Mechanically alloyed magnesium-based materials For hydrogen storage

Mechanical alloying is very promising technique for fabrication of hydrogen storage materials possessing good hydriding properties. Magnesium and magnesium-based alloys are attractive from hydrogen capacity point of view, but the kinetics of hydridingdehydriding of magnesium are not sufficiently fast even at elevated temperature. Moreover, the theoretical hydrogen capacity is never achieved in practice. In this work, various approaches to improving hydrogen storage properties of magnesium-based materials with the help of mechanical alloying are discussed and some experimental results illustrate the possibility of each approach. It is demonstrated that improving the hydrogen storage properties of known hydrogen absorbing materials is possible by affecting their structure, morphology, surface properties and so on, using mechanical activation and mechanical alloying with various types of additives. It is possible to search for new hydrogen absorbing materials by means of mechanochemical fabrication of metastable composites of components very different in nature including thermodynamically immiscible ones. These composites may possess very interesting hydrogen storage properties and serve as precursors for the synthesis of new phases. Direct synthesis of metastable intermetallic compounds or hydrided phases in the course of mechanical alloying also opens opportunities to obtain materials promising for hydrogen storage

Reduction of Bridge Construction and Maintenance Costs through Coupled Geotechnical and Structural Design of Integral Abutment Bridges

Elimination expansion joints in the superstructure of integral abutment bridges offers the advantage of reducing the initial and life cycle costs of the structure. However, such elimination may have an adverse effect on the displacement demand at the pile-abutment connection and on the earth pressures on the abutment wall due to the thermal expansion/contraction cycles of the bridge. These adverse effects have resulted in regulations that impose restrictions on the maximum length and skew angle of integral abutment bridges. This research consisted of a deep analysis of the problem by considering soil-structure interaction. The approach was multifaceted as it included experimental and numerical analysis. Upon calibration and verification of the constitutive model, it was used as part of a parametric analysis to provide recommendations for the design limits of integral abutment bridges. The analysis results showed that active state earth pressure is reached after the first contraction cycle. The displacement demand on piles is a function of the abutment wall displacement. Larger displacement demand of the pile at the acute corner when compared to the obtuse corner was observed during expansion and contraction cycles. The inflection point of the piles deformed shape was found to be at relatively shallow depth. Concrete shrinkage and sequence of loading affected significantly the displacement demand of the supporting piles, lower displacement demand of piles during the expansion cycle and larger displacement demand during contraction cycles. The analysis showed that a 500 ft bridge with 60° skew will provide acceptable long term performance

Estimating Strength from Stiffness for Chemically Treated Soils

The central theme of this study is to identify strength-stiffness correlations for chemically treated subgrade soils in Indiana. This was done by conducting Unconfined Compression (UC) Tests and Resilient Modulus Tests for soils collected at three different sites—US-31, SR-37, and I-65. At each site, soil samples were obtained from 11 locations at 30 ft spacing. The soils were treated in the laboratory with cement, using the same proportions used for construction, and cured for 7 and 28 days before testing. Results from the UC tests were compared with the resilient modulus results that were available. No direct correlation was found between resilient modulus and UCS parameters for the soils investigated in this study. A brief statistical analysis of the results was conducted, and a simple linear regression model involving the soil characteristics (plasticity index, optimum moisture content and maximum dry density) along with UCS and resilient modulus parameters was proposed

Hawaiian Lava Tubes with Extraterrestrial Habitat Applications

One of the next major steps in space exploration, as noted by agencies such as NASA and SpaceX, is the creation of extraterrestrial habitats. Most current extraterrestrial habitat designs focus on above-surface solutions and do not consider all the hazards that can impact this habitat. However, the existence of lava tubes on the moon, supported by data from Gravity Recovery and Interior Laboratory (GRAIL), SELenological and ENgineering Explorer (SELENE), and NASA’s Lunar Reconnaissance Orbiter (LRO), could impact extraterrestrial habitat designs. To support life, a prospective habitat must be safe from the harsh conditions of space, including meteorite impacts, radiation, and fluctuating temperatures. Lunar lava tubes, cave-like structures created during volcanic eruptions, can house a prospective habitat. This paper provides an understanding of lava tube morphology and formation methods on Earth which gives insight into extraterrestrial lava tubes, specifically their structure, stability, and formation methods. By studying lava tubes in Hawaii, a better understanding of these qualities is formed. This knowledge provides for a more accurate model in which stability is further investigated. Several factors are investigated in this model, including size and geometry. Using a case study of the Kaumana Cave and Thurston’s lava tube in Hawaii, it is found that stable terrestrial lava tubes share many similarities with extraterrestrial lava tubes. This shows the stability of lava tubes a few kilometers wide on the Moon. By knowing more about the stability of lunar lava tubes found through this research, future extraterrestrial habitat engineering designs will be impacted

