1,349 research outputs found
Mechanism of the fluxional behaviour in (1–5-η-cycloheptadienyl)-(1–5-η-cycloheptatrienyl)iron
Evidence for a 1.2-shift mechanism of the 1-5-η-cycloheptatrienyl moiety with respect to the central iron atom of the title compound is presented together with absolute assignments of the ^(13)C n.m.r. chemical shifts of the C_(7)H_(7) ring. A low-temperature rocking motion of both rings can be frozen out at -70 °C
Low Voltage Electrical Stimulation of Beef Carcasses Slows Carcass Chilling Rate and Improves Steak Color
The objective of this study was to evaluate the influence of two levels of low voltage electrical stimulation (ES) on temperature decline, pH, and meat quality
Spiritual Struggles among Atheists: Links to Psychological Distress and Well-Being
Religious and spiritual struggles (R/S struggles)—tension or conflicts regarding religious or spiritual matters—have been robustly linked to greater psychological distress and lower well-being. Most research in this area has relied on samples consisting predominantly of participants who believe in god(s). Limited research has examined R/S struggles among atheists, generally conflating them with agnostics and other nontheists. This study investigated the prevalence of R/S struggles among atheists and compared atheists to theists in two samples (3978 undergraduates, 1048 Internet workers). Results of a multilevel model showed that atheists experience less demonic, doubt, divine, moral, and overall R/S struggles than theists, but similar levels of interpersonal and ultimate meaning struggles. Correlation and regression analyses among atheists demonstrated links between moral, ultimate meaning, and overall R/S struggles and greater distress (depression and anxiety symptoms) as well as lower well-being (life satisfaction and meaning in life). Even after controlling neuroticism, ultimate meaning struggles continued to predict lower well-being and higher distress across samples; moral struggles also predicted distress independently. This study demonstrates the relevance of R/S struggles to atheists and reinforces the applicability of previous results to atheist samples, but also highlights substantial differences between atheists and theists in certain R/S struggles
Double quantum dot with tunable coupling in an enhancement-mode silicon metal-oxide semiconductor device with lateral geometry
We present transport measurements of a tunable silicon
metal-oxide-semiconductor double quantum dot device with lateral geometry.
Experimentally extracted gate-to-dot capacitances show that the device is
largely symmetric under the gate voltages applied. Intriguingly, these gate
voltages themselves are not symmetric. Comparison with numerical simulations
indicates that the applied gate voltages serve to offset an intrinsic asymmetry
in the physical device. We also show a transition from a large single dot to
two well isolated coupled dots, where the central gate of the device is used to
controllably tune the interdot coupling.Comment: 4 pages, 3 figures, to be published in Applied Physics Letter
Probing Stereoselectivity in Ring-Opening Metathesis Polymerization Mediated by Cyclometalated Ruthenium-Based Catalysts: A Combined Experimental and Computational Study
The microstructures of polymers produced by ring-opening metathesis polymerization (ROMP) with cyclometalated Ru-carbene metathesis catalysts were investigated. A strong bias for a cis,syndiotactic microstructure with minimal head-to-tail bias was observed. In instances where trans errors were introduced, it was determined that these regions were also syndiotactic. Furthermore, hypothetical reaction intermediates and transition structures were analyzed computationally. Combined experimental and computational data support a reaction mechanism in which cis,syndio-selectivity is a result of stereogenic metal control, while microstructural errors are predominantly due to alkylidene isomerization via rotation about the Ru═C double bond
Effects of Feeding Brassica Mixture Cover Crops During Backgrounding on Carcass Traits and Fresh Meat Quality
Objective: Determine effects of feeding brassica-based cover crops to cattle during backgrounding on carcass characteristics and tenderness, flavor, and juiciness of longissimus dorsi steaks
Enhancement mode double top gated MOS nanostructures with tunable lateral geometry
We present measurements of silicon (Si) metal-oxide-semiconductor (MOS)
nanostructures that are fabricated using a process that facilitates essentially
arbitrary gate geometries. Stable Coulomb blockade behavior free from the
effects of parasitic dot formation is exhibited in several MOS quantum dots
with an open lateral quantum dot geometry. Decreases in mobility and increases
in charge defect densities (i.e. interface traps and fixed oxide charge) are
measured for critical process steps, and we correlate low disorder behavior
with a quantitative defect density. This work provides quantitative guidance
that has not been previously established about defect densities for which Si
quantum dots do not exhibit parasitic dot formation. These devices make use of
a double-layer gate stack in which many regions, including the critical gate
oxide, were fabricated in a fully-qualified CMOS facility.Comment: 11 pages, 6 figures, 3 tables, accepted for publication in Phys. Rev.
Internal Temperature Decline Rate in Beef Primals is Reduced in Heavier Carcasses
The objective of this study was to determine the influence of increasing beef hot carcass weights on internal temperature decline during chilling
Effects of Low-stress Weaning on Calf Growth Performance and Carcass Characteristics
The objective of this study was to compare the influence of two low-stress weaning methods with conventional weaning on post-weaning performance and carcass characteristics of beef steers
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