Transfer-matrix study of a hard-square lattice gas with two kinds of particles and density anomaly

Using transfer matrix and finite-size scaling methods, we study the thermodynamic behavior of a lattice gas with two kinds of particles on the square lattice. Only excluded volume interactions are considered, so that the model is athermal. Large particles exclude the site they occupy and its four first neighbors, while small particles exclude only their site. Two thermodynamic phases are found: a disordered phase where large particles occupy both sublattices with the same probability and an ordered phase where one of the two sublattices is preferentially occupied by them. The transition between these phases is continuous at small concentrations of the small particles and discontinuous at larger concentrations, both transitions are separated by a tricritical point. Estimates of the central charge suggest that the critical line is in the Ising universality class, while the tricritical point has tricritical Ising (Blume-Emery-Griffiths) exponents. The isobaric curves of the total density as functions of the fugacity of small or large particles display a minimum in the disordered phase.Comment: 9 pages, 7 figures and 4 table

Nature of the collapse transition in interacting self-avoiding trails

We study the interacting self-avoiding trail (ISAT) model on a Bethe lattice of general coordination $q$ and on a Husimi lattice built with squares and coordination $q=4$. The exact grand-canonical solutions of the model are obtained, considering that up to $K$ monomers can be placed on a site and associating a weight $\omega_i$ for a $i$-fold visited site. Very rich phase diagrams are found with non-polymerized (NP), regular polymerized (P) and dense polymerized (DP) phases separated by lines (or surfaces) of continuous and discontinuous transitions. For Bethe lattice with $q=4$ and $K=2$, the collapse transition is identified with a bicritical point and the collapsed phase is associated to the dense polymerized phase (solid-like) instead of the regular polymerized phase (liquid-like). A similar result is found for the Husimi lattice, which may explain the difference between the collapse transition for ISAT's and for interacting self-avoiding walks on the square lattice. For $q=6$ and $K=3$ (studied on the Bethe lattice only), a more complex phase diagram is found, with two critical planes and two coexistence surfaces, separated by two tricritical and two critical end-point lines meeting at a multicritical point. The mapping of the phase diagrams in the canonical ensemble is discussed and compared with simulational results for regular lattices.Comment: 12 pages, 13 figure

Simple Model for Attraction between Like-Charged Polyions

We present a simple model for the possible mechanism of appearance of attraction between like charged polyions inside a polyelectrolyte solution. The attraction is found to be short ranged, and exists only in presence of multivalent counterions. The attraction is produced by the correlations in the condensed layers of counterions surrounding each polyion, and appears only if the number of condensed counterions exceeds the threshold, $n > Z/2 \alpha$, where $\alpha$ is the valence of counterions and $Z$ is the polyion charge.Comment: 4 pages, 4 eps figures, also available at http://www.if.ufrgs.br/~arenzon Figure added and a more detailed discussion of conclusion

Entropy of polydisperse chains: solution on the Bethe lattice

We consider the entropy of polydisperse chains placed on a lattice. In particular, we study a model for equilibrium polymerization, where the polydispersivity is determined by two activities, for internal and endpoint monomers of a chain. We solve the problem exactly on a Bethe lattice with arbitrary coordination number, obtaining an expression for the entropy as a function of the density of monomers and mean molecular weight of the chains. We compare this entropy with the one for the monodisperse case, and find that the excess of entropy due to polydispersivity is identical to the one obtained for the one-dimensional case. Finally, we obtain an exponential distribution of molecular weights.Comment: 5 pages, 2 figures. Reference place

Polymers with attractive interactions on the Husimi tree

We obtain the solution of models of self-avoiding walks with attractive interactions on Husimi lattices built with squares. Two attractive interactions are considered: between monomers on first-neighbor sites and not consecutive along a walk and between bonds located on opposite edges of elementary squares. For coordination numbers q>4, two phases, one polymerized the other non-polymerized, are present in the phase diagram. For small values of the attractive interaction the transition between those phases is continuous, but for higher values a first-order transition is found. Both regimes are separated by a tricritical point. For q=4 a richer phase diagram is found, with an additional (dense) polymerized phase, which is stable for for sufficiently strong interactions between bonds. The phase diagram of the model in the three-dimensional parameter space displays surfaces of continuous and discontinuous phase transitions and lines of tricritical points, critical endpoints and triple points.Comment: 7 pages, 6 figure

Generalized Manna sandpile model with height restrictions

Sandpile models with conserved number of particles (also called fixed energy sandpiles) may undergo phase transitions between active and absorbing states. We generalize the Manna sandpile model with fixed number of particles, introducing a parameter $-1 \leq \lambda \leq 1$ related to the toppling of particles from active sites to its first neighbors. In particular, we discuss a model with height restrictions, allowing for at most two particles on a site. Sites with double occupancy are active, and their particles may be transfered to first neighbor sites, if the height restriction do allow the change. For $\lambda=0$ each one of the two particles is independently assigned to one of the two first neighbors and the original stochastic sandpile model is recovered. For $\lambda=1$ exactly one particle will be placed on each first neighbor and thus a deterministic (BTW) sandpile model is obtained. When $\lambda=-1$ two particles are moved to one of the first neighbors, and this implies that the density of active sites is conserved in the evolution of the system, and no phase transition is observed. Through simulations of the stationary state, we estimate the critical density of particles and the critical exponents as functions of $\lambda$.Comment: 5 pages, 11 figures, IV BMS

Solution of a model of SAW's with multiple monomers per site on the Husimi lattice

We solve a model of self-avoiding walks which allows for a site to be visited up to two times by the walk on the Husimi lattice. This model is inspired in the Domb-Joyce model and was proposed to describe the collapse transition of polymers with one-site interactions only. We consider the version in which immediate self-reversals of the walk are forbidden (RF model). The phase diagram we obtain for the grand-canonical version of the model is similar to the one found in the solution of the Bethe lattice, with two distinct polymerized phases, a tricritical point and a critical endpoint.Comment: 16 pages, including 6 figure