Polyelectrolyte Multilayering on a Charged Planar Surface

The adsorption of highly \textit{oppositely} charged flexible polyelectrolytes (PEs) on a charged planar substrate is investigated by means of Monte Carlo (MC) simulations. We study in detail the equilibrium structure of the first few PE layers. The influence of the chain length and of a (extra) non-electrostatic short range attraction between the polycations and the negatively charged substrate is considered. We show that the stability as well as the microstructure of the PE layers are especially sensitive to the strength of this latter interaction. Qualitative agreement is reached with some recent experiments.Comment: 28 pages; 11 (main) Figs - Revtex4 - Higher resolution Figs can be obtained upon request. To appear in Macromolecule

Soft repulsive mixtures under gravity: brazil-nut effect, depletion bubbles, boundary layering, nonequilibrium shaking

A binary mixture of particles interacting via long-ranged repulsive forces is studied in gravity by computer simulation and theory. The more repulsive A-particles create a depletion zone of less repulsive B-particles around them reminiscent to a bubble. Applying Archimedes' principle effectively to this bubble, an A-particle can be lifted in a fluid background of B-particles. This "depletion bubble" mechanism explains and predicts a brazil-nut effect where the heavier A-particles float on top of the lighter B-particles. It also implies an effective attraction of an A-particle towards a hard container bottom wall which leads to boundary layering of A-particles. Additionally, we have studied a periodic inversion of gravity causing perpetual mutual penetration of the mixture in a slit geometry. In this nonequilibrium case of time-dependent gravity, the boundary layering persists. Our results are based on computer simulations and density functional theory of a two-dimensional binary mixture of colloidal repulsive dipoles. The predicted effects also occur for other long-ranged repulsive interactions and in three spatial dimensions. They are therefore verifiable in settling experiments on dipolar or charged colloidal mixtures as well as in charged granulates and dusty plasmas.Comment: 10 pages, 11 figure

An Exploratory Investigation of Comparisons of Student Evaluations of Learning Pre and Post COVID-19 at Private and Public Universities

Although universities attempted to provide as little disruption to student learning as possible, problems arose with their responses to the COVID-19 pandemic. The current literature is rich with studies reporting experiences with the transition to the virtual learning of the pandemic era. In pursuit of the most effective learning and instructional modes to transition to in times of crisis, university administrators and faculty members need to know more regarding what worked and did not work in the initial response to the COVID- 19 crisis. Questions remain. Given the pre-COVID-19 dominance of face-to-face instruction did student opinion of online learning change based on their experiences with the mandated transitions to virtual learning? Are the perceptions different for students at private versus public and small versus large institutions? This paper reports the results of an exploratory study of these bifurcations based on an online survey of student opinion conducted in Spring 2021. The findings provide some insight to student perceptions of the efficacy of the changed learning environment experienced by the subject populations

Stable crystalline lattices in two-dimensional binary mixtures of dipolar particles

The phase diagram of binary mixtures of particles interacting via a pair potential of parallel dipoles is computed at zero temperature as a function of composition and the ratio of their magnetic susceptibilities. Using lattice sums, a rich variety of different stable crystalline structures is identified including $A_mB_n$ structures. [$A$ $(B)$ particles correspond to large (small) dipolar moments.] Their elementary cells consist of triangular, square, rectangular or rhombic lattices of the $A$ particles with a basis comprising various structures of $A$ and $B$ particles. For small (dipolar) asymmetry there are intermediate $AB_2$ and $A_2B$ crystals besides the pure $A$ and $B$ triangular crystals. These structures are detectable in experiments on granular and colloidal matter.Comment: 6 pages - 2 figs - phase diagram update

The effects of Non-Gaussian initial conditions on the structure and substructure of Cold Dark Matter halos