Complexity and robustness of the flavonoid transcriptional regulatory network revealed by comprehensive analyses of MYB-bHLH-WDR complexes and their targets in Arabidopsis seed.

In Arabidopsis thaliana, proanthocyanidins (PAs) accumulate in the innermost cell layer of the seed coat (i.e. endothelium, chalaza and micropyle). The expression of the biosynthetic genes involved relies on the transcriptional activity of R2R3-MYB and basic helix-loop-helix (bHLH) proteins which form ternary complexes (\u27MBW\u27) with TRANSPARENT TESTA GLABRA1 (TTG1) (WD repeat protein). The identification of the direct targets and the determination of the nature and spatio-temporal activity of these MBW complexes are essential steps towards a comprehensive understanding of the transcriptional mechanisms that control flavonoid biosynthesis. In this study, various molecular, genetic and biochemical approaches were used. Here, we have demonstrated that, of the 12 studied genes of the pathway, only dihydroflavonol-4-reductase (DFR), leucoanthocyanidin dioxygenase (LDOX), BANYULS (BAN), TRANSPARENT TESTA 19 (TT19), TT12 and H(+) -ATPase isoform 10 (AHA10) are direct targets of the MBW complexes. Interestingly, although the TT2-TT8-TTG1 complex plays the major role in developing seeds, three additional MBW complexes (i.e. MYB5-TT8-TTG1, TT2-EGL3-TTG1 and TT2-GL3-TTG1) were also shown to be involved, in a tissue-specific manner. Finally, a minimal promoter was identified for each of the target genes of the MBW complexes. Altogether, by answering fundamental questions and by demonstrating or invalidating previously made hypotheses, this study provides a new and comprehensive view of the transcriptional regulatory mechanisms controlling PA and anthocyanin biosynthesis in Arabidopsis

Evaluation of Radiation and Design Criteria for a Lunar Habitat

Extraterrestrial habitation has long been the object of science fiction, and experts in the fields of science and engineering have proposed many designs for a lunar base. The research conducted has focused on either structural stability, radiation protection, or meteorite-impact vulnerabilities, but rarely have these been considered together. The Resilient ExtraTerrestrial Habitats (RETH) project aims to design a lunar habitat from a hazards perspective, considering general degradation, meteorite impacts, seismic activity, radiation exposure, thermal extremes, and geomagnetic storms in addition to the physiological, psychological, and sociological aspects of astronauts living in such a habitat. Several members of the RETH team will begin the project by each quantifying an individual hazard and proposing a solution which, when combined with other members’ research, will provide specific parameters used in designing a safe, self-sustaining lunar or planetary outpost. This paper focuses on the effects of cosmic and solar radiation which can be detrimental to the health of future lunar inhabitants, and as such, quantifying the amount of radiation present in the environment is vital. Different materials such as aluminum, polyethylene, water, and regolith can provide adequate shielding with varying thickness, though the possibility of using lunar lava tubes remains open

Static and dynamic responses to hyperoxia of normal placenta across gestation with T2*-weighted sequences

