40% isoflavones by weight (genistein, daidzein, biochanin A, and formononetin present as hydrolyzed aglycones) together with a modified alkaline supplementation on bone metabolic and biomechanical parameters in an experimental model of surgically-induced menopause. Sprague–Dawley female rats were maintained under controlled standard conditions of light and fed with conventional food of standard calcium content and no alfalfa or soybean components. Rats were randomized into four groups: Group A represented normal rats (sham operated) while three other groups were ovariectomized (OVX) and fed for three months as follows: standard food (group B), 6 mg/kg/day food mixed with RCE (Group C), or given 6 mg/kg/day of RCE plus a modified alkaline supplementation (BP) through a nasogastric tube at a dose of 16 mg (group D). The animals were killed 90 days after surgery. As compared to group B, RCE or RCE + BP treatments brought about significantly higher level of estradiol and mitigated the weight loss of the uterus and improved maximum load of the femoral neck. Osteocalcin level showed an over 65% increase in group B but both RCE and RCE + BP treatments prevented such abnormality with a significantly better result in RCE + BP group which virtually normalized such parameter as well as urinary excretion of DPD. Group C and D reduced the over 20% loss of bone mineral density and bone mineral content/body weight ratio observed in untreated post-ovariectomy group. Untreated ovariectomy caused about 48% decrease of cancellous bone mass in the femoral neck while this abnormality was prevented at similar extent by both RCE and RCE + BP treatments. Ovariectomy determined an over 80% increase of bone alkaline phosphatase (BALP) level but both RCE and RCE + BP treatments significantly mitigated such variable. The BALP decrease yielded by the combined RCE + BP treatment was statistically lower than RCE alone. Taken together these data show that red clover preparation in dosages amenable to clinical practice do improve OVX-induced osteoporosis while a mild metabolic alkalosis might further synergize some therapeutic aspects
Chandra Observations of Type Ia Supernovae: Upper Limits to the X-ray Flux of SN 2002bo, SN 2002ic, SN 2005gj, and SN 2005ke
We set sensitive upper limits to the X-ray emission of four Type Ia
supernovae (SNe Ia) using the Chandra X-ray Observatory. SN 2002bo, a normal,
although reddened, nearby SN Ia, was observed 9.3 days after explosion. For an
absorbed, high temperature bremsstrahlung model the flux limits are 3.2E-16
ergs/cm^2/s (0.5-2 keV band) and 4.1E-15 ergs/cm^2/s (2-10 keV band). Using
conservative model assumptions and a 10 km/s wind speed, we derive a mass loss
rate of \dot{M} ~ 2E-5 M_\odot/yr, which is comparable to limits set by the
non-detection of Halpha lines from other SNe Ia. Two other objects, SN 2002ic
and SN 2005gj, observed 260 and 80 days after explosion, respectively, are the
only SNe Ia showing evidence for circumstellar interaction. The SN 2002ic X-ray
flux upper limits are ~4 times below predictions of the interaction model
currently favored to explain the bright optical emission. To resolve this
discrepancy we invoke the mixing of cool dense ejecta fragments into the
forward shock region, which produces increased X-ray absorption. A modest
amount of mixing allows us to accommodate the Chandra upper limit. SN 2005gj is
less well studied at this time. Assuming the same circumstellar environment as
for SN 2002i, the X-ray flux upper limits for SN 2005gj are ~4 times below the
predictions, suggesting that mixing of cool ejecta into the forward shock has
also occurred here. Our reanalysis of Swift and Chandra data on SN 2005ke does
not confirm a previously reported X-ray detection. The host galaxies NGC 3190
(SN 2002bo) and NGC 1371 (SN 2005ke) each harbor a low luminosity (L_X ~ 3-4E40
ergs/s) active nucleus in addition to wide-spread diffuse soft X-ray emission.Comment: 16 pages, to appear in ApJ (20 Nov 2007
Liquid-like thermal conduction in a crystalline solid
A solid conducts heat through both transverse and longitudinal acoustic
phonons, but a liquid employs only longitudinal vibrations. Here, we report
that the crystalline solid AgCrSe2 has liquid-like thermal conduction. In this
compound, Ag atoms exhibit a dynamic duality that they are exclusively involved
in intense low-lying transverse acoustic phonons while they also undergo local
fluctuations inherent in an order-to-disorder transition occurring at 450 K. As
a consequence of this extreme disorder-phonon coupling, transverse acoustic
phonons become damped as approaching the transition temperature, above which
they are not defined anymore because their lifetime is shorter than the
relaxation time of local fluctuations. Nevertheless, the damped longitudinal
acoustic phonon survives for thermal transport. This microscopic insight might
reshape the fundamental idea on thermal transport properties of matter and
facilitates the optimization of thermoelectrics.Comment: four figures, supplemental informatio
Recent Searches for the Radio Lines of NH_3 in Comets
Radio observations in the ammonia inversion lines of four comets, C/2001 A2
(LINEAR), 153P/Ikeya-Zhang, C/2001 Q4 (NEAT) and C/2002 T7 (LINEAR), were
performed at the Effelsberg 100-m Radio Telescope during their respective close
approaches to Earth. None of the four lowest energy metastable lines
(J,K=J),J=1--4, could be detected in these comets. We derive the following 3
sigma upper bounds on the NH_3 production rate, and c omparing to the
corresponding water production rates, percentage NH_3 abundances relative to
H_2O:
Q(NH_3) < 1.9x10^26 s^-1 (0.63%) for C/2001 A2 (LINEAR),
Q(NH_3) < 2.7x10^26 s^-1 (0.13%) for C/2001 Q4 (NEAT),
Q(NH_3) < 2.3x10^27 s^-1 (0.74%) for C/2002 T7 (LINEAR) and Q(NH_3) <=
6.3x10^26 s^-1 (0.63%) for Comet 153P/Ikeya-Zhang.
At 0.74% or less, the ammonia-to-water ratios are factors of 2 below the
value for C/1995 O1 (Hale-Bopp) and 1P/Halley, suggesting chemical diversity
between comets. The 18-cm lines of OH were clearly detected in the two comets
observed during the 2004 campaign, thereby validating the cometary ephemerides.Comment: 8 pages, 3 figure
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