We study the structure and substructure of halos obtained in N-body simulations for a Lambda Cold Dark Matter (LCDM) cosmology with non-Gaussian initial conditions (NGICs). The initial statistics are lognormal in the gravitational potential field with positive (LNp) and negative (LNn) skewness; the sign of the skewness is conserved by the density field, and the power spectrum is the same for all the simulations. Our aim is not to test a given non-Gaussian statistics, but to explore the generic effect of positive- and negative-skew statistics on halo properties. From our low-resolution simulations, we find that LNp (LNn) halos are systematically more (less) concentrated than their Gaussian counterparts. This result is confirmed by our Milky Way- and cluster-sized halos resimulated with high-resolution. In addition, they show inner density profiles that depend on the statistics: the innermost slopes of LNp (LNn) halos are steeper (shallower) than those obtained from the corresponding Gaussian halos. A subhalo population embedded in LNp halos is more susceptible to destruction than its counterpart inside Gaussian halos. On the other hand, subhalos in LNn halos tend to survive longer than subhalos in Gaussian halos. The spin parameter probability distribution of LNp (LNn) halos is skewed to smaller (larger) values with respect to the Gaussian case. Our results show how the statistics of the primordial density field can influence some halo properties, opening this the possibility to constrain, although indirectly, the primordial statistics at small scale.Comment: 15 pages, 8 figures. Slight corrections after referee report. To appear in ApJ, v598, November 20, 200

Search for Gamma-Ray Transients using the SMM Spectrometer

Observations for transient radiation made by the Gamma Ray Spectrometer on the SMM satellite are summarized. Spectra were obtained from 215 solar flares and 177 gamma-ray bursts. No narrow or moderately broadened lines were observed in any of the bursts. The rate of bursts is consistent with a constant over the mission but is weakly correlated with solar activity. No evidence was found for bursts of 511 keV line emission, unaccompanied by a strong continuum, at levels not less than 0.05 gamma/sq cm s for bursts lasting not more than 16 s. No evidence was found for broad features near 1 MeV from Cyg X-1, the Galactic center, or the Crab in 12-d integrations at levels not less than 0.006 gamma/sq cm s. No evidence was found for transient celestial narrow-line emission from 300 keV to 7 MeV on min-to-hrs-long time scales from 1984 to 1989

Starspots on the fastest rotators in the Beta Pic moving group

Aims: We carried out high-resolution spectroscopy and BV(I)_C photometric monitoring of the two fastest late-type rotators in the nearby Beta Pictoris moving group, HD199143 (F7V) and CD-641208 (K7V). The motivation for this work is to investigate the rotation periods and photospheric spot patterns of these very young stars, with a longer term view to probing the evolution of rotation and magnetic activity during the early phases of main-sequence evolution. We also aim to derive information on key physical parameters, such as rotational velocity and rotation period. Methods: We applied maximum entropy (ME) and Tikhonov regularizing (TR) criteria to derive the surface spot map distributions of the optical modulation observed in HD199143 (F7 V) and CD-641208 (K7V). We also used cross-correlation techniques to determine stellar parameters such as radial velocities and rotational velocities. Lomb-Scargle periodograms were used to obtain the rotational periods from differential magnitude time series. Results: We find periods and inclinations of 0.356 days and 21.5deg for HD199143, and 0.355 days and 50.1deg for CD-641208. The spot maps of HD199143 obtained from the ME and TR methods are very similar, although the latter gives a smoother distribution of the filling factor. Maps obtained at two different epochs three weeks apart show a remarkable increase in spot coverage amounting to ~7% of the surface of the photosphere over a time period of only ~20 days. The spot maps of CD-641208 from the two methods show good longitudinal agreement, whereas the latitude range of the spots is extended to cover the whole visible hemisphere in the TR map. The distributions obtained from the first light curve of HD199143 show the presence of an extended and asymmetric active longitude with the maximum filling factor at longitude ~325degree.Comment: Accepted by A&A. 13 pages, 13 figures (4 online included), 5 Table

Nonlocal properties of entangled two-photon generalized binomial states in two separate cavities

We consider entangled two-photon generalized binomial states of the electromagnetic field in two separate cavities. The nonlocal properties of this entangled field state are analyzed by studying the electric field correlations between the two cavities. A Bell's inequality violation is obtained using an appropriate dichotomic cavity operator, that is in principle measurable.Comment: 5 pages, 1 figur

Accumulation of entanglement in a continuous variable memory

We study the accumulation of entanglement in a memory device built out of two continuous variable (CV) systems. We address the case of a qubit mediating an indirect joint interaction between the CV systems. We show that, in striking contrast with respect to registers built out of bidimensional Hilbert spaces, entanglement superior to a single ebit can be efficiently accumulated in the memory, even though no entangled resource is used. We study the protocol in an immediately implementable setup, assessing the effects of the main imperfections.Comment: 4 pages, 3 figures, RevTeX