OBJECTIVES: T2*-weighted sequences have been identified as non-invasive tools to study the placental oxygenation in-vivo. This study aims to investigate both static and dynamic responses to hyperoxia of the normal placenta across gestation.METHODS: We conducted a single-center prospective study including 52 uncomplicated pregnancies. Two T2*-weighted sequences were performed: T2*-relaxometry was performed before and after maternal hyperoxia. The histogram distribution of T2* values was assessed by fitting a gamma distribution as T2*~Γ(αβ). A dynamic acquisition (BOLD protocol) was also performed before and during oxygen supply, until placental oxygen saturation. The signal change over time was modeled using a sigmoid function, used to determine the intensity of enhancement (∆BOLD,%), a temporal variation coefficient (λ,min -1 , controlling the slope of the curve), and the maximal steepness (Vmax, ∆BOLD.min -1 ) of placental enhancement. RESULTS: The histogram analysis of the T2* values in normoxia showed a whole-placenta variation, with a decreasing linear trend in the mean T2* value (R= -0.83, 95% CI [-0.9, -0.71], p&lt;0.001) along with a more peaked and narrower distribution of T2* values across gestation. After maternal hyperoxia, the mean T2* ratios (mean T2* hyperoxia / mean T2* baseline ) were positively correlated with gestational age, while the other histogram parameters remained stable, suggesting a translation of the histogram towards higher values with a similar aspect. The ∆BOLD showed a non-linear increase across gestation. Conversely, the λ(min -1 ) parameter, showed an inverted trend across gestation, with a significantly weaker correlation (R = -0.33, 95% CI [-0.58, -0.02], p=0.04, R 2 = 0.1). As a combination of ∆BOLD and λ, the changes in Vmax throughout gestation were mainly influenced by the changes in ∆BOLD and resulted in a positive non-linear correlation with gestational age. CONCLUSION: Our results suggest that the decrease in the T2* placental signal over gestation does not reflect a dysfunction. The BOLD effect, representative of a free-diffusion model of oxygenation, highlights the growing differences in oxygen saturation between mother and fetus across gestation (∆BOLD), and placental permeability to oxygen (λ). This article is protected by copyright. All rights reserved.</p

Development of a mathematical model for predicting electrically elicited quadriceps femoris muscle forces during isovelocity knee joint motion

<p>Abstract</p> <p>Background</p> <p>Direct electrical activation of skeletal muscles of patients with upper motor neuron lesions can restore functional movements, such as standing or walking. Because responses to electrical stimulation are highly nonlinear and time varying, accurate control of muscles to produce functional movements is very difficult. Accurate and predictive mathematical models can facilitate the design of stimulation patterns and control strategies that will produce the desired force and motion. In the present study, we build upon our previous isometric model to capture the effects of constant angular velocity on the forces produced during electrically elicited concentric contractions of healthy human quadriceps femoris muscle. Modelling the isovelocity condition is important because it will enable us to understand how our model behaves under the relatively simple condition of constant velocity and will enable us to better understand the interactions of muscle length, limb velocity, and stimulation pattern on the force produced by the muscle.</p> <p>Methods</p> <p>An additional term was introduced into our previous isometric model to predict the force responses during constant velocity limb motion. Ten healthy subjects were recruited for the study. Using a KinCom dynamometer, isometric and isovelocity force data were collected from the human quadriceps femoris muscle in response to a wide range of stimulation frequencies and patterns. % error, linear regression trend lines, and paired t-tests were used to test how well the model predicted the experimental forces. In addition, sensitivity analysis was performed using Fourier Amplitude Sensitivity Test to obtain a measure of the sensitivity of our model's output to changes in model parameters.</p> <p>Results</p> <p>Percentage RMS errors between modelled and experimental forces determined for each subject at each stimulation pattern and velocity showed that the errors were in general less than 20%. The coefficients of determination between the measured and predicted forces show that the model accounted for ~86% and ~85% of the variances in the measured force-time integrals and peak forces, respectively.</p> <p>Conclusion</p> <p>The range of predictive abilities of the isovelocity model in response to changes in muscle length, velocity, and stimulation frequency for each individual make it ideal for dynamic applications like FES cycling.</p

Estimating Strength From Stiffness for Chemically Treated Soils

SPR-4420The central theme of this study is to identify strength-stiffness correlations for chemically treated subgrade soils in Indiana. This was done by conducting Unconfined Compression (UC) Tests and Resilient Modulus Tests for soils collected at three different sites\u2014US-31, SR-37, and I-65. At each site, soil samples were obtained from 11 locations at 30 ft spacing. The soils were treated in the laboratory with cement, using the same proportions used for construction, and cured for 7 and 28 days before testing. Results from the UC tests were compared with the resilient modulus results that were available. No direct correlation was found between resilient modulus and UCS parameters for the soils investigated in this study. A brief statistical analysis of the results was conducted, and a simple linear regression model involving the soil characteristics (plasticity index, optimum moisture content and maximum dry density) along with UCS and resilient modulus parameters was proposed